ABSTRACT
The effect of beating starting pulp was investigated on the oxidation efficiency of ammonium persulfate (APS), the yield, and the properties of the CNCs. The beaten pulp and the subsequent CNCs were characterized, respectively, by different techniques. The CNCs were classified as CNC1 and CNC2, dependent on ultrasonication. It showed that the beating exposed more free OH groups in the pulp and enhanced the yield and surface charges of CNCs. Compared to the CNC2, the CNC1 had a higher surface charge, higher crystallinity, higher thermal stability, shorter length, smaller length distribution, and slightly larger width. The CNC1 and CNC2 had similar rheological properties. For the beaten pulp with a beating degree of 25°SR, the yields of the CNC1 and the total CNCs reached the maximum, 42.65 and 34.11 %, respectively. The surface charges of the CNC1 and the CNC2 also reached the maximum, -44.5 and - 33.6 mV, respectively. Their crystallinity indexes were 80.07 and 75.42 %, respectively. The lengths of the CNC1 and the CNC2 were 157.31 ± 30.61 and 214.92 ± 65.52 nm, and their widths were 10.13 ± 2.74 and 9.43 ± 2.99 nm, respectively. Therefore, proper beating enhanced the APS oxidation efficiency and influenced the CNCs properties.
ABSTRACT
The isothermal crystallization behavior and corresponding morphology evolution of poly(d-lactic acid) (PDLA) blends with PLLA6.7k or MPEG-b-PLLA6.7k-g-glucose with different architectures and different PLLA-grafted copolymer contents were investigated. The formation of stereocomplexes (SCs) in between the chain branched structure of MPEG-b-PLLA6.7k-g-glucose and PDLA chains acting as the physical crosslinking points slows down the motion of PDLA chains, but the SCs could act as a heterogeneous nucleating agent for the late formation of homocrystals (HCs) in the blend system, accelerating the crystallization kinetics of HCs through enhancing the nucleation density. For PDLA/MPEG-b-PLLA6.7k-g-glucose blends, the mobility of SCs in the blend system and the nucleation density of SCs in the blends exhibit oppositional behavior during the isothermal crystallization at a Tc of 130 °C. The evolution of the crystal growth and structure during the isothermal crystallization process by rheometry has revealed the interesting role of the branched chains of MPEG-b-PLLA6.7k-g-glucose in the mechanism of the crystallization in PDLA blends.
ABSTRACT
The fabrication of Zn-CO2 batteries is a promising technique for CO2 fixation and energy storage. Herein, nitrogen-doped ordered mesoporous carbon (NOMC) is adopted as a bifunctional metal-free electrocatalyst for CO2 reduction and oxygen evolution reaction in the near-neutral electrolyte. The ordered mesoporous structures and abundant N-dopings of NOMC facilitate the accessibility and utilization of the active sites, which endow NOMC with excellent electrocatalysis performance and outstanding stability. Especially, a nearly 100% CO Faradaic efficiency is achieved at an ultralow overpotential of 360 mV for CO2 reduction. When constructed as an aqueous rechargeable Zn-CO2 battery using NOMC as the cathode, it yields a high peak power density of 0.71 mW cm-2 , a good cyclability of 300 cycles, and excellent energy efficiency of 52.8% at 1.0 mA cm-2 .
