ABSTRACT
Although it suffers from a heavy dependence on the noble platinum catalyst, the electrochemical hydrogen evolution reaction (HER) is one of the most promising methods for the production of hydrogen. After numerous efforts, it is found that MoS2-based heterostructure may replace platinum as the electrochemical HER catalyst. In this work, the nanocrystalline NiSe2/MoS2 heterostructures were successfully prepared on the carbon fiber paper (CFP) substrate through electrochemical deposition and hydrothermal process. According to a series of electrochemical HER tests and a comparison with other MoS2-based heterostructure catalysts, the CFP/NiSe2/MoS2 catalyst with an overpotential η 10 of 143 mV and a Tafel slope of 45 mV dec-1 exhibited an excellent electrochemical HER catalytic performance and durability. In addition, CFP/NiSe2/MoS2 catalyst was treated by plasma to further improve the catalytic performance of the catalyst.
ABSTRACT
Although MoS2 has shown its potential as an electro-catalyst for the oxygen evolution reaction (OER), its research is still insufficient. In this study, as a novel MoS2-based heterostructure electro-catalyst for OER, namely NiSe2@MoS2 nano-heterostructure, was constructed on a carbon fiber paper (CFP) substrate by a simple approach, which includes electrochemical deposition of NiSe2 film and hydrothermal processing of MoS2 film. In addition to a series of observations on the material structure, electrocatalytic OER performance of NiSe2@MoS2 was fully evaluated and further compared with other MoS2-based OER electro-catalysts. It exhibits an outstanding catalytic performance with an overpotential η 10 of 267 mV and a Tafel slope of 85 mV dec-1. Only 6% loss of current density before and after 10 h indicates its excellent durability. The results indicate that the obtained NiSe2@MoS2 is an excellent OER electro-catalyst and worth exploring as a substitute for noble metal-based materials.
