Isotope engineering for spin defects in van der Waals materials.

Spin defects in van der Waals materials offer a promising platform for advancing quantum technologies. Here, we propose and demonstrate a powerful technique based on isotope engineering of host materials to significantly enhance the coherence properties of embedded spin defects. Focusing on the recently-discovered negatively charged boron vacancy center ([Formula: see text]) in hexagonal boron nitride (hBN), we grow isotopically purified h10B15N crystals. Compared to [Formula: see text] in hBN with the natural distribution of isotopes, we observe substantially narrower and less crowded [Formula: see text] spin transitions as well as extended coherence time T2 and relaxation time T1. For quantum sensing, [Formula: see text] centers in our h10B15N samples exhibit a factor of 4 (2) enhancement in DC (AC) magnetic field sensitivity. For additional quantum resources, the individual addressability of the [Formula: see text] hyperfine levels enables the dynamical polarization and coherent control of the three nearest-neighbor 15N nuclear spins. Our results demonstrate the power of isotope engineering for enhancing the properties of quantum spin defects in hBN, and can be readily extended to improving spin qubits in a broad family of van der Waals materials.

Absolutely Stable Time Crystals at Finite Temperature.

We show that locally interacting, periodically driven (Floquet) Hamiltonian dynamics coupled to a Langevin bath support finite-temperature discrete time crystals (DTCs) with an infinite autocorrelation time. By contrast to both prethermal and many-body localized DTCs, the time crystalline order we uncover is stable to arbitrary perturbations, including those that break the time translation symmetry of the underlying drive. Our approach utilizes a general mapping from probabilistic cellular automata to open classical Floquet systems undergoing continuous-time Langevin dynamics. Applying this mapping to a variant of the Toom cellular automaton, which we dub the "π-Toom time crystal," leads to a 2D Floquet Hamiltonian with a finite-temperature DTC phase transition. We provide numerical evidence for the existence of this transition, and analyze the statistics of the finite temperature fluctuations. Finally, we discuss how general results from the field of probabilistic cellular automata imply the existence of discrete time crystals (with an infinite autocorrelation time) in all dimensions, d≥1.

Operator Growth in Open Quantum Systems.

The spreading of quantum information in closed systems, often termed scrambling, is a hallmark of many-body quantum dynamics. In open systems, scrambling competes with noise, errors, and decoherence. Here, we provide a universal framework that describes the scrambling of quantum information in open systems: we predict that the effect of open-system dynamics is fundamentally controlled by operator size distributions and independent of the microscopic error mechanism. This framework allows us to demonstrate that open quantum systems exhibit universal classes of information dynamics that fundamentally differ from their unitary counterparts. Implications for the Loschmidt echo, nuclear magnetic resonance experiments, and the classical simulability of open quantum dynamics will be discussed.

Quasi-Floquet Prethermalization in a Disordered Dipolar Spin Ensemble in Diamond.

Floquet (periodic) driving has recently emerged as a powerful technique for engineering quantum systems and realizing nonequilibrium phases of matter. A central challenge to stabilizing quantum phenomena in such systems is the need to prevent energy absorption from the driving field. Fortunately, when the frequency of the drive is significantly larger than the local energy scales of the many-body system, energy absorption is suppressed. The existence of this so-called prethermal regime depends sensitively on the range of interactions and the presence of multiple driving frequencies. Here, we report the observation of Floquet prethermalization in a strongly interacting dipolar spin ensemble in diamond, where the angular dependence of the dipolar coupling helps to mitigate the long-ranged nature of the interaction. Moreover, we extend our experimental observation to quasi-Floquet drives with multiple incommensurate frequencies. In contrast to a single-frequency drive, we find that the existence of prethermalization is extremely sensitive to the smoothness of the applied field. Our results open the door to stabilizing and characterizing nonequilibrium phenomena in quasiperiodically driven systems.

Quantum Noise Spectroscopy of Dynamical Critical Phenomena.

The transition between distinct phases of matter is characterized by the nature of fluctuations near the critical point. We demonstrate that noise spectroscopy can not only diagnose the presence of a phase transition, but can also determine fundamental properties of its criticality. In particular, by analyzing a scaling collapse of the decoherence profile, one can directly extract the critical exponents of the transition and identify its universality class. Our approach naturally captures the presence of conservation laws and distinguishes between classical and quantum phase transitions. In the context of quantum magnetism, our proposal complements existing techniques and provides a novel toolset optimized for interrogating two-dimensional magnetic materials.

Scalable spin squeezing in a dipolar Rydberg atom array.

