Bearing Fault Diagnosis Method Based on RCMFDE-SPLR and Ocean Predator Algorithm Optimizing Support Vector Machine.

For the problem that rolling bearing fault characteristics are difficult to extract accurately and the fault diagnosis accuracy is not high, an unsupervised characteristic selection method of refined composite multiscale fluctuation-based dispersion entropy (RCMFDE) combined with self-paced learning and low-redundant regularization (SPLR) is proposed, for which the fault diagnosis is carried out by support vector machine (SVM) optimized by the marine predator algorithm (MPA). First, we extract the entropy characteristics of the bearings under different fault states by RCMFDE and the introduction of the fine composite multiscale coarse-grained method and fluctuation strategy improves the stability and estimation accuracy of the bearing characteristics; then, a novel dimensionality-reduction method, SPLR, is used to select better entropy characteristics, and the local flow structure of the fault characteristics is preserved and the redundancy is constrained by two regularization terms; finally, using the MPA-optimized SVM classifier by combining Levy motion and Eddy motion strategies, the preferred RCMFDE is fed into the MPA-SVM model for fault diagnosis, for which the obtained bearing fault diagnosis accuracy is 97.67%. The results show that the RCMFDE can effectively improve the stability and accuracy of the bearing characteristics, the SPLR-based low-dimensional characteristics can suppress the redundancy characteristics and improve the effectiveness of the characteristics, and the MPA-based adaptive SVM model solves the parameter randomness problem and, therefore, the proposed method has outstanding superiority.

Copper catalyzed borocarbonylation of benzylidenecyclopropanes through selective proximal C-C bond cleavage: synthesis of γ-boryl-γ,δ-unsaturated carbonyl compounds.

A copper catalyzed borocarbonylation of BCPs via proximal C-C bond cleavage for the synthesis of γ-boryl-γ,δ-unsaturated carbonyl compounds has been developed. Using substituted benzylidenecyclopropanes (BCPs) and chloroformates as starting material, a broad range of γ-boryl-γ,δ-unsaturated esters were prepared in moderate to excellent yields with excellent regio- and stereoselectivity. Besides, when aliphatic acid chlorides were used in this reaction, γ-boryl-γ,δ-unsaturated ketones could be produced in excellent yields. When substituted BCPs were used as substrates, the borocarbonylation occurred predominantly at the proximal C-C bond trans to the phenyl group in a regio- and stereoselective manner, which leads to the Z-isomers as the products. This efficient methodology involves the cleavage of a C-C bond and the formation of a C-C bond as well as a C-B bond, and provides a new method for the proximal C-C bond difunctionalization of BCPs.

Palladium Catalyzed Cascade Azidation/Carbonylation of Aryl Halides with Sodium Azide for the Synthesis of Amides.

Amide synthesis is one of the most important transformations in organic chemistry due to their ubiquitous presence in our daily life. In this communication, a palladium catalyzed cascade azidation/carbonylation of aryl halides for the synthesis of amides was developed. Both iodo- and bromobenzene derivatives were transformed to the corresponding amides using PdCl2 /xantphos as the catalyst system and sodium azide as the nitrogen-source. The reaction proceeds via a cascade azidation/carbonylation process. A range of alkyl and halogen substituted amides were prepared in moderate to good yields.