Portable Thomson scattering system for temporally resolved plasma measurements under low density conditions.

We present the development of a portable Thomson scattering diagnostic system allowing simultaneous spatially and temporally resolved plasma property measurements for low density plasmas. The setup uses a compact pulsed Nd:YAG laser (532 nm) as the light source with suppression by two volume Bragg grating notch filters and dispersion with a single-stage spectrometer before measurement with an intensified camera. A key issue is the detailed light collection and how it impacts the sensitivity and elastic light suppression, for which we have investigated two optical configurations, one based on a 7 × 1 linear fiber bundle and the other based on a slit spatial-filter. We find that the configuration with the slit spatial-filter provides a higher sensitivity by a factor of ∼2 along with more uniform spatial response. We have developed a custom pulsed-plasma setup with a modulation at 20 kHz, representative of the Hall thruster breathing mode oscillation, to show the possibility of temporally resolved measurements for electric propulsion applications. We have successfully recorded the variations in electron number density and temperature with sub-mm spatial resolution and capturing ten temporal points over the 50 µs modulation period. The detection limit of electron density (with the spatial-filter configuration) is ∼1.6 × 1017 m-3, which is ∼1/10 of the plasma density in the acceleration channel of Hall thrusters.

Contributed review: quantum cascade laser based photoacoustic detection of explosives.

Detecting trace explosives and explosive-related compounds has recently become a topic of utmost importance for increasing public security around the world. A wide variety of detection methods and an even wider range of physical chemistry issues are involved in this very challenging area. Optical sensing methods, in particular mid-infrared spectrometry techniques, have a great potential to become a more desirable tools for the detection of explosives. The small size, simplicity, high output power, long-term reliability make external cavity quantum cascade lasers (EC-QCLs) the promising spectroscopic sources for developing analytical instrumentation. This work reviews the current technical progress in EC-QCL-based photoacoustic spectroscopy for explosives detection. The potential for both close-contact and standoff configurations using this technique is completely presented over the course of approximately the last one decade.

A cavity ring-down spectroscopy sensor for real-time Hall thruster erosion measurements.

A continuous-wave cavity ring-down spectroscopy sensor for real-time measurements of sputtered boron from Hall thrusters has been developed. The sensor uses a continuous-wave frequency-quadrupled diode laser at 250 nm to probe ground state atomic boron sputtered from the boron nitride insulating channel. Validation results from a controlled setup using an ion beam and target showed good agreement with a simple finite-element model. Application of the sensor for measurements of two Hall thrusters, the H6 and SPT-70, is described. The H6 was tested at power levels ranging from 1.5 to 10 kW. Peak boron densities of 10 ± 2 × 10(14) m(-3) were measured in the thruster plume, and the estimated eroded channel volume agreed within a factor of 2 of profilometry. The SPT-70 was tested at 600 and 660 W, yielding peak boron densities of 7.2 ± 1.1 × 10(14) m(-3), and the estimated erosion rate agreed within ~20% of profilometry. Technical challenges associated with operating a high-finesse cavity in the presence of energetic plasma are also discussed.

Quartz crystal microbalance-based system for high-sensitivity differential sputter yield measurements.

We present a quartz crystal microbalance-based system for high sensitivity differential sputter yield measurements of different target materials due to ion bombardment. The differential sputter yields can be integrated to find total yields. Possible ion beam conditions include ion energies in the range of 30-350 eV and incidence angles of 0 degrees-70 degrees from normal. A four-grid ion optics system is used to achieve a collimated ion beam at low energy (<100 eV) and a two-grid ion optics is used for higher energies (up to 750 eV). A complementary weight loss approach is also used to measure total sputter yields. Validation experiments are presented that confirm high sensitivity and accuracy of sputter yield measurements.

Single-mode delivery of 250 nm light using a large mode area photonic crystal fiber.

We demonstrate that large mode area (LMA) photonic crystal fibers (PCFs) can be used as single-mode patch-cords for 250 nm laser light. We have studied the transmission of the 250 nm output beam of a frequency-quadrupled diode laser through a triangular structure LMA PCF with 10 microm core. We have achieved single-mode output with coupling loss of 1.8 +/- 0.6 dB and transmission loss of 1.5 +/- 0.2 dB/m. The critical bend loss radius is approximately 6 cm. The transmission loss is compared with published bulk silica measurements. Effects of optically induced damage were observed after prolonged operation and have been studied as function of laser power and time. The optical damage occurs primarily at the fiber input and can be partly ameliorated by cleaving the fiber input. For input power levels of < approximately 0.3 mW stable operation can be achieved for periods of >40 hours which is sufficient for many laboratory based applications. The results show the utility of these fibers for single-mode beam delivery in a spectral region where step-index single-mode fibers are not readily available.