The standard quantum limit bounds the precision of measurements that can be achieved by ensembles of uncorrelated particles. Fundamentally, this limit arises from the non-commuting nature of quantum mechanics, leading to the presence of fluctuations often referred to as quantum projection noise. Quantum metrology relies on the use of non-classical states of many-body systems to enhance the precision of measurements beyond the standard quantum limit1,2. To do so, one can reshape the quantum projection noise-a strategy known as squeezing3,4. In the context of many-body spin systems, one typically uses all-to-all interactions (for example, the one-axis twisting model4) between the constituents to generate the structured entanglement characteristic of spin squeezing5. Here we explore the prediction, motivated by recent theoretical work6-10, that short-range interactions-and in particular, the two-dimensional dipolar XY model-can also enable the realization of scalable spin squeezing. Working with a dipolar Rydberg quantum simulator of up to N = 100 atoms, we demonstrate that quench dynamics from a polarized initial state lead to spin squeezing that improves with increasing system size up to a maximum of -3.5 ± 0.3 dB (before correcting for detection errors, or roughly -5 ± 0.3 dB after correction). Finally, we present two independent refinements: first, using a multistep spin-squeezing protocol allows us to further enhance the squeezing by roughly 1 dB, and second, leveraging Floquet engineering to realize Heisenberg interactions, we demonstrate the ability to extend the lifetime of the squeezed state by freezing its dynamics.

Ergodicity breaking in rapidly rotating C60 fullerenes.

Ergodicity, the central tenet of statistical mechanics, requires an isolated system to explore all available phase space constrained by energy and symmetry. Mechanisms for violating ergodicity are of interest for probing nonequilibrium matter and protecting quantum coherence in complex systems. Polyatomic molecules have long served as a platform for probing ergodicity breaking in vibrational energy transport. Here, we report the observation of rotational ergodicity breaking in an unprecedentedly large molecule, 12C60, determined from its icosahedral rovibrational fine structure. The ergodicity breaking occurs well below the vibrational ergodicity threshold and exhibits multiple transitions between ergodic and nonergodic regimes with increasing angular momentum. These peculiar dynamics result from the molecule's distinctive combination of symmetry, size, and rigidity, highlighting its relevance to emergent phenomena in mesoscopic quantum systems.

Continuous symmetry breaking in a two-dimensional Rydberg array.

Spontaneous symmetry breaking underlies much of our classification of phases of matter and their associated transitions1-3. The nature of the underlying symmetry being broken determines many of the qualitative properties of the phase; this is illustrated by the case of discrete versus continuous symmetry breaking. Indeed, in contrast to the discrete case, the breaking of a continuous symmetry leads to the emergence of gapless Goldstone modes controlling, for instance, the thermodynamic stability of the ordered phase4,5. Here, we realize a two-dimensional dipolar XY model that shows a continuous spin-rotational symmetry using a programmable Rydberg quantum simulator. We demonstrate the adiabatic preparation of correlated low-temperature states of both the XY ferromagnet and the XY antiferromagnet. In the ferromagnetic case, we characterize the presence of a long-range XY order, a feature prohibited in the absence of long-range dipolar interaction. Our exploration of the many-body physics of XY interactions complements recent works using the Rydberg-blockade mechanism to realize Ising-type interactions showing discrete spin rotation symmetry6-9.

Universal Kardar-Parisi-Zhang Dynamics in Integrable Quantum Systems.

Although the Bethe ansatz solution of the spin-1/2 Heisenberg model dates back nearly a century, the anomalous nature of its high-temperature transport dynamics has only recently been uncovered. Indeed, numerical and experimental observations have demonstrated that spin transport in this paradigmatic model falls into the Kardar-Parisi-Zhang (KPZ) universality class. This has inspired the significantly stronger conjecture that KPZ dynamics, in fact, occur in all integrable spin chains with non-Abelian symmetry. Here, we provide extensive numerical evidence affirming this conjecture. Moreover, we observe that KPZ transport is even more generic, arising in both supersymmetric and periodically driven models. Motivated by recent advances in the realization of SU(N)-symmetric spin models in alkaline-earth-based optical lattice experiments, we propose and analyze a protocol to directly investigate the KPZ scaling function in such systems.

SWAP Gate between a Majorana Qubit and a Parity-Protected Superconducting Qubit.

High fidelity quantum information processing requires a combination of fast gates and long-lived quantum memories. In this Letter, we propose a hybrid architecture, where a parity-protected superconducting qubit is directly coupled to a Majorana qubit, which plays the role of a quantum memory. The superconducting qubit is based upon a π-periodic Josephson junction realized with gate-tunable semiconducting wires, where the tunneling of individual Cooper pairs is suppressed. One of the wires additionally contains four Majorana zero modes that define a qubit. We demonstrate that this enables the implementation of a SWAP gate, allowing for the transduction of quantum information between the topological and conventional qubit. This architecture combines fast gates, which can be realized with the superconducting qubit, with a topologically protected Majorana memory.

