Event-triggered prescribed-time control for a class of uncertain nonlinear systems using finite time-varying gain.

This paper addresses the event-triggered prescribed-time control problem for a class of high-order nonlinear systems based on finite time-varying gain. Due to the existence of unknown gain functions and system uncertainties, the resultant control with prescribed-time convergence performance becomes nontrivial. The problem becomes even more complex due to the use of event-based communication instead of continuous communication. To tackle the aforementioned challenges, this paper proposes an event-triggered prescribed-time stabilization approach with the following key steps. Firstly, we establish a new prescribed-time stability lemma to overcome the technical difficulty arising from the prescribed-time controller design, and stability analysis. Secondly, we give the controller design procedure upon using the backstepping technique. Thirdly, we redesign the event-triggering threshold condition based on time-varying functions, which allows the controller terminal jitter to be mitigated and the controller to be implemented straightforwardly in practice. Furthermore, the proposed control scheme avoids Zeno behavior. The numerical simulation confirms the effectiveness of the proposed control scheme.

Can stable carbon isotope fingerprints be competent for geographic traceability of rice?

This study aimed to improve the traceability of rice-producing areas to address the increasing demand for accurate methods to confirm food quality and safety. Compound-specific δ13C of fatty acids, δ13C of starch and bulk of rice were measured. PCA, PLS-DA and VIP value analysis of the obtained data were performed to track the source of rice from the six regions. The PLS-DA model established with bulk δ13C, starch δ13C, and fatty acid δ13C, which clearly separated the rice from six regions. The VIP graph showed the value of starch, C18:0 and C18:2 δ13C values (VIP > 1) were important to distinguish the origin of rice. Also, according to loading plots the contribution of starch δ13C was the largest. The findings indicate that the introduction of starch δ13C improves the precision of rice traceability and provides an effective method for identifying rice origin.

The interplay of motor adaptation and groupitizing in numerosity perception: Insights from visual motion adaptation and proprioceptive motor adaptation.

Groupitizing is a well-established strategy in numerosity perception that enhances speed and sensory precision. Building on the ATOM theory, Anobile proposed the sensorimotor numerosity system, which posits a strong link between number and action. Previous studies using motor adaptation technology have shown that high-frequency motor adaptation leads to underestimation of numerosity perception, while low-frequency adaptation leads to overestimation. However, the impact of motor adaptation on groupitizing, and whether visual motion adaptation produces similar effects, remain unclear. In this study, we investigate the persistence of the advantage of groupitizing after motor adaptation and explore the effects of visual motion adaptation. Surprisingly, our findings reveal that proprioceptive motor adaptation weakens the advantage of groupitizing, indicating a robust effect of motor adaptation even when groupitizing is employed. Moreover, we observe a bidirectional relationship, as groupitizing also weakens the adaptation effect. These results highlight the complex interplay between motor adaptation and groupitizing in numerosity perception. Furthermore, our study provides evidence that visual motion adaptation also has an adaptation effect, but does not fully replicate the effects of proprioceptive motor adaptation on groupitizing. In conclusion, our research underscores the importance of groupitizing as a valuable strategy in numerosity perception, and sheds light on the influence of motion adaptation on this strategy.

Disclosing the effect of exogenous betaine on growth of Suaeda salsa (L.) Pall in the Liaohe coastal wetland, North China.

Liaohe coastal wetland has experienced severe degradation of Suaeda salsa (L.) Pall (S. salsa) in recent years. However, the impact of exogenous betaine (GB) on S. salsa growth remains unclear. Therefore, we conducted a natural simulated cultivation in soils of coastal wetland to investigate the effects of GB on S. salsa growth. The results showed that GB increased the height and weight of S. salsa, and meanwhile stimulated the synthesis of endogenous betaine and amino acids, increased soluble sugars and elevated the activity of Na+, K+-ATPase (enhancing osmotic stability). In addition, the activities of superoxide dismutase (SOD), peroxidase (POD), and catalase (CAT) increased, and malondialdehyde (MDA) and H2O2 decreased correspondingly, thereby improving the antioxidant capacity. Overall, GB application significantly alleviated salt stress and effectively promoted S. salsa growth. This study first indicated the important role of GB in influencing S. salsa growth, offering potential strategies for remediation in coastal wetlands.

