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1.
Sci Rep ; 14(1): 6909, 2024 Mar 22.
Article in English | MEDLINE | ID: mdl-38519594

ABSTRACT

Layered rock slope exists widely. Because of its special slope structure, it is prone to bending deformation and toppling failure, which is a serious threat to engineering construction and safety operation. At present, the research of layered rock slope still has great innovation potential. During the construction of Wudongde Hydropower Station on Jinsha River, safety and stability problems such as slope geological structure development, face rock unloading and relaxation, and even slip and large deformation were encountered. Through field exploration, it is found that the rock and soil stratification of the slope on both sides of Wudongde Hydropower Station is highly obvious. At present, there is a lack of research on-site long-term displacement monitoring of layered rock high-steep slope, especially for layered slope in complex hydrogeology and construction environment. In order to strengthen the research on the deformation and stability of layered rock slope, this paper analyzes the measured displacement data of Wudongde hydropower station slope, and establishes three-dimensional geological finite element model with the help of numerical simulation software. The stability of the slope is calculated by combining the finite difference method and the strength reduction method. Finally, the evolution mechanism of the deformation of the layered rock slope is explained according to the geological structure characteristics. The main conclusions of this paper are as follows: the layered slope in the dam reservoir area is prone to deformation under the combined action of long-term construction disturbance and fissure water seepage, and the construction disturbance has a strong influence on the artificial excavation area below 1070 m, and the maximum rock mass deformation and surface displacement in the artificial excavation area of the slope reach 92.2 mm and 312.5 mm, respectively. However, the influence of construction disturbance on the natural mountain above 1070 m is limited, the valley deformation of the natural mountain on the left bank of the reservoir area is higher than that on the right bank, and the cumulative deformation is still less than 20 mm. The influence of seepage on the displacement of the area with higher elevation at the top of the slope is more obvious, and the influence of excavation and other disturbances on the displacement of the artificial excavation area with lower elevation is more obvious. The deformation of the river valley in the water cushion pond behind the dam increases slowly, and the change trend of the field deformation data is mostly consistent with that of the numerical calculation. The horizontal shrinkage of the mountains on both sides shows a contraction trend on the whole, and the maximum horizontal shrinkage calculated by numerical simulation is close to 20 mm, which is located at the elevation of 990 m.

2.
Sci Rep ; 13(1): 17288, 2023 Oct 12.
Article in English | MEDLINE | ID: mdl-37828256

ABSTRACT

The construction sector has become the most critical source of carbon emissions, but the existing thermal insulation materials such as thermal insulation mortar have obvious limitations, so it is urgent to develop building thermal insulation materials with superior performance and low cost. Aiming at the problem of poor bond strength of foam thermal insulation mortar, this research team selected basalt fiber as admixture to verify the influence of basalt fiber content on its performance and the economic feasibility of thermal insulation mortar. The main finding is that basalt fiber as an additive can obviously improve the crack resistance of thermal insulation mortar. When the content of basalt fiber increases from 0 to 2.5%, the compressive strength of mortar increases at first and then decreases, and the bond strength increases nonlinearly, but the thermal conductivity and dry density also increase. Therefore, the optimal content of basalt fiber is 1.5%. The improvement effect of fire resistance of thermal insulation mortar with 1.5% basalt fiber content is better. After curing for 28 days, the mass loss rate of the sample is reduced by about 11.1% after high temperature, and the relative compressive strength is increased by about 9.71% after high temperature. The raw material cost of the new fireproof thermal insulation mortar improved by basalt fiber is lower, and the cost of the finished product is reduced by 16.98%, 28.18%, 33.05% and 38.96%, respectively, compared with the four types of thermal insulation mortar already used in the market. More importantly, the economic recovery period of the new fireproof and thermal insulation mortar is undoubtedly shorter than that of alternative thermal insulation or energy storage materials, which not only achieves low emission and environmental protection, but also satisfies the economic feasibility.

3.
Analyst ; 148(23): 5942-5948, 2023 Nov 20.
Article in English | MEDLINE | ID: mdl-37853759

ABSTRACT

On the basis of the "seeing is believing" concept and the existing theory of Hg2+ coordination chemistry, for the first time, we innovatively designed and synthesized a visual-volumetric sensor platform with fluorescein and uracil functionalized polyacrylamide hydrogel. Without the aid of any complicated instruments and power sources, the sensor-enabled quantitative µM-level Hg2+ detection Hg2+ by reading graduation on a pipette with the naked eye. The sensor undergoes volumetric response and shows a wide linear response range to Hg2+ (1.0 × 10-6-5.0 × 10-5 mol L-1) with 2.8 × 10-7 mol L-1 as the detection limit. The highly selective (easily distinguished Hg2+ from other common metal ions), rapid response (∼30 min), and acceptable repeatability (RSD < 5% in all cases) demonstrated that the developed sensor is suitable for onsite practical use for the determination of Hg2+ while being low-cost, simple, and portable. The design principles of the obtained materials and the construction techniques and methods of the sensors described in our study provide a new idea for the research and development of smart materials and a series of visual-volumetric sensors for other analytes.

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