Investigation of the Effect of Stress on Oxygen Diffusion in Pure Titanium Using a Phase-Field Model.

Diffusion plays a vital role during the fabrication of many materials. It is a well-known fact that stress can influence diffusion behavior. In order to optimize material processing techniques, a quantitative evaluation of the effect of stress on diffusion is essentially required. By analyzing the free energy change in a Ti-O system during diffusion, a phase-field model was developed to address this issue. Using this model, the diffusion of oxygen atoms in pure titanium under different stress states was investigated. It was observed that the true equilibrium concentration of oxygen was proportional to its hydrostatic pressure. Tensile stress can increase the oxygen concentration. This raise in concentration decreased with temperature. However, the promotion of diffusion can be attained in deeper regions at a higher temperature. On the contrary, compressive stress inhibited the diffusion of oxygen in pure titanium. Under a certain compressive stress, the decrease in the oxygen concentration at the surface layer was more significant at a lower temperature, while a decrease could be observed at a deeper distance from the surface at a higher temperature. A thermodynamic explanation of the effect of stress on diffusion was given based on the proposed phase-field model.

Case Report: Identification of a novel LYN::LINC01900 transcript with promyelocytic phenotype and TP53 mutation in acute myeloid leukemia.

Acute myeloid leukemia (AML) is a malignant disease of myeloid hematopoietic stem/progenitor cells characterized by the abnormal proliferation of primitive and naive random cells in the bone marrow and peripheral blood. Acute promyelocytic leukemia (APL) is a type (AML-M3) of AML. Most patients with APL have the characteristic chromosomal translocation t(15; 17)(q22; q12), forming PML::RARA fusion. The occurrence and progression of AML are often accompanied by the emergence of gene fusions such as PML::RARA, CBFß::MYH11, and RUNX1::RUNX1T1, among others. Gene fusions are the main molecular biological abnormalities in acute leukemia, and all fusion genes act as crucial oncogenic factors in leukemia. Herein, we report the first case of LYN::LINC01900 fusion transcript in AML with a promyelocytic phenotype and TP53 mutation. Further studies should address whether new protein products may result from this fusion, as well as the biological function of these new products in disease occurrence and progression.

Role of Lanthanides and Bilayer Fe2As2 in the Electronic Properties of RbLn2Fe4As4O2 (Ln = Gd, Tb, and Dy) Superconductors.

The superconducting transition temperatures (Tc) of RbGd2Fe4As4O2, RbTb2Fe4As4O2, and RbDy2Fe4As4O2 are 35 K, 34.7 K, and 34.3 K without doping, respectively. For the first time, we have studied the high-temperature nonmagnetic state and the low-temperature magnetic ground state of 12442 materials, RbTb2Fe4As4O2 and RbDy2Fe4As4O2, using first principles calculations and comparing them with RbGd2Fe4As4O2. We also performed a detailed study of the effects of lanthanides and bilayer Fe2As2. We predict that the ground state of RbLn2Fe4As4O2 (Ln = Gd, Tb, and Dy) is spin-density-wave-type, in-plane, striped antiferromagnets, and the magnetic moment around each Fe atom is about 2 µB. We also found that the structural differences caused by the simple ionic radius have little effect on the properties of these three materials. Different lanthanide elements themselves play a major role in the electronic properties of the materials. It can be confirmed that the effect of Gd on RbLn2Fe4As4O2 is indeed different from that of Tb and Dy, and the presence of Gd is more conducive to interlayer electron transfer. This means that Gd can transfer more electrons from the GdO layer to the FeAs layer compared to Tb and Dy. Therefore, RbGd2Fe4As4O2 has a stronger internal coupling strength of the bilayer Fe2As2 layer. This can explain why the Tc of RbGd2Fe4As4O2 is slightly higher than that of RbTb2Fe4As4O2 and RbDy2Fe4As4O2.

Improving the Shape Memory Effect of a Fe-Mn-Si-Cr-Ni Alloy through Shot Peening.

To improve the shape memory effect, the solutionized Fe-24Mn-6Si-9Cr-6Ni alloy was shot peened and subsequently annealed. The phase constituent was examined using the X-ray diffraction method. Microstructure evolution was characterized using an optical microscope and the electronic backscatter diffraction method, and the shape memory effect was evaluated using a bending test. The results show that α'-martensite and ε-martensite were introduced into the shot-peened surface layer. The α'-martensite remained after annealing even at 850 °C. Microstructure of the surface layer was refined through shot peening and subsequent annealing. Compared with those of the solutionized specimen, the shape recovery ratio and recovery strain of the specimens that are shot peened and subsequently annealed are significantly improved at different prestrains.

Influence of the Mechanical Properties of Elastoplastic Materials on the Nanoindentation Loading Response.

