Entrepreneurship education of college students and entrepreneurial psychology of new entrepreneurs under causal attribution theory.

With the rapid development of information technology, the society's demand for innovative talents has become increasingly prominent. The purpose of this study is to optimize the teaching strategies of entrepreneurship education for college students, further cultivate college students' entrepreneurial ideas, and promote the formation of entrepreneurial values. The problems existing in entrepreneurship education in colleges and universities are studied based on entrepreneurial psychology and attribution theory. A questionnaire survey is conducted on the problems with a high probability of entrepreneurial failure of college students. The heads of new ventures in Xi'an are selected. Then, 300 questionnaires are distributed, and 209 are returned. The survey results are analyzed using failure attribution and failure learning. Suggestions are provided for management strategies of new ventures. The results show that the Corrected Item-Total Correlation (CITC) value of R-1 is 0.65, and the CITC value of R-2 is 0.35. In addition, the Kaiser-Meyer-Olkin (KMO) values of entrepreneurial failure attribution and entrepreneurial failure mode are both greater than 0.7, which indicates that the scale of entrepreneurial failure attribution has good validity and can be used for factor analysis. However, the KMO values of entrepreneurial failure attribution and entrepreneurial failure learning model are both greater than 0.7, and the significance of Bartlett sphericity test is 0.00, which indicates that the survey has good validity. The research has practical application and reference value for the cultivation of college students' innovative and entrepreneurial ability.

In-situ preparation of biochar-loaded particle electrode and its application in the electrochemical degradation of 4-chlorophenol in wastewater.

In order to effectively degrade 4-chlorophenol in wastewater, a biochar-loaded particle electrode was prepared using an in-situ method. The method employed bagasse as the raw material, KOH as the activator, SnCl4·5H2O, MnCl2·4H2O and SbCl3 as the modifiers. Furthermore, X-ray diffraction, scanning electron microscopy and energy dispersive spectrometer were used to characterize the crystal composition, morphology and elemental compositions of the proposed particle electrode. The electrochemical performance of the proposed particle electrode was analyzed using an electrochemical workstation. A three-dimensional packed-bed electrochemical reactor was constructed using the loaded biomass carbon particle electrodes. The effects of different loaded biomass carbon particle electrodes on the electrochemical degradation of 4-chlorophenol were studied, and the mechanism of electrochemical degradation of 4-chlorophenol was discussed. The results showed that the effect of the supported biomass carbon particle electrode on the degradation of 4-chlorophenol was significantly higher than that of the unsupported biomass carbon particle electrode. Additionally, the electrochemical degradation of 4-chlorophenol was greatly influenced by the biomass carbon particle electrode with different loading and concentration. The removal efficiencies of 4-chlorophenol using the electrochemical treatment under the studied experimental conditions were found in the following descending order: Mn/AC > Sn/AC > Sb/AC. Among them, the biomass carbon particle electrode prepared using 150 g L-1 MnCl2·4H2O showed the best treatment effect for 4-chlorophenol. After electrochemical treatment of 500 mg L-1 of 4-chlorophenol-simulated wastewater for 1 h, the removal efficiency of 4-chlorophenol reached 99.93%.

Facile synthesis of S-Ag nanocomposites and Ag2S short nanorods by the interaction of sulfur with AgNO3 in PEG400.

A facile, eco-friendly and inexpensive method to prepare Ag2S short nanorods and S-Ag nanocomposites using sublimed sulfur, AgNO3, PVP and PEG400 was studied. According to x-ray diffraction and scanning electron microscopy of the Ag2S, the products are highly crystalline and pure Ag2S nanorods with diameters of 70-160 nm and lengths of 200-360 nm. X-ray diffraction of the S-Ag nanocomposites shows that we obtained cubic Ag and S nanoparticles. Transmission electron microscopy shows that the molar ratio of PVP to Ag(+) plays an important role in controlling the size and morphology of the S-Ag nanocomposites. When the molar ratio of PVP to Ag(+) was 10:1, smaller sizes, better dispersibility and narrower distribution of S-Ag nanocomposites with diameters of 10-40 nm were obtained. The formation mechanism of the S-Ag nanocomposites was studied by designing a series of experiments using ultraviolet-visible measurement, and it was found that S nanoparticles are produced first and act as seed crystals; then Ag(+) becomes Ag nanocrystals on the surfaces of the S nanoparticles by the reduction of PVP. PEG400 acts as a catalyzer, accelerating the reaction rate, and protects the S-Ag nanocomposites from reacting to produce Ag2S. The antimicrobial experiments show that the S-Ag nanocomposites have greater antimicrobial activity on Staphylococcus aureus, Aspergillus niger and blue mold than Ag nanoparticles.