Comparison of Magnetic Deflection among Neutral Sodium-Doped Clusters: Na(H2O)n, Na(NH3)n, Na(MeOH)n, and Na(DME)n.

Using a pulsed Stern-Gerlach deflection experiment, we present the results of a comparative study on the magnetic properties of neutral sodium-doped solvent clusters Na(Sol)n with n = 1-4 (Sol: H2O, NH3, CH3OH, CH3OCH3). Experimental deflection ratios are compared with values calculated from molecular dynamics simulations. NaNH3 and NaH2O are deflected as a spin 1/2 system, consistent with spin transitions occurring on a time scale significantly longer than 100 µs. For all other clusters, reduced deflection is observed. The observed magnetic deflection behavior is correlated to the number of thermally populated rotational states in the clusters. We discuss that spin-rotational couplings allow for avoided crossings and a reduction in the effective magnetic moment of the cluster. This work attempts to understand the evolution of magnetic properties in isolated weakly bound clusters and is relevant to diamagnetic and paramagnetic species expected to exist in solvated electron systems.

A Novel Smart CFRP Cable Based on Optical Electrical Co-Sensing for Full-Process Prestress Monitoring of Structures.

Carbon-fiber-reinforced polymer (CFRP) is a type of composite material with many superior performances, such as high tensile strength, light weight, corrosion resistance, good fatigue, and creep performance. As a result, CFRP cables have great potential to replace steel cables in prestressed concrete structures. However, the technology to monitor the stress state in real-time throughout the entire life cycle is very important in the application of CFRP cables. Therefore, an optical-electrical co-sensing CFRP cable (OECSCFRP cable) was designed and manufactured in this paper. Firstly, a brief description is outlined for the production technology of the CFRP-DOFS bar, CFRP-CCFPI bar, and CFRP cable anchorage technology. Subsequently, the sensing and mechanical properties of the OECS-CFRP cable were characterized by serious experiments. Finally, the OECS-CFRP cable was used for the prestress monitoring of an unbonded prestressed RC beam to verify the feasibility of the actual structure. The results show that the main static performance indexes of DOFS and CCFPI meet the requirements of civil engineering. In the loading test of the prestressed beam, the OECS-CFRP cable can effectively monitor the cable force and the midspan defection of the beam so as to obtain the stiffness degradation of the prestressed beam under different loads.

Displacement Monitoring of a Bridge Based on BDS Measurement by CEEMDAN-Adaptive Threshold Wavelet Method.

From the viewpoint of BDS bridge displacement monitoring, which is easily affected by background noise and the calculation of a fixed threshold value in the wavelet filtering algorithm, which is often related to the data length. In this paper, a data processing method of Complete Ensemble Empirical Mode Decomposition with Adaptive Noise (CEEMDAN), combined with adaptive threshold wavelet de-noising is proposed. The adaptive threshold wavelet filtering method composed of the mean and variance of wavelet coefficients of each layer is used to de-noise the BDS displacement monitoring data. CEEMDAN was used to decompose the displacement response data of the bridge to obtain the intrinsic mode function (IMF). Correlation coefficients were used to distinguish the noisy component from the effective component, and the adaptive threshold wavelet de-noising occurred on the noisy component. Finally, all IMF were restructured. The simulation experiment and the BDS displacement monitoring data of Nanmao Bridge were verified. The results demonstrated that the proposed method could effectively suppress random noise and multipath noise, and effectively obtain the real response of bridge displacement.

Related consistent lures increase the judgment of multiplication facts: Evidence using event-related potential technique.

Simple multiplication errors are primarily shown in whether the lures are related to the operands (relatedness, such as 3 × 4 = 15 vs. 17) or whether the same decades are shared with the correct answers (consistency, such as 3 × 4 = 16 vs. 21). This study used a delayed verification paradigm and event-related potential technique to investigate the effects of relatedness and consistency in simple multiplication mental arithmetic for 30 college students in an experiment of presenting probes in auditory channels. We found that, compared to the related inconsistent lures, the related consistent lures showed significantly faster reaction time and induced significantly large amplitudes of N400 and late positive component. The findings suggest that related consistent lures are less affected by the activation diffusion of the arithmetic problem, and the credibility of being perceived as the correct answer is less; the lures related to operands and sharing the same decades with the accurate results can promote the judgment of multiplication mental arithmetic, and the results support the Interacting Neighbors Model.

