Chemiluminescence sensing for Hg2+ in environment water using carbon materials from PVC dechlorination as signal initiator.

Chemiluminescence (CL) sensing with good performance remains a challenge. The utilization of secondary residues from polyvinyl chloride (PVC) treatment is the key to improve PVC recycling rate. Herein, dechlorinated carbon materials from PVC/iron scrap co-treatment in subcritical water were used as CL sensing element. It was found that tiny changes in the spatial structure of aptamer could cause huge changes in CL signal of the residue-luminol system. A CL biosensor was constructed for mercury in environment water for the first time. The detection limit was estimated to be 0.37 pM. High sensitivity was mainly due to strong CL triggering and signal amplification from residues and effective regulating residue activity by aptamer space dimension. For real water samples, the results by residue CL analysis were consistent with that by cold vapor atom adsorption spectroscopy (CVAAS). Most strikingly, the used material was secondary residues from the treatment of PVC waste, which reduced the time and energy consumption of CL sensing. This research proposed the approach for routine monitoring mercury in environment but also provided the reference for developing other environmentally beneficial analysis platforms.

Designing Phenyl Porous Organic Polymers with High-Efficiency Tetracycline Adsorption Capacity and Wide pH Adaptability.

Adsorption is an effective method to remove tetracycline (TC) from water, and developing efficient and environment-friendly adsorbents is an interesting topic. Herein, a series of novel phenyl porous organic polymers (P-POPs), synthesized by one-pot polymerization of different ratios of biphenyl and triphenylbenzene under AlCl3 catalysis in CH2Cl2, was studied as a highly efficient adsorbent to removal of TC in water. Notably, the obtained POPs possessed abundant phenyl-containing functional groups, large specific surface area (1098 m2/g) with abundant microporous structure, high pore volume (0.579 cm3/g), favoring the removal of TC molecules. The maximum adsorption capacity (fitted by the Sips model) could achieve 581 mg/g, and the adsorption equilibrium is completed quickly within 1 h while obtaining excellent removal efficiency (98%). The TC adsorption process obeyed pseudo-second-order kinetics and fitted the Sips adsorption model well. Moreover, the adsorption of POPs to TC exhibited a wide range of pH (2-10) adaptability and outstanding reusability, which could be reused at least 5 times without significant changes in structure and efficiency. These results lay a theoretical foundation for the application of porous organic polymer adsorbents in antibiotic wastewater treatment.

Evaluation of riparian condition of Songhua River by integration of remote sensing and field measurements.

Riparian zone is crucial to the health of streams and their surrounding environment. Evaluation of riparian condition is essential to achieve and maintain good stream health, as well as to sustain ecological functions that riparian areas provide. This manuscript is aimed to evaluate riparian conditions of Songhua River, the fifth longest river in China, using physical structural integrality (PSI) values derived from remote sensing and validated by field measurements. The variation and clusters of PSI values were discriminated by the spatial statistics to quantify variation of riparian condition in each measurement section. Evaluation results derived from 13 measurement sections indicated that over 60% of the riparian zones have been disturbed by human activities. Analysis of land use patterns of riparian zone in the cold and hot spots found that land-use patterns had an important effect on riparian condition. The build-up and farmland areas had been the main human disturbances to the riparian condition, which were increased from 1976 to 2013. The low-low clusters (low PSI values with low neighbors) of PSI values can be implemented to identify the vulnerability of the riparian zone.