The nanoindentation loading response of elastoplastic materials was simulated by the finite element method (FEM). The influence of the Young's modulus E, yield stress σy, strain hardening exponent n and Poisson's ratio ν on the loading response was investigated. Based on an equivalent model, an equation with physical meaning was proposed to quantitatively describe the influence. The calculations agree well with the FEM simulations and experimental results in literature. Comparisons with the predictions using equations in the literature also show the reliability of the proposed equation. The investigations show that the loading curvature C increases with increasing E, σy, n and ν. The increase rates of C with E, σy, n and ν are different for their different influences on the flow stress after yielding. It is also found that the influence of one of the four mechanical parameters on C can be affected by the other mechanical parameters.

Hierarchical core-shell CoMn2O4@MnO2 nanoneedle arrays for high-performance supercapacitors.

Hierarchical mesoporous core-shell CoMn2O4@MnO2 nanoneedle arrays on nickel foam have been manufactured via a two-step hydrothermal process. Electrochemical performances of the CoMn2O4@MnO2 nanomaterials have been tested for supercapacitors and demonstrated outstanding properties. The CoMn2O4@MnO2 electrode delivers a specific capacitance of 2126 F g-1 at a current density of 1 A g-1 in 2 M KOH aqueous solution and also shows an excellent cycling stability, which retains 94.4% of the initial capacitance after 5000 charge/discharge cycles at a current density of 4 A g-1. The result confirms the superiority of the CoMn2O4@MnO2 electrode compared with the CoMn2O4 electrode and demonstrates the potential application of the CoMn2O4@MnO2 nanoneedle array electrode for high-performance energy storage device applications.

Preparation of supercapacitor electrodes through selection of graphene surface functionalities.

In order to investigate the effect of graphene surface chemistry on the electrochemical performance of graphene/polyaniline composites as supercapacitor electrodes, graphene oxide (G-O), chemically reduced G-O (RG-O), nitrogen-doped RG-O (N-RG-O), and amine-modified RG-O (NH(2)-RG-O) were selected as carriers and loaded with about 9 wt % of polyaniline (PANi). The surface chemistry of these materials was analyzed by FTIR, NEXAFS, and XPS, and the type of surface chemistry was found to be important for growth of PANi that influences the magnitude of increase of specific capacitance. The NH(2)-RG-O/PANi composite exhibited the largest increase in capacitance with a value as high as 500 F g(-1) and good cyclability with no loss of capacitance over 680 cycles, much better than that of RG-O/PANi, N-RG-O/PANi, and G-O/PANi when measured in a three-electrode system. A NH(2)-RG-O/PANi//N-RG-O supercapacitor cell has a capacitance of 79 F g(-1), and the corresponding specific capacitance for NH(2)-RG-O/PANi is 395 F g(-1). This research highlights the importance of introducing -NH(2) to RG-O to achieve highly stable cycling performance and high capacitance values.

Influences of graphene oxide support on the electrochemical performances of graphene oxide-MnO2 nanocomposites.

MnO2 supported on graphene oxide (GO) made from different graphite materials has been synthesized and further investigated as electrode materials for supercapacitors. The structure and morphology of MnO2-GO nanocomposites are characterized by X-ray diffraction, X-ray photoemission spectroscopy, scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and Nitrogen adsorption-desorption. As demonstrated, the GO fabricated from commercial expanded graphite (denoted as GO(1)) possesses more functional groups and larger interplane gap compared to the GO from commercial graphite powder (denoted as GO(2)). The surface area and functionalities of GO have significant effects on the morphology and electrochemical activity of MnO2, which lead to the fact that the loading amount of MnO2 on GO(1) is much higher than that on GO(2). Elemental analysis performed via inductively coupled plasma optical emission spectroscopy confirmed higher amounts of MnO2 loading on GO(1). As the electrode of supercapacitor, MnO2-GO(1) nanocomposites show larger capacitance (307.7 F g-1) and better electrochemical activity than MnO2-GO(2) possibly due to the high loading, good uniformity, and homogeneous distribution of MnO2 on GO(1) support.

Fabrication of Co3O4-reduced graphene oxide scrolls for high-performance supercapacitor electrodes.

A new type of scrolled structure of Co(3)O(4)/reduced graphene oxide (r-GO) is facilely prepared through a two-step surfactant-assisted method. This assembly enables almost every single Co(3)O(4) scroll to connect with the r-GO platelets, thus leading to remarkable electrochemical performances in terms of high specific capacitance and good rate capability.

Metal hydroxide and metal oxide nanostructures from metal corrosion.

Unique metal hydroxide (Co(OH)2 and Mg(OH)2) and metal oxide (Co3O4 and MgO) nanosheet arrays have been successfully achieved on a large scale by simple metal corrosion process in deionized water at room temperature. The X-ray diffraction (XRD) and micro-Raman scattering investigations reveal the crystalline feature of the resulted nanosheets. The magnesium based nanosheet exhibits strong visible photoluminescence (PL) emission. The water wettability of cobalt based nanosheet has also been studied.