Orcinol and resorcinol induce local ordering of water molecules near the liquid-vapor interface.

Resorcinol and orcinol are simple members of the family of phenolic compounds present in particulate matter in the atmosphere; they are amphiphilic in nature and thus surface active in aqueous solution. Here, we used X-ray photoelectron spectroscopy to probe the concentration of resorcinol (benzene-1,3-diol) and orcinol (5-methylbenzene-1,3-diol) at the liquid-vapor interface of aqueous solutions. Qualitatively consistent surface propensity and preferential orientation was obtained by molecular dynamics simulations. Auger electron yield near-edge X-ray absorption fine structure (NEXAFS) spectroscopy was used to probe the hydrogen bonding (HB) structure, indicating that the local structure of water molecules near the surface of the resorcinol and orcinol solutions tends towards a larger fraction of tetrahedrally coordinated molecules than observed at the liquid-vapor interface of pure water. The order parameter obtained from the molecular dynamics simulations confirm these observations. This effect is being discussed in terms of the formation of an ordered structure of these molecules at the surface leading to patterns of hydrated OH groups with distances among them that are relatively close to those in ice. These results suggest that the self-assembly of phenolic species at the aqueous solution-air interface could induce freezing similar to the case of fatty alcohol monolayers and, thus, be of relevance for ice nucleation in the atmosphere. We also attempted at looking at the changes of the O 1b1, 3a2 and 1b2 molecular orbitals of liquid water, which are known to be sensitive to the HB structure as well, in response to the presence of resorcinol and orcinol. However, these changes remained negligible within uncertainty for both experimentally obtained valence spectra and theoretically calculated density of states.

Reply to "Comment on 'Liquid-Gas Interface of Iron Aqueous Solutions and Fenton Reagents'".

A Viewpoint regarding our recently published Letter in this Journal (Gladich et al. J. Phys. Chem. Lett. 13, 2994-3001) criticizes some of our conclusions. While a sentence in the abstract and one in the conclusion of the Letter might seem too conclusive, in the body text we objectively discussed experimental results obtained by means of three different surface-/interface-sensitive spectroscopies. Such results were supported by theoretical calculations. The aim of our work was not to criticize past results. On the contrary, we critically discussed our data taking into account those obtained in the past.

Ice nucleation imaged with X-ray spectro-microscopy.

Ice nucleation is one of the most uncertain microphysical processes, as it occurs in various ways and on many types of particles. To overcome this challenge, we present a heterogeneous ice nucleation study on deposition ice nucleation and immersion freezing in a novel cryogenic X-ray experiment with the capability to spectroscopically probe individual ice nucleating and non-ice nucleating particles. Mineral dust type particles composed of either ferrihydrite or feldspar were used and mixed with organic matter of either citric acid or xanthan gum. We observed in situ ice nucleation using scanning transmission X-ray microscopy (STXM) and identified unique organic carbon functionalities and iron oxidation state using near-edge X-ray absorption fine structure (NEXAFS) spectroscopy in the new in situ environmental ice cell, termed the ice nucleation X-ray cell (INXCell). Deposition ice nucleation of ferrihydrite occurred at a relative humidity with respect to ice, RH i, between ∼120-138% and temperatures, T ∼ 232 K. However, we also observed water uptake on ferrihydrite at the same T when deposition ice nucleation did not occur. Although, immersion freezing of ferrihydrite both in pure water droplets and in aqueous citric acid occurred at or slightly below conditions for homogeneous freezing, i.e. the effect of ferrihydrite particles acting as a heterogeneous ice nucleus for immersion freezing was small. Microcline K-rich feldspar mixed with xanthan gum was also used in INXCell experiments. Deposition ice nucleation occurred at conditions when xanthan gum was expected to be highly viscous (glassy). At less viscous conditions, immersion freezing was observed. We extended a model for heterogeneous and homogeneous ice nucleation, named the stochastic freezing model (SFM). It was used to quantify heterogeneous ice nucleation rate coefficients, mimic the competition between homogeneous ice nucleation; water uptake; deposition ice nucleation and immersion freezing, and predict the T and RH i at which ice was observed. The importance of ferrihydrite to act as a heterogeneous ice nucleating particle in the atmosphere using the SFM is discussed.

