Extraction of heavy metals from copper tailings by ryegrass (Lolium perenne L.) with the assistance of degradable chelating agents.

Heavy metal contamination is an urgent ecological governance problem in mining areas. In order to seek for a green and environmentally friendly reagent with better plant restoration effect to solve the problem of low efficiency in plant restoration in heavy metal pollution soil. In this study, we evaluated the effects of three biodegradable chelating agents, namely citric acid (CA), fulvic acid (FA) and polyaspartic acid (PASP), on the physicochemical properties of copper tailings, growth of ryegrass (Lolium perenne L.) and heavy metal accumulation therein. The results showed that the chelating agent application improved the physicochemical properties of copper tailings, increased the biomass of ryegrass and enriched more Cu and Cd in copper tailings. In the control group, the main existing forms of Cu and Cd were oxidizable state, followed by residual, weak acid soluble and reducible states. After the CA, FA or PASP application, Cu and Cd were converted from the residual and oxidizable states to the reducible and weak acid soluble states, whose bioavailability in copper tailings were thus enhanced. Besides, the chelating agent incorporation improved the Cu and Cd extraction efficiencies of ryegrass from copper tailings, as manifested by increased root and stem contents of Cu and Cd by 30.29-103.42%, 11.43-74.29%, 2.98-110.98% and 11.11-111.11%, respectively, in comparison with the control group. In the presence of multiple heavy metals, CA, FA or PASP showed selectivity regarding the ryegrass extraction of heavy metals from copper tailings. PCA analysis revealed that the CA-4 and PASP-7 treatment had great remediation potentials against Cu and Cd in copper tailings, respectively, as manifested by increases in Cu and Cd contents in ryegrass by 90.98% and 74.29% compared to the CK group.

Influence of conditioner and straw on the herbaceous plant-based phytoremediation copper tailings: a field trial at Liujiagou tailings pond, China.

A field trial was performed to carry out an enhanced phytoremediation technique for multi-metal contaminated copper tailings by Sudan grass (Sorghum Sudanese), ryegrass (Lolium perenne L.), and Bermuda grass (Cynodon dactylon), using conditioner (TH-LZ01) and straw combination into composite amendments as soil amendments, aimed to obtain the maximum of phytoremediation effect. The results showed that compared with untreated herbaceous plants, the application of conditioner and straw planted with herbaceous plants reduced the pH and conductivity and increased the organic matter and water content of the copper tailings to different degrees. With the addition of conditioner and straw, the DTPA-Cd, DTPA-Cu, DTPA-Pb, and DTPA-Zn contents in the copper tailings showed a decreasing trend compared with the untreated group. The herbaceous plants were promoted to reduce the percentage contents of acid soluble fractions Cd, Cu, Pb, and Zn and to increase the percentage contents of reducible, oxidizable, and residual fractions heavy metals (Cd, Cu, Pb, and Zn) in the copper tailings to different degrees. The contents of Cd, Cu, Pb, and Zn in the underground part of herbaceous plants were higher than those in the aboveground part, and the contents of Cd, Cu, Pb, and Zn in the aboveground part and underground part decreased after adding conditioner and straw, which indicated that the conditioner and straw inhibited the transport of heavy metals in the plant. Furthermore, the principal component analysis showed that the application of conditioner and straw with planting ryegrass had more potential for improving the physicochemical properties of copper tailings and reducing heavy metal toxicity, followed by Bermuda grass and Sudan grass.

Study on improvement of copper sulfide acid soil properties and mechanism of metal ion fixation based on Fe-biochar composite.

In this study, Fe modification of bamboo biochar (BC) with ferrate was used to construct a composite soil amendment based on K2FeO4-biochar (Fe-BC) system. Based on soil culture experiments, Fe-BC combined with organic-inorganic materials at the application levels of 3%, 5% and 10% to copper sulfide contaminated acid soil was studied. Adsorption kinetics experiment was used to investigate the adsorption capacity of Fe-modified biochar to heavy metal Cu. The results showed that the pH value of bamboo biochar could be increased by 1.12 units after K2FeO4 modification. Compared with the BC, the adsorption capacity of Cu2+ increased from 190.48 to 276.12 mg/g, which was mainly reflected in single-layer surface adsorption and chemisorption. Pore diffusion, electrostatic interaction and surface interaction are the possible mechanisms of Fe-BC interaction with Cu2+ ions. And the contents of Pb, Cu and Zn in soil leaching state decreased by 59.20%, 65.88% and 57.88%, respectively, at the 10% application level of Fe-BC. In general, the composite modifier based on ferrate and biochar has a positive effect on improving the characteristics of acidic soil in copper mining area.

Effect of composite amendments on physicochemical properties of copper tailings repaired by herbaceous plants.

Phytoremediation is considered to be the most environmentally friendly green restoration technology for dealing with mine waste. Adding amendments can improve the substrate environment for plant growth and enhance remediation efficiency. Herbaceous plants have become the preferred species for vegetation restoration in abandoned mines because of their fast greening and simple management. After 8 weeks of pot experiments in the early stage, it was shown that the plant height and fresh weight of the plants treated with 5% conditioner and 0.5% straw (C2S2) were significantly higher than those of other treatments. Considering that, in this paper, to explore the effect of composite amendments on physicochemical properties of copper tailings repaired by herbaceous plants, the untreated copper tailings were employed as the control group, whereas copper tailings repaired by ryegrass (Lolium perenne L.), vetiver grass (Chrysopogon zizanioides L.), and tall fescue (Festuca arundinacea) with or without conditioners and straw combination into the compound amendments were taken separately as the test group. After 6 months of planting, the pH, electrical conductivity, water content, available potassium, organic matter, total nitrogen, and available phosphorus in the main physical and chemical properties of copper tailings in each experimental area were analyzed. The results showed that the electrical conductivity, organic matter, and total nitrogen content of copper tailings were improved to a certain extent by planting plants without treatment. Meanwhile, compared with the control group, all indexes of planting plants showed an upward trend after adding composite amendments. Among them, pH, water content, and available potassium content of copper tailings were enhanced more obviously. Furthermore, as discovered from the gray correlation analysis results, vetiver grass planted with composite amendments has the best comprehensive effect of improving the physicochemical properties of copper tailings, followed by tall fescue and ryegrass.