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Int J Biol Macromol ; 271(Pt 1): 132198, 2024 Jun.
Article in English | MEDLINE | ID: mdl-38821789

ABSTRACT

To address the issue of bisphenol A (BPA) contamination in wastewater, a novel hydrogel, sodium alginate/cellulose nanofibrils/ZIF-8 composite hydrogel (SCZC), was synthesized for efficient BPA removal. The SCZC exhibited an exceptional adsorption capacity of 1696 mg/g, aligning well with both Langmuir and pseudo-second-order models. Furthermore, it exhibited remarkable regeneration properties, maintaining 89.1 % of its adsorption capacity even after undergoing five adsorption-desorption cycles. The synthesized SCZC also acted as a fluorescent sensor for detecting BPA, employing dynamic quenching and offering linear detection ranges of 10-100 mg/L and 0.2-1.0 µg/L, with a low detection limit of 0.06 µg/L. Analysis of adsorption and detection mechanisms revealed that SCZC's exceptional performance could be attributed to the three-dimensional (3D) porous structure formed by sodium alginate and cellulose nanofibrils. Economic analysis indicated that SCZC, in comparison to commercially activated carbon, was relatively inexpensive. This study introduces a novel approach for designing and preparing a sodium alginate-based hydrogel incorporating metal-organic frameworks, offering simultaneous BPA detection and removal capabilities.


Subject(s)
Alginates , Benzhydryl Compounds , Cellulose , Hydrogels , Nanofibers , Phenols , Water Pollutants, Chemical , Alginates/chemistry , Phenols/analysis , Phenols/chemistry , Benzhydryl Compounds/analysis , Benzhydryl Compounds/chemistry , Cellulose/chemistry , Adsorption , Nanofibers/chemistry , Hydrogels/chemistry , Water Pollutants, Chemical/analysis , Water Pollutants, Chemical/chemistry , Metal-Organic Frameworks/chemistry
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