Enhancing Photodynamic Therapy Efficacy Against Cancer Metastasis by Ultrasound-Mediated Oxygen Microbubble Destruction to Boost Tumor-Targeted Delivery of Oxygen and Renal-Clearable Photosensitizer Micelles.

Hypoxic tumor microenvironment and nonspecific accumulation of photosensitizers are two key factors that limit the efficacy of photodynamic therapy (PDT). Herein, a strategy of oxygen microbubbles (MBs) boosting photosensitizer micelles is developed to enhance PDT efficacy and inhibit tumor metastasis by self-assembling renal-clearable ultrasmall poly(ethylene glycol)-modified protoporphyrin IX micelles (PPM) and perfluoropentane (PFP)-doped oxygen microbubbles (OPMBs), followed by ultrasound imaging-guided OPMB destruction to realize the tumor-targeted delivery of PPM and oxygen in tumor. Doping PFP into oxygen MBs increases the production of MBs and stability of oxygen MBs, allowing for persistent circulation in blood. Following co-injection, destruction of OPMBs with ultrasound leads to ∼2.2-fold increase of tumor-specific PPM accumulation. Furthermore, the burst release of oxygen by MB destruction improves tumor oxygenation from 22 to 50%, which not only raises the production of singlet oxygen but also significantly reduces the expression of hypoxia-inducible factor-1 alpha and related genes, thus preventing angiogenesis and epithelial-mesenchymal transition. It is verified that this strategy effectively eradicates orthotopic breast cancer and inhibits lung metastasis. Furthermore, the survival rate of mice bearing orthotopic pancreatic tumor is significantly extended by such interventional PDT strategy. Therefore, the combination of ultrasmall PPM and OPMBs represents a simple but effective strategy in overcoming the limitations of PDT.

Liquid-Gas Interface of Iron Aqueous Solutions and Fenton Reagents.

Fenton chemistry, involving the reaction between Fe2+ and hydrogen peroxide, is well-known due to its applications in the mineralization of extremely stable molecules. Different mechanisms, influenced by the reaction conditions and the solvation sphere of iron ions, influence the fate of such reactions. Despite the huge amount of effort spent investigating such processes, a complete understanding is still lacking. This work combines photoelectron spectroscopy and theoretical calculations to investigate the solvation and reactivity of Fe2+ and Fe3+ ions in aqueous solutions. The reaction with hydrogen peroxide, both in homogeneous Fenton reagents and at the liquid-vapor interface, illustrates that both ions are homogeneously distributed in solutions and exhibit an asymmetric octahedral coordination to water in the case of Fe2+. No indications of differences in the reaction mechanism between the liquid-vapor interface and the bulk of the solutions have been found, suggesting that Fe3+ and hydroxyl radicals are the only intermediates.

Colorimetric quantification of sodium benzoate in food by using d-amino acid oxidase and 2D metal organic framework nanosheets mediated cascade enzyme reactions.

A rapid colorimetric method for detecting sodium benzoate in food products was established based on the d-amino acid oxidase (DAAO) and 2D metal organic framework (2D MOF) nanosheets mediated cascade enzyme reactions. Firstly, the synthesized 2D MOF nanosheets served as high efficient nanozyme with outstanding peroxidase-like catalytic activity and catalyzed the color reaction between H2O2 and 3, 3', 5, 5'- tetramethylbenzidine. Secondly, sodium benzoate as a competitive inhibitor of DAAO, could influence the production of H2O2 in DAAO mediated oxidation reaction. After a combination of those two reactions, this colorimetric quantitative method was constructed and validated for sodium benzoate determination with wide linear range (2.0-200.0 µM), low limit of detection (2.0 µM), high accuracy (recovery rate in 95.80-108.00%) and satisfied selectivity. Lastly, this method was utilized to analyze sodium benzoate concentration in juice, wine and vinegar by naked eyes.

Ultrasmall Au nanoparticles modified 2D metalloporphyrinic metal-organic framework nanosheets with high peroxidase-like activity for colorimetric detection of organophosphorus pesticides.

