ABSTRACT
Prestressed high-strength concrete (PHC) pipe pile with the static press-in method has been widely used in recent years. The generation and dissipation of excess pore water pressure at the pile-soil interface during pile jacking have an important influence on the pile's mechanical characteristics and bearing capacity. In addition, this can cause uncontrolled concrete damage. Monitoring the change in excess pore water pressure at the pile-soil interface during pile jacking is a plan that many researchers hope to implement. In this paper, field tests of two full-footjacked piles were carried out in a viscous soil foundation, the laws of generation and dissipation of excess pore water pressure at the pile-soil interface during pile jacking were monitored in real time, and the laws of variation in excess pore water pressure at the pile-soil interface with the burial depth and time were analyzed. As can be seen from the test results, the excess pore water pressure at the pile-soil interface increased to the peak and then began to decline, but the excess pore water pressure after the decline was still relatively large. Test pile S1 decreased from 201.4 to 86.3 kPa, while test pile S2 decreased from 374.1 to 114.3 kPa after pile jacking. The excess pore water pressure at the pile-soil interface rose first at the initial stage of consolidation and dissipated only after the hydraulic gradient between the pile-soil interface and the soil surrounding the pile disappeared. The dissipation degree of excess pore water pressure reached about 75-85%. The excess pore water pressure at the pile-soil interface increased with the increase in buried depth and finally tended to stabilize.
ABSTRACT
In order to have a better understanding of the real contact area of granular materials, the white light interference method is applied to explore the real surface morphology of clay soils under high stress. Analysis of the surface profile indicates that there exists a support point height z0 with the highest distribution frequency. A concept of a real contact region (from z0 to z0 + d90; d90 represents the particle size corresponding to 90% of the volume fraction) is proposed by combining a surface profile with the particle size distribution of clay soil. It was found that under the compressive stress of 106 MPa-529 MPa, the actual contact area ratio of clay soil varies between 0.375 and 0.431. This demonstrates an increasing trend with the rise of stress. On the contrary, the apparent porosity decreases with an increasing stress, varying between 0.554 and 0.525. In addition, as the compressive stress increases, the cumulative frequency of apparent profile height (from z0 - d90 to z0 + d90) has a concentrated tendency with a limited value of 0.9.
ABSTRACT
In this study, we reported facile synthesis of Fe3O4/C composite and its application for the cost-effective and sensitive determination of tryptophan (Trp) in human serum samples. Fe3O4/C composites were prepared by a simple one-pot hydrothermal method followed by a mild calcination procedure, using FeCl3â6H2O as Fe3O4 precursor, and glucose as reducing agent and carbon source simultaneously. The Fe3O4/C composite modified glassy carbon electrode (Fe3O4/C/GCE) was prepared by drop-casting method. The microstructure and morphology of Fe3O4/C composite was characterized by powder X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Due to large specific surface area and synergistic effect from Fe3O4 nanoparticles and carbon coating, Fe3O4/C composite showed excellent electrocatalytic activity toward the oxidation of Trp. As a result, the proposed Fe3O4/C/GCE displayed superior analytical performances toward Trp determination, with two wide detection ranges (1.0-80 µM and 80-800 µM) and a low detection limit (0.26 µM, S/N = 3). Moreover, successful detection of Trp in human serum samples further validate the practicability of the proposed sensor.
