Thermo-osmosis of a near-critical binary fluid mixture: A general formulation and universal flow direction.

We consider a binary fluid mixture, which lies in the one-phase region near the demixing critical point, and study its transport through a capillary tube linking two large reservoirs. We assume that short-range interactions cause preferential adsorption of one component onto the tube's wall. The adsorption layer can become much thicker than the molecular size, which enables us to apply hydrodynamics based on a coarse-grained free-energy functional. For transport processes induced by gradients of the pressure, composition, and temperature along a cylindrical tube, we obtain the formulas of the Onsager coefficients to extend our previous results on isothermal transport, assuming the critical composition in the middle of each reservoir in the reference equilibrium state. Among the processes, we focus on thermo-osmosis-mass flow due to a temperature gradient. We explicitly derive a formula for the thermal force density, which is nonvanishing in the adsorption layer and causes thermo-osmosis. This formula for a near-critical binary fluid mixture is an extension of the conventional formula for a one-component fluid, expressed in terms of local excess enthalpy. We predict that the direction of thermo-osmotic flow of a mixture near the upper (lower) consolute point is the same as (opposite to) that of the temperature gradient, irrespective of which component is adsorbed on the wall. Our procedure would also be applied to dynamics of a soft material, whose mesoscopic inhomogeneity can be described by a coarse-grained free-energy functional.

One Fixed Point Can Hide Another One: Nonperturbative Behavior of the Tetracritical Fixed Point of O(N) Models at Large N.

We show that at N=∞ and below its upper critical dimension, d

Real-Time Observation of Charge-Spin Cooperative Dynamics Driven by a Nonequilibrium Phonon Environment.

We report on experimental observations of charge-spin cooperative dynamics of two-electron states in a GaAs double quantum dot located in a nonequilibrium phonon environment. When the phonon energy exceeds the lowest excitation energy in the quantum dot, the spin-flip rate of a single electron strongly enhances. In addition, originated from the spatial gradient of phonon density between the dots, the parallel spin states become more probable than the antiparallel ones. These results indicate that spin is essential for further demonstrations of single-electron thermodynamic systems driven by phonons, which will greatly contribute to understanding of the fundamental physics of thermoelectric devices.

Why Might the Standard Large N Analysis Fail in the O(N) Model: The Role of Cusps in Fixed Point Potentials.

The large N expansion plays a fundamental role in quantum and statistical field theory. We show on the example of the O(N) model that at N=∞ its standard implementation misses some fixed points of the renormalization group in all dimensions smaller than four. These new fixed points show singularities under the form of cusps at N=∞ in their effective potential that become a boundary layer at finite N. We show that they have a physical impact on the multicritical physics of the O(N) model at finite N. We also show that the mechanism at play holds also for the O(N)⊗O(2) model and is thus probably generic.

Surprises in O(N) Models: Nonperturbative Fixed Points, Large N Limits, and Multicriticality.

We find that the multicritical fixed point structure of the O(N) models is much more complicated than widely believed. In particular, we find new nonperturbative fixed points in three dimensions (d=3) as well as at N=∞. These fixed points come together with an intricate double-valued structure when they are considered as functions of d and N. Many features found for the O(N) models are shared by the O(N)⊗O(2) models relevant to frustrated magnetic systems.

Electric Double Layer Composed of an Antagonistic Salt in an Aqueous Mixture: Local Charge Separation and Surface Phase Transition.

We examine an electric double layer containing an antagonistic salt in an aqueous mixture, where the cations are small and hydrophilic but the anions are large and hydrophobic. In this situation, a strong coupling arises between the charge density and the solvent composition. As a result, the anions are trapped in an oil-rich adsorption layer on a hydrophobic wall. We then vary the surface charge density σ on the wall. For σ>0 the anions remain accumulated, but for σ<0 the cations are attracted to the wall with increasing |σ|. Furthermore, the electric potential drop Ψ(σ) is nonmonotonic when the solvent interaction parameter χ(T) exceeds a critical value χ_{c} determined by the composition and the ion density in the bulk. This leads to a first-order phase transition between two kinds of electric double layers with different σ and common Ψ. In equilibrium such two-layer regions can coexist. The steric effect due to finite ion sizes is crucial in these phenomena.

Cell growth, division, and death in cohesive tissues: A thermodynamic approach.

Cell growth, division, and death are defining features of biological tissues that contribute to morphogenesis. In hydrodynamic descriptions of cohesive tissues, their occurrence implies a nonzero rate of variation of cell density. We show how linear nonequilibrium thermodynamics allows us to express this rate as a combination of relevant thermodynamic forces: chemical potential, velocity divergence, and activity. We illustrate the resulting effects of the nonconservation of cell density on simple examples inspired by recent experiments on cell monolayers, considering first the velocity of a spreading front, and second an instability leading to mechanical waves.

Emergence of epithelial cell density waves.

Epithelial cell monolayers exhibit traveling mechanical waves. We rationalize this observation thanks to a hydrodynamic description of the monolayer as a compressible, active and polar material. We show that propagating waves of the cell density, polarity, velocity and stress fields may be due to a Hopf bifurcation occurring above threshold values of active coupling coefficients.

