ABSTRACT
It is important to develop new energy storage and conversion technology to mitigate the energy crisis for the sustainable development of human society. In this study, free-standing porous nitrogen-doped carbon fiber (PN-CF) membranes were obtained from the pyrolysis of Zn-MOF-74/polyacrylonitrile (PAN) composite fibers, which were fabricated in situ by an electrospinning technology. The resulting free-standing fibers can be cut into membrane disks and directly used as an anode electrode without the addition of any binder or additive. The PN-CFs showed great reversible capacities of 210 mAh g-1 at a current density of 0.05 A g-1 and excellent cyclic stability of 170.5 mAh g-1 at a current density of 0.2 A g-1 after 600 cycles in sodium ion batteries (SIBs). The improved electrochemical performance of PN-CFs can be attributed to the rich porous structure derived by the incorporation of Zn-MOF-74 and nitrogen doping to promote sodium ion transportation.
ABSTRACT
It is a great challenge to accurately estimate chemical activity of hydrophobic organic contaminants in field soils. Ex-situ and in-situ determinations were developed for this purpose based on low-density polyethylene (LDPE) passive sampling and non-equilibrium correction by release of performance reference compounds (PRCs) previously spiked to the samplers. This work investigated kinetic processes of target contaminants' uptake into and PRCs' release from the sampler in an ex-situ soil suspension incubated for 100 days. A close agreement of kinetic parameters for pyrene's (target) uptake into and deuterated pyrene's (PRC) release from LDPE indicated their similar exchange kinetics. Three kinetic models were developed to correct uptake of target compounds in non-equilibrium conditions via release processes of PRCs. The second-order kinetic model was recommended for ex-situ measurements. The PRC-based non-equilibrium corrections were further applied to in-situ static passive sampling from several weeks to months in a PAH-contaminated field site. Two-weeks' deployments were sufficient for quantifying lighter PAHs (logKOA < 8.0), but not recommended to accurately estimate heavier PAHs (logKOA > 9.0), even if over four months. Concentration estimates from the in-situ and ex-situ passive samplings were comparable in order of magnitude with traditional estimation from equilibrium partitioning models considering both organic and black carbon fractions.
ABSTRACT
Compared with dry and wet deposition rates, air-soil exchange fluxes cannot be directly measured experimentally. Polyethylene passive sampling was applied to assess transport directions and to measure concentration gradients in order to calculate diffusive fluxes of polycyclic aromatic hydrocarbons (PAHs) across the air-soil interface in an urban park of Shanghai, China. Seven campaigns with high spatial resolution sampling at 18 heights between 0 and 200â¯cm above the ground were conducted in 2017-2018. Air-to-soil deposition was observed, e.g. for phenanthrene, and soil-to-air volatilization for high molecular weight compounds, such as benzo[b]fluoranthene. Significant linear correlations between gaseous PAH concentration and log-transformed height were observed. Influence of vegetation on vertical concentration gradients of gaseous PAHs was insignificant in most cases except during the growing season. Local micrometeorological conditions resulted in a directional eddy diffusion in air and then influenced vertical diffusion of gaseous PAHs. Furthermore, the vertical eddy diffusivity was estimated as a function of distance to the air-soil surface. Air-soil exchange fluxes based on the Mackay's fugacity approach were calculated and confirmed by diffusive fluxes within air layer based on vertical concentration gradient of PAHs and eddy/molecular diffusion. Polyethylene passive sampling technology provides a useful tool to investigate air-soil exchange process.
