Analysis of optical propagation characteristics of the ultra-long period grating using RCWA.

There have been significant research and analyses on the diffraction efficiency and characteristics of spectral grating with a wavelength-scale period. However, thus far an analysis on a diffraction grating with an ultra-long pitch over several hundred times of the wavelength (>100µm) and a very deep groove over dozens of micrometers has not been performed. We analyzed the diffraction efficiency of these gratings by using the rigorous coupled-wave analysis (RCWA) method and confirmed that the RCWA analytic results correspond well to the actual experimental results on the wide-angle beam-spreading phenomenon. In addition, because a long-period grating with a deep groove results in a small diffraction angle with relatively uniform efficiency, it is possible to convert a point-like distribution to a linear distribution for a short working distance and a discrete distribution for a very long working distance. We believe that a wide-angle line laser with a long grating period can be used in various applications, such as level detectors, precision measurements, multi-point light detecting and ranging (LiDAR) light sources, and security systems.

Light-to-Hydrogen Improvement Based on Three-Factored Au@CeO2/Gr Hierarchical Photocatalysts.

Recently, various attempts have been made for light-to-fuels conversion, often with limited performance. Herein we report active and lasting three-factored hierarchical photocatalysts consisting of plasmon Au, ceria semiconductor, and graphene conductor for hydrogen production. The Au@CeO2/Gr2.0 entity (graphene outer shell thickness of 2.0 nm) under visible-light irradiation exhibits a colossal achievement (8.0 µmol mgcat-1 h-1), which is 2.2- and 14.3-fold higher than those of binary Au@CeO2 and free-standing CeO2 species, outperforming the currently available catalysts. Yet, it delivers a high maximum quantum yield efficiency of 38.4% at an incident wavelength of 560 nm. These improvements are unambiguously attributed to three indispensable effects: (1) the plasmon resonant energy is light-excited and transferred to produce hot electrons localizing near the surface of Au@CeO2, where (2) the high-surface-area Gr conductive shell will capture them to direct hydrogen evolution reactions, and (3) the active graphene hybridized on the defect-rich surface of Au@CeO2 favorably adsorbs hydrogen atoms, which all bring up thorough insight into the working of a ternary Au@CeO2/Gr catalyst system in terms of light-to-hydrogen conversion.

Directional coupling of surface plasmon polaritons at complementary split-ring resonators.

We propose a complementary split-ring resonator (CSRR) for a directional coupling of surface plasmon polaritons. An air-slot split-ring in a gold film is investigated using the finite-difference time-domain method. The normally incident light couples to either a monopole or a dipole SPP depending on the polarization of light. Adjusting the angle of the linear polarization of the incident light enables a one-way propagation of SPPs on the gold film. Theoretical analysis based on the propagation of cylindrical waves from the SPP point source is provided with Hankel function. The propagated power in one direction is obtained to be 30 times higher than the opposite direction with a coupling efficiency of 18.2% from the simulation for an array of the CSRRs. This approach to the directional coupling of SPPs will be advantageous for miniaturizing photonic and plasmonic circuits and devices.

High refractive index metamaterials using corrugated metallic slots.

We report on a method for realizing high refractive index metamaterials using corrugated metallic slot structures at terahertz frequencies. The effective refractive index and peak index frequency can be controlled by varying the width of the air gap in the corrugated slot arrays. The phenomenon occurs because of the secondary resonance effect due to the fundamental inductive-capacitive resonance, which generates a red-shift of the fundamental resonance determined by twice the length of the corrugated metallic slots. In addition, multiple gaps in the corrugated slots act as plasmonic hotspots which have the properties of three-dimensional subwavelength confinement due to extremely strong enhancement of the terahertz waves. The versatile characteristics of the structures may have many potential applications in designing compact optical devices incorporating various functionalities and in developing highly sensitive spectroscopic/imaging systems.

Morphological and SERS Properties of Silver Nanorod Array Films Fabricated by Oblique Thermal Evaporation at Various Substrate Temperatures.

