Development of gelatin/PVA based colorimetric films with a wide pH sensing range winery solid by-product (Vinasse) for monitor shrimp freshness.

Anthocyanins were extracted from a winery solid by-product (Vinasse) and added to fish gelatin (FG) and polyvinyl alcohol (PVA) matrices to create freshness monitoring labels. Three different colorimetric indicator smart films [PWE = polyvinyl alcohol with wine extract (WE), FWE = fish gelatin with WE, and PFWE = polyvinyl alcohol and FG blended film with WE] were generated and examined for their suitability to monitor the freshness of shrimp. The mechanical and optical properties, ammonia sensitivity, and colorimetric analysis of smart films were determined. Fourier transform-infrared spectroscopy (FTIR) was used to evaluate the interaction of anthocyanins with FG and PVA and changes in the film's chemical composition with storage. The film surfaces were characterized with atomic force microscopy (AFM). The incorporation of WE enhanced the films' flexibility by providing plasticizer and surfactant properties. The PWE film showed the best color stability. The FWE film showed the least amount of total color change with exposure to ammonia gas and was deemed suitable for refrigerated food packaging. The color of all indicator films showed significant changes suggesting that PWE, FWE, and PFWE films can be utilized in the intelligent packaging application for protein-rich foods to detect spoilage.

Combined fixed-functional treatment of skeletal class II malocclusions with the EVAA appliance: a preliminary study.

OBJECTIVES: The aim of this study was to compare the skeletal and dental effects of the EVAA appliance with those of an activator appliance in growing children with skeletal Class II anomalies. MATERIALS AND METHODS: A total of 34 subjects with Class II anomalies were recruited for this study. They were divided into three groups: the EVAA group (n=13; mean chronological age: 11 years 9 months), activator group (n=13; mean chronological age: 11 years 8 months) and control group (n=8; mean chronological age: 10 years 8 months). Lateral cephalometric radiographs were taken at the beginning and end of functional therapy. Fixed orthodontic treatment was completed in the EVAA group. A statistical software program (SPSS 18) was used for one-way analysis of variance and multiple comparisons with the Duncan test. RESULTS: We observed a significant decrease in the ANB, convexity, and 1┴NA (°), while a significant increase appeared in upper anterior facial height, posterior facial height, 1┴NB (mm), SN-lower occlusal plane values in the EVAA and activator groups after treatment (p<0.05). No significant difference in study parameters in the control group during the treatment period except for the increase in SNA and 1┴NA (mm) values (p<0.05) were observed. There were no significant differences between EVAA and activator treatment groups in terms of study parameters except for the articular angle, which was significantly higher in the EVAA group after therapy (p<0.05). CONCLUSION: The effects of EVAA appliances were similar to those of activator treatment.