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1.
Analyst ; 148(14): 3174-3178, 2023 Jul 10.
Article in English | MEDLINE | ID: mdl-37337824

ABSTRACT

In this study, we propose a novel ion formation simulation method for electrospray ionization (ESI) and atmosphere pressure interface (API). In this method, not the sheer particle trajectory, but the evolution of droplets and the offspring of gaseous ions are introduced instead. For the first time, the dynamic droplet-to-ion transformation process in the API of ESI-MS is visualized. The results suggest that this model provides a better understanding of the ion evolution mechanism and we propose a way for mass spectrometer structure optimization and ion source parameter adjustment in new aspects.

2.
Ultrasonics ; 124: 106763, 2022 Aug.
Article in English | MEDLINE | ID: mdl-35598582

ABSTRACT

The stress monitoring of bolted connections is crucial in the evaluation of mechanical systems' structural health, and the ultrasonic method using TOF (Time of Flight) is considered promising in this application. However, the discrete nature of couplant layer characteristics can deteriorate the robustness of the ultrasonic method significantly. Here, for the purpose of deducting the coupling error, a compensating method of TOF is proposed. In this method, the components of the waves backscattering from bolt bearing surface within the temporal signal are filtered and utilized. The analytical coupling error correction model is established and the influences of the installation eccentricity upon the model are analyzed. Meanwhile, the proposed method is further verified by a finite element simulation and the results are consistent with the analytical derivations. Ultimately, the proposed method is experimentally validated and the scattering components are extracted from the pulse echo signal by using the synchrosqueezed wavelet transform. The results imply that, after being compensated by the proposed method, the stress measurement error decreased from 5% to 1%. This research provides a novel perspective in reducing the coupling error in a concise manner and is potential in improving the practicality of the ultrasonic bolt axial stress measurement methods.

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