Aligned silver nanorod (AgNR) array films were fabricated by oblique thermal evaporation. The substrate temperature during evaporation was varied from 10 to 100 °C using a home-built water cooling system. Deposition angle and substrate temperature were found to be the most important parameters for the morphology of fabricated films. Especially, it was found that there exists a critical temperature at ~90 °C for the formation of the AgNR array. The highest enhancement factor of the surface-enhanced Raman scattering (SERS), observed in the Ag films coated with benzenethiol monolayer, was ~6 × 10(7). Hot spots, excited in narrow gaps between nanorods, were attributed to the huge enhancement factor by our finite-difference time-domain (FDTD) simulation reflecting the real morphology.

Device performance of inverted polymer solar cells with AgSiO(2) nanoparticles in active layer.

Localized surface plasmon mediated polymer solar cells (PSCs) were fabricated using the Ag/SiO(2) nanoparticles (NPs). The inverted PSC structure without poly (3,4-ethylenedioxythiophene) polystyrene sulfonate ( PEDOT: PSS) was prepared due to the efficient insertion of Ag/SiO(2) NPs in the vicinity of active layer, which led to an enhancement in photo-conversion efficiency (PCE). This enhancement mainly comes from the light scattering by the SiO(2) shell and the localized surface plasmon effect by the Ag core, but we also considered the structural issues such as the NP distribution, the swelling of the active layer and of the metal electrode.

Monopole resonators in planar plasmonic metamaterials.

We first present a new phenomenon: the quarter-wavelength resonance of an electromagnetic field in planar plasmonic metamaterials consisting of asymmetrically coupled air-slot arrays, which is essential for a monopole resonator. The anti-nodal electric field intensity of the quarter-wavelength fundamental mode is formed by strong charge concentrations at the sharp metallic edges of the crossing position of the air-slots, and the nodal point of the electric field intensity naturally occurs at the other end of the air-slot. By tuning the structural asymmetry, the quarter-wavelength resonances were successfully split from the half-wavelength resonance, experimentally and numerically.

Plantar Pressure Distribution During Robotic-Assisted Gait in Post-stroke Hemiplegic Patients.

OBJECTIVE: To assess the plantar pressure distribution during the robotic-assisted walking, guided through normal symmetrical hip and knee physiological kinematic trajectories, with unassisted walking in post-stroke hemiplegic patients. METHODS: Fifteen hemiplegic stroke patients, who were able to walk a minimum of ten meters independently but with asymmetric gait patterns, were enrolled in this study. All the patients performed both the robotic-assisted walking (Lokomat) and the unassisted walking on the treadmill with the same body support in random order. The contact area, contact pressure, trajectory length of center of pressure (COP), temporal data on both limbs and asymmetric index of both limbs were obtained during both walking conditions, using the F-Scan in-shoe pressure measurement system. RESULTS: The contact area of midfoot and total foot on the affected side were significantly increased in robotic-assisted walking as compared to unassisted walking (p<0.01). The contact pressure of midfoot and total foot on affected limbs were also significantly increased in robotic-assisted walking (p<0.05). The anteroposterior and mediolateral trajectory length of COP were not significantly different between the two walking conditions, but their trajectory variability of COP was significantly improved (p<0.05). The asymmetric index of area, stance time, and swing time during robotic-assisted walking were statistically improved as compared with unassisted walking (p<0.05). CONCLUSION: The robotic-assisted walking may be helpful in improving the gait stability and symmetry, but not the physiologic ankle rocker function.

Localized surface plasmon enhanced quantum efficiency of InGaN/GaN quantum wells by Ag/SiO2 nanoparticles.

Optical properties of InGaN/GaN multi-quantum-well (MQW) structures with a nanolayer of Ag/SiO2 nanoparticle (NP) on top were studied. Modeling and optical absorption (OA) measurements prove that the NPs form localized surface plasmons (LSP) structure with a broad OA band peaked near 440-460 nm and the fringe electric field extending down to about 10 nm into the GaN layer. The presence of this NP LSP electrical field increases the photoluminescence (PL) intensity of the MQW structure by about 70% and markedly decreases the time-resolved PL (TRPL) relaxation time due to the strong coupling of MQW emission to the LSP mode.

Three-dimensional subwavelength confinement of terahertz electromagnetic surface modes in a coupled slit structure.

We report on the three-dimensional subwavelength confinement of the electromagnetic waves at a coupled metallic slit structure beyond diffraction limit in terahertz region. Lateral confinement behavior, leading to the three-dimensional confinement, is caused by a strong funneling effect of the light which occurs at the intersection of slits with a sharp metal geometry. Tunability of the resonant frequency and the position of the light confinement is achieved by controlling the slit length and the position of the intersection of slits, respectively.