Ultrasmall Au nanoparticles (UsAuNPs) in the size range of 4.0-7.0 nm was successfully immobilized on the surface of 2D metalloporphyrinic metal-organic framework nanosheets (2D MOF). Firstly, The obtained hybrid nanomaterial, UsAuNPs/2D MOF, was fully characterized by TEM, HRTEM, element mapping images and XPS. Then, the peroxidase-like activity of UsAuNPs/2D MOF was comparatively studied with other hybrid nanozyme to explore the influence of AuNPs size on peroxidase-like activity. Further, UsAuNPs/2D MOF with outstanding peroxidase-like activity was selected to form ternary cascade enzyme reaction with acetylcholinesterase (AChE) and choline oxidase (ChOx). Based on the inhibitory effect of organophosphorus pesticides on AChE, a fast and sensitive colorimetric method was established for trichlorfon detection with the advantages of simple operation, low detection limit (1.7 µM), good linear range (1.7-42.4 µM) and high accuracy (recovery rate of 96.6-105.3%). Finally, this method was applied to visual analysis of trichlorfon concentration in tomatoes, cucumbers and eggplants.

Impact of Tetrabutylammonium on the Oxidation of Bromide by Ozone.

The reaction of ozone with sea-salt derived bromide is relevant for marine boundary layer atmospheric chemistry. The oxidation of bromide by ozone is enhanced at aqueous interfaces. Ocean surface water and sea spray aerosol are enriched in organic compounds, which may also have a significant effect on this reaction at the interface. Here, we assess the surface propensity of cationic tetrabutylammonium at the aqueous liquid-vapor interface by liquid microjet X-ray photoelectron spectroscopy (XPS) and the effect of this surfactant on ozone uptake to aqueous bromide solutions. The results clearly indicate that the positively charged nitrogen group in tetrabutylammonium (TBA), along with its surface activity, leads to an enhanced interfacial concentration of both bromide and the bromide ozonide reaction intermediate. In parallel, off-line kinetic experiments for the same system demonstrate a strongly enhanced ozone loss rate in the presence of TBA, which is attributed to an enhanced surface reaction rate. We used liquid jet XPS to obtain detailed chemical composition information from the aqueous-solution-vapor interface of mixed aqueous solutions containing bromide or bromide and chloride with and without TBA surfactant. Core level spectra of Br 3d, C 1s, Cl 2p, N 1s, and O 1s were used for this comparison. A model was developed to account for the attenuation of photoelectrons by the carbon-rich layer established by the TBA surfactant. We observed that the interfacial density of bromide is increased by an order of magnitude in solutions with TBA. The salting-out of TBA in the presence of 0.55 M sodium chloride is apparent. The increased interfacial bromide density can be rationalized by the association constants for bromide and chloride to form ion-pairs with TBA. Still, the interfacial reactivity is not increasing simply proportionally with the increasing interfacial bromide concentration in response to the presence of TBA. The steady state concentration of the bromide ozonide intermediate increases by a smaller degree, and the lifetime of the intermediate is 1 order of magnitude longer in the presence of TBA. Thus, the influence of cationic surfactants on the reactivity of bromide depends on the details of the complex environment at the interface.

Grouping strategies in numerosity perception between intrinsic and extrinsic grouping cues.

The number of items in an array can be quickly and accurately estimated by dividing the array into subgroups, in a strategy termed "groupitizing." For example, when memorizing a telephone number, it is better to do so by divide the number into several segments. Different forms of visual grouping can affect the precision of the enumeration of a large set of items. Previous studies have found that when groupitizing, enumeration precision is improved by grouping arrays using visual proximity and color similarity. Based on Gestalt theory, Palmer (Cognit Psychol 24:436, 1992) divided perceptual grouping into intrinsic (e.g., proximity, similarity) and extrinsic (e.g., connectedness, common region) principles. Studies have investigated groupitizing effects on intrinsic grouping. However, to the best of our knowledge, no study has explored groupitizing effects for extrinsic grouping cues. Therefore, this study explored whether extrinsic grouping cues differed from intrinsic grouping cues for groupitizing effects in numerosity perception. The results showed that both extrinsic and intrinsic grouping cues improved enumeration precision. However, extrinsic grouping was more accurate in terms of the sensory precision of the numerosity perception.

Photosensitizer Nanoparticles Boost Photodynamic Therapy for Pancreatic Cancer Treatment.

