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Molecules ; 24(10)2019 May 16.
Article in English | MEDLINE | ID: mdl-31100815

ABSTRACT

In this study, a carbon-based solid acid was created through the sulfonation of carbon obtained from the hydrothermal pretreatment of glucose. Additionally, ethyl levulinate, a viable liquid biofuel, was produced from furfuryl alcohol using the environmentally benign and low-cost catalyst in ethanol. Studies for optimizing the reaction conditions, such as reaction time, temperature, and catalyst loading, were performed. Under the optimal conditions, a maximum ethyl levulinate yield of 67.1% was obtained. The recovered catalyst activity (Ethyl levulinate yield 57.3%) remained high after being used four times, and it was easily regenerated with a simple sulfonation process. Moreover, the catalyst was characterized using FT-IR, XRD, SEM, elemental analysis, and acid-base titration techniques.


Subject(s)
Acids , Carbon , Ethanol , Furans , Glucose , Levulinic Acids , Acids/chemistry , Acids/metabolism , Carbon/chemistry , Carbon/metabolism , Catalysis , Ethanol/chemistry , Ethanol/metabolism , Furans/chemistry , Furans/metabolism , Glucose/chemistry , Glucose/metabolism , Hydrolysis , Levulinic Acids/chemistry , Levulinic Acids/metabolism , Metabolic Networks and Pathways , Molecular Structure
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