Critical adsorption profiles around a sphere and a cylinder in a fluid at criticality: Local functional theory.

We study universal critical adsorption on a solid sphere and a solid cylinder in a fluid at bulk criticality, where preferential adsorption occurs. We use a local functional theory proposed by Fisher et al. [M. E. Fisher and P. G. de Gennes, C. R. Acad. Sci. Paris Ser. B 287, 207 (1978); M. E. Fisher and H. Au-Yang, Physica A 101, 255 (1980)PHYADX0378-437110.1016/0378-4371(80)90112-0]. We calculate the mean order parameter profile ψ(r), where r is the distance from the sphere center and the cylinder axis, respectively. The resultant differential equation for ψ(r) is solved exactly around a sphere and numerically around a cylinder. A strong adsorption regime is realized except for very small surface field h_{1}, where the surface order parameter ψ(a) is determined by h_{1} and is independent of the radius a. If r considerably exceeds a, ψ(r) decays as r^{-(1+η)} for a sphere and r^{-(1+η)/2} for a cylinder in three dimensions, where η is the critical exponent in the order parameter correlation at bulk criticality.

Hydrodynamics in bridging and aggregation of two colloidal particles in a near-critical binary mixture.

We investigate bridging and aggregation of two colloidal particles in a near-critical binary mixture when the fluid far from the particles is outside the coexistence (CX) curve and is rich in the component disfavored by the colloid surfaces. In such situations, the adsorption-induced interaction is enhanced, leading to bridging and aggregation of the particles. We realize bridging firstly by changing the temperature with a fixed interparticle separation and secondly by letting the two particles aggregate. The interparticle attractive force dramatically increases upon bridging. The dynamics is governed by hydrodynamic flow around the colloid surfaces. In aggregation, the adsorption layers move with the particles and squeezing occurs at narrow separation. These results suggest relevance of bridging in the reversible colloid aggregation observed so far. We use the local functional theory [J. Chem. Phys., 2012, 136, 114704] to take into account the renormalization effect and the simulation method [Phys. Rev. Lett., 2000, 85, 1338] to calculate the hydrodynamic flow around the colloidal particles.

Geometric pumping induced by shear flow in dilute liquid crystalline polymer solutions.

We investigate nonlinear rheology of dilute liquid crystalline polymer solutions under time dependent two-directional shear flow. We analyze the Smoluchowski equation, which describes the dynamics of the orientation of a liquid crystalline polymer, by employing technique of the full counting statistics. In the adiabatic limit, we derive the expression for time integrated currents generated by a Berry-like curvature. Using this expression, it is shown that the expectation values of the time-integrated angular velocity of a liquid crystalline polymer and the time-integrated stress tensor are generally not zero even if the time average of the shear rate is zero. The validity of the theoretical calculations is confirmed by direct numerical simulations of the Smoluchowski equation. Nonadiabatic effects are also investigated by means of simulations and it is found that the time-integrated stress tensor depends on the speed of the modulation of the shear rate if we adopt the isotropic distribution as an initial state.

Interface and vortex motion in the two-component complex dissipative Ginzburg-Landau equation in two-dimensional space.

We study interface and vortex motion in the two-component dissipative Ginzburg-Landau equation in two-dimensional space. We consider cases where the whole system is divided into several domains, and we assume that these domains are separated by interfaces and each domain contains quantized vortices. The equations for interface and vortex motion will be derived by means of a variational approach by Kawasaki. These equations indicate that, along an interface, the phase gradient fields of the complex order parameters is parallel to the interface. They also indicate that the interface motion is driven by the curvature and the phase gradient fields along the interface, and vortex motion is driven by the phase gradient field around the vortex. With respect to the static interactions between defects, we find an analogy between quantized vortices in a domain and electric charges in a vacuum domain surrounded by a metallic object in electrostatic. This analogy indicates that there is an attractive interaction between an interface and a quantized vortex with any charge. We also discuss several examples of interface and vortex motion.

Polydomain growth at isotropic-nematic transitions in liquid crystalline polymers.

We studied the dynamics of isotropic-nematic transitions in liquid crystalline polymers by integrating time-dependent Ginzburg-Landau equations. In a concentrated solution of rodlike polymers, the rotational diffusion constant D(r) of the polymer is severely suppressed by the geometrical constraints of the surrounding polymers so that the rodlike molecules diffuse only along their rod directions. In the early stage of phase transition, the rodlike polymers with nearly parallel orientations assemble to form a nematic polydomain. This polydomain pattern, with characteristic length ℓ, grows with self-similarity in three dimensions over time with an ℓ~t(1/4) scaling law. In the late stage, the rotational diffusion becomes significant, leading to a crossover of the growth exponent from 1/4 to 1/2. This crossover time is estimated to be on the order of t~D(r)(-1). We also examined the time evolution of a pair of disclinations placed in a confined system by solving the same time-dependent Ginzburg-Landau equations in two dimensions. If the initial distance between the disclinations is shorter than some critical length, they approach and annihilate each other; however, at larger initial separations, they are stabilized.