Cavity ring-down spectroscopy sensor for ion beam etch monitoring and end-point detection of multilayer structures.

This contribution reports on the development of in situ sputter monitoring and end-point detection for ion beam etch systems using continuous-wave cavity ring-down spectroscopy (cw-CRDS). The demonstrated system is based on the detection of sputtered manganese atoms using a tunable external cavity diode laser in the vicinity of 403.07 nm. The cw-CRDS system is described and measurements from a manganese-iron target are presented. End-point detection is demonstrated by monitoring the time dependence of manganese concentration for a multilayer target comprised of alternating layers of manganese/iron and titanium. Detection limits are shown to be adequate for today's commercial ion beam sputter systems.

Velocity measurements by cavity ringdown spectroscopy.

We demonstrate velocity measurements of gas-phase particles by using cavity ringdown spectroscopy (CRDS). Velocity information is inferred from the Doppler-shift contributions to the measured absorption line shape. Because in CRDS the laser beam propagates back and forth within the optical cavity, a measured absorption feature is both upshifted and downshifted; i.e., it is split by the velocity component parallel to the optical axis. The splitting of the absorption features allows direct velocity measurements to be made without requiring an external frequency reference. The CRDS velocity measurement approach is demonstrated for sputtered molybdenum atoms in a low-pressure (collisionless) environment.

Detection of sputtered metals with cavity ring-down spectroscopy.

We report on use of cavity ring-down spectroscopy (CRDS) as a means to detect and quantify ion sputtering of refractory metal species. CRDS measurements are made with a neodymium:YAG-pumped optical parametric oscillator laser system in the 375-400 nm region. CRDS sputtering measurements are presented for argon ions incident on iron, aluminum, molybdenum, and titanium. The measurements are based on absorption from fine-structure levels of the electronic ground-state multiplets. For each species, characteristic spectra are provided, the dependence of sputtered particle number density on the beam current is examined, measured densities are compared with a sputter model, and detection limits are determined. For iron, aluminum, and titanium we probe multiple fine-structure levels within the ground-state multiplet and obtain information on their relative populations.

Use of hollow-core fibers to deliver nanosecond Nd:YAG laser pulses to form sparks in gases.

We report what is to our knowledge the first delivery of nanosecond laser pulses through flexible fibers to produce optical sparks in atmospheric-pressure gases. Our work employs a Nd:YAG laser beam (1.064 microm) delivered through a cyclic olefin polymer-coated silver hollow fiber. We studied the beam properties at the fiber exit as a function of the fiber launch geometry. We found that for a low-angle launch (approximately 0.01 rad half-angle), the exit beam has relatively high optical intensity (approximately 2 GW/cm2) and low light divergence (approximately 0.01 rad half-angle) and allows downstream spark formation. The effect of fiber bending on the exit beam and on the ability to make sparks is also investigated.

Characterization of laser seeding by use of group-velocity dispersion in an atomic-vapor filter.

A method for measuring laser seeding efficiencies by use of group-velocity dispersion has been developed. By tuning the laser near a resonance in an atomic-vapor filter it is possible to temporally decouple the seeded (narrow-band) light from the unseeded (broadband) light. We measured a seeding efficiency of 99.8% of the third harmonic of an injection-seeded Ti:sapphire laser. A model for the observed dispersion has been developed and tested. The group-velocity dispersion in the filter may also be used to chirp pulses for spectral analysis in the time domain.

Ultraviolet filtered Rayleigh scattering temperature measurements with a mercury filter.

We report the development of ultraviolet filtered Rayleigh scattering as a diagnostic tool for measurements of gas properties. A frequency-tripled narrow-linewidth Ti:sapphire laser illuminates a sample, and Rayleigh scattered light is imaged through a mercury-vapor absorption filter. Working in the ultraviolet improves the signal-to-noise ratio compared with that previously obtained in the visible as the result of an enhanced scattering cross section as well as the nearly ideal properties of the mercury filter. Tuning the laser through the absorption notch of the filter is a means of probing the scattering line shape, which contains temperature information. Temperature measurements of air are shown to have uncertainties of less than 3%.

Dispersion filter for spectral and spatial resolution of pure rotational Raman scattering.

A new filtering technique for Raman spectroscopy utilizes atomic vapor to suppress strong elastic and Rayleigh scattering while simultaneously resolving individual rotational Raman lines. Filtered images capture high-resolution spectral information in one dimension and spatial resolution in the other dimension. The filter is based on resonance enhanced dispersion, where the index of refraction varies dramatically. In a simple prism geometry the vapor disperses incident radiation according to frequency. A mercury-vapor-based dispersion filter has been fabricated, modeled, and demonstrated to capture pure rotational Raman scattering from CO(2).