Patients with pancreatic cancer (PCa) have a poor prognosis apart from the few suitable for surgery. Photodynamic therapy (PDT) is a minimally invasive treatment modality whose efficacy and safety in treating unresectable localized PCa have been corroborated in clinic. Yet, it suffers from certain limitations during clinical exploitation, including insufficient photosensitizers (PSs) delivery, tumor-oxygenation dependency, and treatment escape of aggressive tumors. To overcome these obstacles, an increasing number of researchers are currently on a quest to develop photosensitizer nanoparticles (NPs) by the use of a variety of nanocarrier systems to improve cellular uptake and biodistribution of photosensitizers. Encapsulation of PSs with NPs endows them significantly higher accumulation within PCa tumors due to the increased solubility and stability in blood circulation. A number of approaches have been explored to produce NPs co-delivering multi-agents affording PDT-based synergistic therapies for improved response rates and durability of response after treatment. This review provides an overview of available data regarding the design, methodology, and oncological outcome of the innovative NPs-based PDT of PCa.

Effects of excessive nitrogen on nitrogen uptake and transformation in the wetland soils of Liaohe estuary, northeast China.

It remains unclear whether excessive nitrogen additions lead to the degradation of Suaeda salsa (S. salsa) by affecting the nitrogen pool, enzyme activities, and bacterial community structure of wetland soils. This study investigated the effect of five added nitrogen concentrations (0, 1, 2, 4, and 6 mmol L-1 N with NH4NO3 = group C, group L, group M, group H, and group G, respectively) on nitrogen uptake by S. salsa and nitrogen transformation in the wetland soils of the Liaohe estuary. The height, weight, and total nitrogen (TN) of S. salsa in group G was significantly lower than in the other groups (p <0.05). The NH4+-N concentration in the soil tended to increase with increasing nitrogen addition, but the TN concentration in the soil tended to decrease. The nitrogenase, protease, urease, ammonia monooxygenase (AMO), nitrous oxide reductase (NOR), and dehydrogenase (DHA) activities increased with increasing nitrogen addition within the range of 0 to 4 mmol L-1. We identified 30 phyla and 48 known genera across all five groups. The predominant phyla were Proteobacteria (52.68%), Bacteroidetes (22.58%), and Planctomycetes (3.94%). The most abundant genus was Acinetobacter (13.38%), followed by Proteiniphilum (11.88%) and Brevundimonas (6.03%). The total number of soil bacterial species increased with increasing nitrogen addition. Group G had lower soil bacterial activity and diversity than the other groups. It was concluded that appropriate levels of nitrogen addition could promote nitrogen uptake by S. salsa and nitrogen transformation in the wetland soils of the Liaohe estuary by affecting soil enzyme activities and soil bacterial activity, diversity, abundance, and composition, while excessive nitrogen additions may be one of the reasons for the degradation of S. salsa.

Joining of Silicon Particle-Reinforced Aluminum Matrix Composites to Kovar Alloys Using Active Melt-Spun Ribbons in Vacuum Conditions.

The vacuum brazing of dissimilar electronic packaging materials has been investigated. In this research, this applies silicon particle-reinforced aluminum matrix composites (Sip/Al MMCs) to Kovar alloys. Active melt-spun ribbons were employed as brazing filler metals under different joining temperatures and times. The results showed that the maximum joint shear strength of 96.62 MPa was achieved when the joint was made using Al-7.5Si-23.0Cu-2.0Ni-1.0Ti as the brazing filler metal at 580 °C for 30 min. X-ray diffraction (XRD) analysis of the joint indicated that the main phases were composed of Al, Si and intermetallics, including CuAl, TiFeSi, TiNiSi and Al3Ti. When the brazing temperature ranged from 570 °C to 590 °C, the leakage rate of joints remained at 10-8 Pa·m3/s or better. When the joint was made using Al-7.5Si-23.0Cu-2.0Ni-2.5Ti as the brazing filler metal at 580 °C for 30 min, the higher level of Ti content in the brazing filler metal resulted in the formation of a flake-like Ti(AlSi)3 intermetallic phase with an average size of 7 µm at the interface between the brazing seam and Sip/Al MMCs. The joint fracture was generally in the form of quasi-cleavage fracture, which primarily occurred at the interface between the filler metal and the Sip/Al MMCs. The micro-crack propagated not only Ti(AlSi)3, but also the Si particles in the substrate.