Quantum gas microscopy of Kardar-Parisi-Zhang superdiffusion.

The Kardar-Parisi-Zhang (KPZ) universality class describes the coarse-grained behavior of a wealth of classical stochastic models. Surprisingly, KPZ universality was recently conjectured to also describe spin transport in the one-dimensional quantum Heisenberg model. We tested this conjecture by experimentally probing transport in a cold-atom quantum simulator via the relaxation of domain walls in spin chains of up to 50 spins. We found that domain-wall relaxation is indeed governed by the KPZ dynamical exponent z = 3/2 and that the occurrence of KPZ scaling requires both integrability and a nonabelian SU(2) symmetry. Finally, we leveraged the single-spin-sensitive detection enabled by the quantum gas microscope to measure an observable based on spin-transport statistics. Our results yield a clear signature of the nonlinearity that is a hallmark of KPZ universality.

Measurement-Induced Transition in Long-Range Interacting Quantum Circuits.

The competition between scrambling unitary evolution and projective measurements leads to a phase transition in the dynamics of quantum entanglement. Here, we demonstrate that the nature of this transition is fundamentally altered by the presence of long-range, power-law interactions. For sufficiently weak power laws, the measurement-induced transition is described by conformal field theory, analogous to short-range-interacting hybrid circuits. However, beyond a critical power law, we demonstrate that long-range interactions give rise to a continuum of nonconformal universality classes, with continuously varying critical exponents. We numerically determine the phase diagram for a one-dimensional, long-range-interacting hybrid circuit model as a function of the power-law exponent and the measurement rate. Finally, by using an analytic mapping to a long-range quantum Ising model, we provide a theoretical understanding for the critical power law.

Floquet Phases of Matter via Classical Prethermalization.

We demonstrate that the prethermal regime of periodically driven (Floquet), classical many-body systems can host nonequilibrium phases of matter. In particular, we show that there exists an effective Hamiltonian that captures the dynamics of ensembles of classical trajectories despite the breakdown of this description at the single trajectory level. In addition, we prove that the effective Hamiltonian can host emergent symmetries protected by the discrete time-translation symmetry of the drive. The spontaneous breaking of such an emergent symmetry leads to a subharmonic response, characteristic of time crystalline order, that survives to exponentially late times in the frequency of the drive. To this end, we numerically demonstrate the existence of classical prethermal time crystals in systems with different dimensionalities and ranges of interaction. Extensions to higher order and fractional time crystals are also discussed.

Dynamic Tuning of Moiré Excitons in a WSe2/WS2 Heterostructure via Mechanical Deformation.

Moiré superlattices in van der Waals (vdW) heterostructures form by stacking atomically thin layers on top of one another with a twist angle or lattice mismatch. The resulting moiré potential leads to a strong modification of the band structure, which can give rise to exotic quantum phenomena ranging from correlated insulators and superconductors to moiré excitons and Wigner crystals. Here, we demonstrate the dynamic tuning of moiré potential in a WSe2/WS2 heterostructure at cryogenic temperature. We utilize the optical fiber tip of a cryogenic scanning near-field optical microscope (SNOM) to locally deform the heterostructure and measure its near-field optical response simultaneously. The deformation of the heterostructure increases the moiré potential, which leads to a red shift of the moiré exciton resonances. We observe the interlayer exciton resonance shifts up to 20 meV, while the intralayer exciton resonances shift up to 17 meV.

Realizing Hopf Insulators in Dipolar Spin Systems.

The Hopf insulator is a weak topological insulator characterized by an insulating bulk with conducting edge states protected by an integer-valued linking number invariant. The state exists in three-dimensional two-band models. We demonstrate that the Hopf insulator can be naturally realized in lattices of dipolar-interacting spins, where spin exchange plays the role of particle hopping. The long-ranged, anisotropic nature of the dipole-dipole interactions allows for the precise detail required in the momentum-space structure, while different spin orientations ensure the necessary structure of the complex phases of the hoppings. Our model features robust gapless edge states at both smooth edges, as well as sharp edges obeying a certain crystalline symmetry, despite the breakdown of the two-band picture at the latter. In an accompanying paper [T. Schuster et al., Phys. Rev. A 103, AW11986 (2021)PLRAAN2469-9926] we provide a specific experimental blueprint for implementing our proposal using ultracold polar molecules of ^{40}K^{87}Rb.

