High-performance carboxymethyl starch/PVA based intelligent packaging films engineered with Cu-Trp nanocrystal as functional compatibilizer.

A spindle-like Cu-based framework (Cu-Trp, Trp = L-Tryptophan) nanocrystal with ammonia-responsiveness was fabricated via simple aqueous solution approach, and it was subsequently explored as a functional compatibilizer of carboxymethyl starch/polyvinyl alcohol (CMS/PVA) blend toward constructing high-performance intelligent packaging films. The results showed that incorporation of Cu-Trp nanocrystal into CMS/PVA blend resulted in significant promotions regarding to the compatibility, mechanical strength (42.92 MPa), UV-blocking (with UV transmittance of only 2.4%), and water vapor barrier effectiveness of the blend film. Besides, the constructed CMS/PVA/Cu-Trp nanocomposite film exhibited superb long-term color stability, favorable antibacterial capacity (over 98.0%) toward both E. coli and S. aureus bacteria, as well as color change ability under ammonia environment. Importantly, the application trial confirmed that the CMS/PVA/Cu-Trp nanocomposite film is capable of visually monitoring shrimp spoilage during storage. These results implied that the CMS/PVA/Cu-Trp nanocomposite film holds tremendous potential as an intelligent active packaging material.

pH-responsive citral microcapsules with tannic acid-FeIII coordination complexes.

Citral is one of the most important aromatic ingredients in foods and beverages for its distinct lemon-like odor. However, the fast evaporation and oxidation limit these applications. Herein, citral microcapsules were constructed by tannic acid-FeIII coordination complexes (citral@TA-FeIII). The morphologies, structure, citral loading amount, pH responsiveness, oxidative stability and olfactory sensory evaluation were investigated. The obtained citral@TA-FeIII microcapsules presented core-shell structure with the average size of 528.16 nm. Citral loading amount was 12.79 %. Citral release exhibited pH-responsiveness with a sustained release rate at neutral pH and a fast release under acidic condition. Citral microcapsules retained excellent sensory profile due to the antioxidant capsule shells. Citral@TA-FeIII microcapsules efficiently inhibited bacteria (S. aureus and E. coli) growth, and the performance is enhanced under acidic condition by citral pH-responsive release. This work may open a new path for hydrophobic unsaturated aroma compounds encapsulation, widening their applications with multifunctionalities.

Dual stabilization of Pickering emulsion with epigallocatechin gallate loaded mesoporous silica nanoparticles.

Oxidation in food emulsions remains challenging to keep food quality and shelf-life. In this paper, a dual stabilization to both oil phase and antioxidant in Pickering emulsion is presented. Mesoporous silica nanospheres (MSN) were prepared to incorporate epigallocatechin gallate (EGCG), a typical plant-based antioxidant. EGCG loaded MSN were used to emulsify Litsea cubeba essential oil, a model oil, with olfactory investigation of the chemical stability. The emulsions improved the physical and chemical stabilization. The emulsions were uniformly stable with various parameters with one-month observation. Olfactory evaluation and GC-MS-O investigation reveal that the odors and odorous compounds of essential oil were well preserved in Pickering emulsions and much better than those in conventional emulsion with Tween 80. EGCG loaded MSN Pickering emulsion efficiently protect essential oil from oxidation. EGCG was also well retained in Pickering emulsion. This strategy could inspire new designs for food functional Pickering emulsions with efficient protective effect.

Supersmall Dendritic Mesoporous Silica Nanospheres as Antioxidant Nanocarriers for Pickering Emulsifiers.

Encapsulation of flavor and aromatic compounds in emulsions holds great potential for development of novel formulations in food applications. In this paper, supersmall dendritic mesoporous silica nanospheres (DMSNs) were fabricated by the one-pot strategy. The morphologies of DMSNs were directly tuned in terms of diameter from 35 ± 2 to 85 ± 4 nm. The obtained DMSNs are nanocarriers for hydrophilic or hydrophobic antioxidants with superior loading performance. Both DMSNs and antioxidant-loaded ones can emulsify the flavor and aromatic compounds yielding stable Pickering emulsions with droplets of approximately 2 µm in diameter. The emulsions possess excellent physical stability for at least half a year. More importantly, gas chromatography-mass spectrometry-olfactometry (GC-MS-O) analysis shows that antioxidant-loaded DMSNs provide outstanding protective functionalities to the encapsulated flavoring oil. A universality study reveals that DMSNs are an ideal platform for stable Pickering emulsions for aromatic compounds. Our design could provide a new path for flavor and sensitive bioactives for codelivery with excellent stability in food, medicine, cosmetics, etc.