1.
Chem Commun (Camb)
; 50(40): 5355-7, 2014 May 25.
Article
in English
| MEDLINE
| ID: mdl-24413285
ABSTRACT
Measurements of photoinduced Fe(2+)-to-Ru(3+) electron transfer (ET), supported by theoretical analysis, demonstrate that mutations off the dominant ET pathways can strongly influence the redox reactivity of cytochrome c. The effects arise from the change in the protein dynamics mediated by the intraprotein hydrogen-bonding network.