Rheological studies of cellulose nanocrystal/dimethyl sulfoxide organogels.

Cellulose nanocrystals (CNCs)/H2O gels have received significant interest in various applications for the past decades. And yet CNCs organogels, which are important to their wider application, are less explored. In this work, CNCs/Dimethyl sulfoxide (DMSO) organogels are carefully investigated by rheological methods. It is found that metal ions also can facilitate the organogel formation as in hydrogel. Charge screening and coordination effects play vital roles in the organogel formation and their mechanical strength. CNCs/DMSO gels with different cations display similar mechanical strength, while CNCs/H2O gels show increasing mechanical strength with the increasing valence of cations. It seems that the coordination between cations and DMSO alleviate the influence of valence on gel mechanical strength. Due to weak, fast and reversible electrostatic interactions among CNCs particles, both CNCs/DMSO and CNCs/H2O gels show instant thixotropic behavior, which may find some interesting applications in the field of drug delivery. The morphological changes observed in polarized optical microscope appear to be consistent with rheological results.

Nanomaterials for Combined Stabilisation and Deacidification of Cellulosic Materials-The Case of Iron-Tannate Dyed Cotton.

The conservation of textiles is a challenge due to the often fast degradation that results from the acidity combined with a complex structure that requires remediation actions to be conducted at several length scales. Nanomaterials have lately been used for various purposes in the conservation of cultural heritage. The advantage with these materials is their high efficiency combined with a great control. Here, we provide an overview of the latest developments in terms of nanomaterials-based alternatives, namely inorganic nanoparticles and nanocellulose, to conventional methods for the strengthening and deacidification of cellulose-based materials. Then, using the case of iron-tannate dyed cotton, we show that conservation can only be addressed if the mechanical strengthening is preceded by a deacidification step. We used CaCO3 nanoparticles to neutralize the acidity, while the stabilisation was addressed by a combination of nanocellulose, and silica nanoparticles, to truly tackle the complexity of the hierarchical nature of cotton textiles. Silica nanoparticles enabled strengthening at the fibre scale by covering the fibre surface, while the nanocellulose acted at bigger length scales. The evaluation of the applied treatments, before and after an accelerated ageing, was assessed by tensile testing, the fibre structure by SEM and the apparent colour changes by colourimetric measurements.