ABSTRACT
A light reflection device combined with visible light spectrophotometer was used to measure the reflectance-wavelength curves of colored stainless steel after coloring, hardening and sealing. After these processes, the coordinate in CIE 1931 color coordinate system and brightness of samples were confirmed by chromatometry method, and the effects of hardening and sealing processes on color were determined. In hardening process, the thickness of coloring film increases significantly, the peaks of reflectance-wavelength curves move to the long-wave region, the hue of samples changes clockwise in CIE 1931 coordinate diagram, and the trend of saturation in hardening process is consistent with the saturation of the sample having larger potential difference. In sealing process, the thickness of film increases slightly, the peaks of reflectance-wavelength curves move to the long-wave region, the reflectivity and brightness of samples increase, the hue of samples moves clockwise in CIE 1931 coordinate diagram, and the saturation of some samples decreases.
ABSTRACT
Development of catalytic routes to incorporate CO2 into carbonyl compounds at mild conditions remains attractive and challenging. Herein, a one-pot three-component cascade reaction of terminal propargylic alcohols, CO2 , and 2-aminoethanols through Ag(I) -based catalysis is reported for the synthesis of carbonyl compounds through C-O/C-N bond formation. This thermodynamically favorable route can be ingeniously regulated to afford a wide range of 2-oxazolidinones along with concurrent production of α-hydroxyl ketone derivatives in excellent yields and selectivity. Preliminary mechanistic studies indicate that such a process proceeds through successive formation of α-alkylidene cyclic carbonate, ß-oxopropylcarbamate, and 2-oxazolidinones.
