ABSTRACT
The short-chain forming process using rotary swaging (RS) is an important method of achieving the manufacturing of lightweight axles. Axle steel, like 42CrMo, is widely used in many types of axles and shafts; however, there is no existing research on rotary-swaged axle steel's mechanical properties. It makes sense to carry out a comprehensive study on the effect of RS on the mechanical behaviors of axle steel rods. In this study, a 42CrMo steel rod was processed by RS through ten passes. The tensile properties, torsion properties, compression properties, and fatigue properties were tested. There was an overall improvement in the torsional and fatigue performance after RS. Combined with a finite element analysis (FEM), the uneven distribution of the dislocations and existence of the elongation material were inferred to have caused the different modes of the mechanical behaviors. Fracture surfaces were analyzed and the results showed that the fracture pattern had changed. There existed a competitive relation between the internal fatigue cracks and external cracks, which could be attributed to uneven strain hardening. This research proved the advantages of RS in the processing of axle parts, which mainly benefitted the torsional working conditions, and provided evidence for a new processing route for lightweight axles with RS.
ABSTRACT
Inspired by adaptive natural organisms and living matter, soft actuators appeal to a variety of innovative applications such as soft grippers, artificial muscles, wearable electronics, and biomedical devices. However, their fabrication is typically limited in laboratories or a few enterprises since specific instruments, strong stimuli, or specialized operation skills are inevitably involved. Here a straightforward "cloth-to-clothes-like" method to prepare soft actuators with a low threshold by combining the hysteretic behavior of liquid crystal elastomers (LCEs) with the exchange reaction of dynamic covalent bonds, is proposed. Due to the hysteretic behavior, the LCEs (resemble "cloth") effectively retain predefined shapes after stretching and releasing for extended periods. Subsequently, the samples naturally become soft actuators (resemble "clothes") via the exchange reaction at ambient temperatures. As a post-synthesis method, this strategy effectively separates the production of LCEs and soft actuators. LCEs can be mass-produced in bulk by factories or producers and stored as prepared, much like rolls of cloth. When required, these LCEs can be customized into soft actuators as needed. This strategy provides a robust, flexible, and scalable solution to engineer soft actuators, holding great promise for mass production and universal applications.
ABSTRACT
Liquid crystalline elastomers are regarded as a kind of desirable soft actuator material for soft robotics and other high-tech areas. The isotropization temperature (Ti) plays an important role as it determines the actuation temperature and other properties, which in turn has a great effect on their applications. In the past, the common physical methods (e.g. annealing) to tune Ti is not applicable to tune the actuation temperature. The new Ti obtained by annealing immediately goes back to the old one once it is heated to a temperature above Ti, while actuation needs a temperature higher than Ti. For a fully cross-linked LCE material, once it is synthesized, the actuation temperature is fixed. Accordingly, the actuation temperature can not be tuned unless the chemical structure is changed, which usually needs to start from the very beginning of the molecular design and material synthesis. Here, we found that different Ti achieved by annealing can be preserved by reversible reactions of dynamic covalent bonds in covalently adaptable LC networks including LC vitrimers. Thus, a variety of soft actuators with different actuation temperatures can be obtained from the same fully cross-linked LCE material. As the tuning of Ti is also reversible, the same actuator can be adjusted for applications with different actuation temperature requirements. Such tuning will also expand the application of LCEs.
ABSTRACT
Liquid crystal vitrimers can be reprocessed, reshaped, welded, and healed due to exchange-reaction-enabled topology changes despite having fully covalently cross-linked network structures. Fabricating liquid crystal (LC) vitrimer actuators is invariably carried out above a characteristic temperature known as the topology freezing transition temperature (Tv). The reason that all exchange-reaction-based operations must be performed above Tv is because the exchange reaction is insignificant below Tv. Here we find that LC vitrimers can be reshaped at temperatures below the measured Tv, whereas non-LC vitrimers cannot. The work here not only makes it possible to create reprogrammable and stable LC vitrimer actuators at low temperatures but also reminds us that both our measurement and understanding of the Tv need further attention to facilitate the use of vitrimers in different areas.
ABSTRACT
Sophisticated shape-shifting structures and integration of advanced functions often call for different-chemistry-based polymers (such as epoxy and polyurethane) in a unified system. However, permanent cross-links pose crucial obstacles to be seamless. Here, merging interfaces via hybrid exchange reactions among different dynamic covalent bonds (including ester, urethane, thiourethane, boronic-ester, and oxime-ester linkages) is proposed, breaking the long-lasting restriction that these widely used bonds only undergo self-exchange reactions. Model compound studies are conducted to verify that hybrid exchange reactions occur. As demonstrations, different liquid crystal elastomers are tenaciously joined into coherent assemblies, with the desired biomimetic structures (e.g., flying fish containing stiff and flexible parts) and rare deformation modes (e.g., flower blooming upon both heating and cooling). Besides connecting polymers, hybrid exchange reactions also facilitate the creation of new materials through cross-fusion of different polymers. In addition to the polymers used in this work, hybrid exchange reactions can be adapted to other polymers based on similar mechanisms and beyond. Besides shape-shifting-related areas (e.g., soft robots, flexible electronics, and biomedical devices), it may also foster innovation in other fields involving general polymers, as well as promote deeper understanding of dynamic covalent chemistry.
Subject(s)
Elastomers , Polymers , Animals , Polymers/chemistry , Amides , EstersABSTRACT
25CrMo4 steel is widely used in the manufacturing of high-speed train axles due to its excellent mechanical properties. The purpose of this study is to develop an accurate modified constitutive model to describe the hot deformation behavior of the steel. Isothermal compression experiments were performed at different strain rates (0.01, 0.1, 0.5, and 1 s-1) and different temperatures (950, 1000, 1050, and 1100 °C) using a Gleeble-3800 thermal simulator. The microstructure after hot deformation was observed by the electron backscatter diffraction (EBSD), and the effects of temperature and strain rate were analyzed. The results showed that the coupling effect of temperature and strain rate on the dislocation density led to the change in the shape of the true stress-strain curve and that dynamic recovery (DRV) and dynamic recrystallization (DRX) caused the macroscopic softening phenomenon, with DRX being the main mechanism. Based on the true stress-strain curves, the strain-compensated Arrhenius constitutive model was calibrated. To improve prediction ability, a modified Arrhenius constitutive model was proposed, in which the temperature and strain rate coupling correction functions were incorporated. The original, modified Arrhenius models were evaluated according to the absolute relative error (ARE), the average absolute relative error (AARE), and the correlation coefficient (R2). Compared with the original model, the modified Arrhenius model has a higher prediction accuracy, with the ARE value mostly below 4%, the AARE value of 1.91%, and the R2 value of 0.9958.