Emergent Ergodicity at the Transition between Many-Body Localized Phases.

Strongly disordered systems in the many-body localized (MBL) phase can exhibit ground state order in highly excited eigenstates. The interplay between localization, symmetry, and topology has led to the characterization of a broad landscape of MBL phases ranging from spin glasses and time crystals to symmetry protected topological phases. Understanding the nature of phase transitions between these different forms of eigenstate order remains an essential open question. Here, we conjecture that no direct transition between distinct MBL orders can occur in one dimension; rather, an ergodic phase always intervenes. Motivated by recent advances in Rydberg-atom-based quantum simulation, we propose an experimental protocol where the intervening ergodic phase can be diagnosed via the dynamics of local observables.

Preparation of Low Entropy Correlated Many-Body States via Conformal Cooling Quenches.

We propose and analyze a method for preparing low entropy many-body states in isolated quantum optical systems of atoms, ions, and molecules. Our approach is based upon shifting entropy between different regions of a system by spatially modulating the magnitude of the effective Hamiltonian. We conduct two case studies, on a topological spin chain and the spinful fermionic Hubbard model, focusing on the key question: can a "conformal cooling quench" remove sufficient entropy within experimentally accessible timescales? Finite-temperature, time-dependent matrix product state calculations reveal that even moderately sized bath regions can remove enough energy and entropy density to expose coherent low-temperature physics. The protocol is particularly natural in systems with long-range interactions, such as lattice-trapped polar molecules and Rydberg-excited atoms, where the magnitude of the Hamiltonian scales directly with the interparticle spacing. To this end, we propose simple, near-term implementations of conformal cooling quenches in systems of atoms or molecules, where signatures of low-temperature phases may be observed.

Many-Body Chaos in the Sachdev-Ye-Kitaev Model.

Many-body chaos has emerged as a powerful framework for understanding thermalization in strongly interacting quantum systems. While recent analytic advances have sharpened our intuition for many-body chaos in certain large N theories, it has proven challenging to develop precise numerical tools capable of exploring this phenomenon in generic Hamiltonians. To this end, we utilize massively parallel, matrix-free Krylov subspace methods to calculate dynamical correlators in the Sachdev-Ye-Kitaev model for up to N=60 Majorana fermions. We begin by showing that numerical results for two-point correlation functions agree at high temperatures with dynamical mean field solutions, while at low temperatures finite-size corrections are quantitatively reproduced by the exactly solvable dynamics of near extremal black holes. Motivated by these results, we develop a novel finite-size rescaling procedure for analyzing the growth of out-of-time-order correlators. Our procedure accurately determines the Lyapunov exponent, λ, across a wide range in temperatures, including in the regime where λ approaches the universal bound, λ=2π/ß.

Symmetry-Enhanced Boundary Qubits at Infinite Temperature.

The Z_{2}×Z_{2} symmetry-protected topological (SPT) phase hosts a robust boundary qubit at zero temperature. At finite energy density, the SPT phase is destroyed and bulk observables equilibrate in finite time. Nevertheless, we predict parametric regimes in which the boundary qubit survives to arbitrarily high temperature, with an exponentially longer coherence time than that of the thermal bulk degrees of freedom. In a dual picture, the persistence of the qubit stems from the inability of the bulk to absorb the virtual Z_{2}×Z_{2} domain walls emitted by the edge during the relaxation process. We confirm the long coherence times via exact diagonalization and connect it to the presence of a pair of conjugate almost strong zero modes. Our results provide a route to experimentally construct long-lived coherent boundary qubits at infinite temperature in disorder-free systems. To this end, we propose and analyze an implementation using a Rydberg optical-tweezer array and demonstrate that the difference between edge- and bulk-spin autocorrelators can be distinguished on timescales significantly shorter than the typical coherence time.

Emergent Hydrodynamics in Nonequilibrium Quantum Systems.

A tremendous amount of recent attention has focused on characterizing the dynamical properties of periodically driven many-body systems. Here, we use a novel numerical tool termed "density matrix truncation" (DMT) to investigate the late-time dynamics of large-scale Floquet systems. We find that DMT accurately captures two essential pieces of Floquet physics, namely, prethermalization and late-time heating to infinite temperature. Moreover, by implementing a spatially inhomogeneous drive, we demonstrate that an interplay between Floquet heating and diffusive transport is crucial to understanding the system's dynamics. Finally, we show that DMT also provides a powerful method for quantitatively capturing the emergence of hydrodynamics in static (undriven) Hamiltonians; in particular, by simulating the dynamics of generic, large-scale quantum spin chains (up to L=100), we are able to directly extract the energy diffusion coefficient.