Water-Bridge-Assisted Ionic Conduction in Probe-Induced Conical Polymer Pattern Formation.

Formation of conical polymer structures by atomic force microscopy (AFM) nanolithography and the electrical-conduction mechanism involved in the AFM- probe-induced patterning process are reported. The current is dominated by water-bridge-assisted ionic conduction. Polymer phase transition and mass redistribution occur without modification or degradation of the poly(methyl methacrylate) (PMMA) material.