1.
Org Lett
; 22(9): 3566-3569, 2020 05 01.
Article
in English
| MEDLINE
| ID: mdl-32282216
ABSTRACT
Chloroformates are key reagents for synthesizing carbonates and carbamates. The present study reports a novel photo-on-demand in situ synthesis of chloroformates with a CHCl3 solution containing a primary alkyl alcohol. It further allowed the one-pot synthesis of carbonates and carbamates through subsequent addition of alcohols or amines, respectively.