Photonic network laser.

We demonstrated lasing in two-dimensional trivalent network structures with short-range order. Despite the lack of translational and rotational symmetries, such structures possess a large isotropic photonic bandgap. Different from those of a photonic crystal, the band-edge modes are spatially localized and have high quality factor.

Control of lasing in biomimetic structures with short-range order.

We demonstrate lasing in photonic amorphous structures that mimic the isotropic nanostructures which produce noniridescent color in nature. Our experimental and numerical studies reveal that lasing becomes most efficient at certain frequencies, due to enhanced optical confinement by short-range order. The optimal lasing frequency can be tuned by adjusting the structure factor. This work shows that lasing in nanostructures may be effectively improved and manipulated by short-range order.

Effective description of THz localized waveguide resonance through metal film with split ring resonator holes: zero refractive index.

Using a periodic array of split ring resonator holes within a terahertz range, we numerically and experimentally confirmed a zero refractive index at localized waveguide resonant frequency of aluminum film. The effective index was directly calculated from the phase difference of electromagnetic waves passing through film and air. Thickness-independent resonant frequency, as well as spatially static hole resonant modes, clearly verified a zero refractive index. For experimentation, we fabricated samples by means of a femtosecond laser machining system and employed a terahertz time domain spectroscopy system to measure transmitted terahertz pulses. Further, the effective index of refraction extracted from phases and amplitude of measured transmitted pulses confirmed a zero refraction index at resonant frequency.

Plasmon-suppressed vertically-standing nanometal structures.

The authors report plasmon-suppressed vertically-standing nanometal-stripe-array structures fabricated by Ar ion sputtering after electron-beam lithography and Ag deposition. When the width of the Ag stripe is comparable to the skin depth of a metal (~ 20 nm), the particle plasmon resonance is strongly suppressed for electric fields oscillating perpendicular to the length of the stripe. This suppression of the particle plasmon excitation is attributed to the limited movement of free electrons localized near the bottom of Ag stripe. This plasmon-suppressed vertically-standing nanometal structures could be used for broad band polarizers.

Controlled sub-nanometer tuning of photonic crystal resonator by carbonaceous nano-dots.

We propose and demonstrate a scheme that enables spectral tuning of a photonic crystal high-quality resonant mode, in steps finer than 0.2 nm, via electron beam induced deposition of carbonaceous nano-dots. The position and size of a nano-dot with a diameter of <100 nm are controlled to an accuracy on the order of nanometers. The possibility of selective modal tuning is also demonstrated by placing nano-dots at locations pre-determined by theoretical computation. The lasing threshold of a photonic crystal mode tends to increase when a nano-dot is grown at the point of strong electric field, showing the absorptive nature of the nano-dot.

Modal characteristics in a single-nanowire cavity with a triangular cross section.

In this study, the modal characteristics of a single-GaN nanowire cavity with a triangular cross section surrounded by air or located on a silicon dioxide substrate have been analyzed. Two transverse resonant modes, transverse electric-like and transverse magnetic-like modes, are dominantly excited for nanowire cavities that have a small cross-sectional size of <300 nm and length of 10 microm. Using the three-dimensional finite-difference time-domain simulation method, quality factors, confinement factors, single-mode conditions, and far-field emission patterns are investigated for a nanowire cavity as a function of one length of the triangular cross section. The results of these simulations provide information that will be vital for the design and development of efficient nanowire lasers and light sources in ultracompact nanophotonic integrated circuits.

Electrically driven single-cell photonic crystal laser.

We report the experimental demonstration of an electrically driven, single-mode, low threshold current (approximately 260 microA) photonic band gap laser operating at room temperature. The electrical current pulse is injected through a sub-micrometer-sized semiconductor wire at the center of the mode with minimal degradation of the quality factor. The actual mode of interest operates in a nondegenerate monopole mode, as evidenced through the comparison of the measurement with the computation based on the actual fabricated structural parameters. As a small step toward a thresholdless laser or a single photon source, this wavelength-size photonic crystal laser may be of interest to photonic crystals, cavity quantum electrodynamics, and quantum information communities.