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J Antibiot (Tokyo) ; 62(8): 453-60, 2009 Aug.
Article in English | MEDLINE | ID: mdl-19644517

ABSTRACT

Twenty-five aromatic nitro, dinitro and trinitro compounds were isolated in low yields of less than 1 mg l(-1) from a Salegentibacter sp. strain T436 derived from Arctic pack ice. Their structures were elucidated by MS and NMR techniques. Seven of these compounds, namely, 2-hydroxy-3-(4'-hydroxy-3'-nitrophenyl)-propionic acid methyl ester (6), 2-chloro-3- (4'-hydroxy-3'-nitrophenyl)propionic acid methyl ester (7), 3-(4'-hydroxy-3',5'-dinitrophenyl)-propionic acid methyl ester (14), 4'-hydroxy-3',5'-dinitrophenylethylchloride (16), (4'-hydroxy-3',5'-dinitrophenyl)-2-chloropropionic acid methyl ester (17), N-acetyl-3',5'-dinitrotyramine (18) and 2,6-dinitro-4-(2'-nitroethenyl)phenol (19) are new, and five are reported in this study from a natural source for the first time.


Subject(s)
Flavobacteriaceae/metabolism , Nitro Compounds/chemistry , Nitro Compounds/metabolism , Arctic Regions , Chromatography, High Pressure Liquid , Dinitrophenols/chemistry , Dinitrophenols/metabolism , Fermentation , Flavobacteriaceae/chemistry , Flavobacteriaceae/classification , Ice , Indicators and Reagents , Magnetic Resonance Spectroscopy , Molecular Conformation , Spectrometry, Mass, Electrospray Ionization , Spectrophotometry, Infrared , Spectroscopy, Fourier Transform Infrared
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