5†kW power-level 1050†nm narrow-linewidth fiber amplifier enabled by biconical-tapered active fiber.

Effective wavelength extension is vital in the applications of high-power narrow-linewidth fiber lasers. In this work, we demonstrate a 5-kW power-level narrow-linewidth fiber amplifier at 1050 nm utilizing a homemade biconical-tapered Yb-doped fiber (BT-YDF). Up to ∼4.96 kW fiber laser is achieved with a 3 dB linewidth of ∼0.54 nm and a beam quality factor of Mx 2 = 1.46, My 2 = 1.6. The experimental comparisons reveal that BT-YDF has the advantages of improving a stimulated Raman scattering threshold and balancing transverse mode instability suppression in the fiber amplifier. This work could provide a good reference for extending the operating wavelength of high-power fiber amplifiers.

Reduction strategies of polycyclic aromatic hydrocarbons in farmland soils: Microbial degradation, plant transport inhibition, and their mechanistic analysis.

This study focuses on the abatement of polycyclic aromatic hydrocarbons (PAHs), a global pollutant, in farmland soils. Seven controlled PAHs in China were used as the target ligands, and four key target receptors degradable PAHs and two key target receptors transport PAHs were used as the target receptors. Firstly, the degradation abilities of the four key target receptors on PAHs were quantified, and the dominant target receptors that could efficiently degrade PAHs were screened out. Then, the co-degradation abilities of PAHs under the coexistence of the dominant target receptors (microbial diversity) were assessed, and 30 external condition-adding schemes to promote the microbial (co-)degradation of PAHs were designed. In addition, the microbial dominant target receptor mutants and the plant key target receptor mutants were obtained, the degradation and transportation of PAHs were improved by 8.06%∼22.27% and 39.86%∼45.43%. Finally, the mechanism analysis of PAHs biodegradation and transportation found that the Van der Waals interactions dominated the enhancement of PAHs' degradation in soil, and the solvation capacity dominated the decrease of PAHs' transportation in plant. This study aims to provide theoretical support for the prevention and control of PAHs residue pollution in farmland soil, as well as the protection of human dietary health.

Broadband tunable Raman fiber laser with monochromatic pump.

Raman fiber laser (RFL) has been widely adopted in astronomy, optical sensing, imaging, and communication due to its unique advantages of flexible wavelength and broadband gain spectrum. Conventional RFLs are generally based on silica fiber. Here, we demonstrate that the phosphosilicate fiber has a broader Raman gain spectrum as compared to the common silica fiber, making it a better choice for broadband Raman conversion. By using the phosphosilicate fiber as gain medium, we propose and build a tunable RFL, and compare its operation bandwidth with a silica fiber-based RFL. The silica fiber-based RFL can operate within the Raman shift range of 4.9 THz (9.8-14.7 THz), whereas in the phosphosilicate fiber-based RFL, efficient lasing is achieved over the Raman shift range of 13.7 THz (3.5-17.2 THz). The operation bandwidths of the two RFLs are also calculated theoretically. The simulation results agree well with experimental data, where the operation bandwidth of the phosphosilicate fiber-based RFL is more than twice of that of the silica fiber-based RFL. This work reveals the phosphosilicate fiber's unique advantage in broadband Raman conversion, which has great potential in increasing the reach and capacity of optical communication systems.

Mode-modulation-induced high power dual-wavelength generation in a random distributed feedback Raman fiber laser.

An all-fiberized random distributed feedback Raman fiber laser (RRFL) with mode-modulation-induced wavelength manipulation and dual-wavelength generation has been demonstrated, where an electrically controlled intra-cavity acoustically-induced fiber grating (AIFG) is employed to adjust the input modal content at the signal wavelength. The wavelength agility of both the Raman effect and the Rayleigh backscattering in RRFL benefits on broadband laser output in case of broadband pumping. The feedback modal content at different wavelengths can be adjusted by AIFG, and then the output spectral manipulation can be ultimately manifested through the mode competition in RRFL. Under the efficient mode modulation, the output spectrum can be continuously tuned from 1124.3 nm to 1133.8 nm with single wavelength, while ulteriorly the dual-wavelength spectrum can be formed at 1124.1 nm and 1134.7 nm with a signal-noise-ratio of 45 dB. Throughout, the power is beyond 47 W with good stability and repeatability. To the best of our knowledge, this is the first dual-wavelength fiber laser based on mode modulation and the highest output power ever reported for an all-fiberized continuous wave dual-wavelength fiber laser.

Triazine Herbicides Risk Management Strategies on Environmental and Human Health Aspects Using In-Silico Methods.

As an effective herbicide, 1, 3, 5-Triazine herbicides (S-THs) are used widely in the pesticide market. However, due to their chemical properties, S-THs severely threaten the environment and human health (e.g., human lung cytotoxicity). In this study, molecular docking, Analytic Hierarchy Process-Technique for Order Preference by Similarity to the Ideal Solution (AHP-TOPSIS), and a three-dimensional quantitative structure-active relationship (3D-QSAR) model were used to design S-TH substitutes with high herbicidal functionality, high microbial degradability, and low human lung cytotoxicity. We discovered a substitute, Derivative-5, with excellent overall performance. Furthermore, Taguchi orthogonal experiments, full factorial design of experiments, and the molecular dynamics method were used to identify three chemicals (namely, the coexistence of aspartic acid, alanine, and glycine) that could promote the degradation of S-THs in maize cropping fields. Finally, density functional theory (DFT), Estimation Programs Interface (EPI), pharmacokinetic, and toxicokinetic methods were used to further verify the high microbial degradability, favorable aquatic environment, and human health friendliness of Derivative 5. This study provided a new direction for further optimizations of novel pesticide chemicals.

Phosphosilicate Fiber-Based Low Quantum Defect Raman Fiber Laser with Ultrahigh Spectral Purity.

The phosphosilicate fiber-based Raman fiber laser (RFL) has great potential in achieving low-quantum defect (QD) high-power laser output. However, the laser's performance could be seriously degraded by the Raman-assisted four-wave mixing (FWM) effect and spontaneous Raman generation at 14.7 THz. To find possible ways to suppress the Raman-assisted FWM effect and spontaneous Raman generation, here, we propose a revised power-balanced model to simulate the nonlinear process in the low-QD RFL. The power evolution characteristics in this low-QD RFL with different pump directions are calculated. The simulation results show that, compared to the forward-pumped low-QD RFL, the threshold powers of spontaneous Raman generation in the backward-pumped RFL are increased by 40% and the Raman-assisted FWM effect is well suppressed. Based on the simulation work, we change the pump direction of a forward-pumped low-QD RFL into backward pumping. As a result, the maximum signal power is increased by 20% and the corresponding spectral purity is increased to 99.8%. This work offers a way for nonlinear effects controlling in low-QD RFL, which is essential in its further performance scaling.

Low quantum defect random Raman fiber laser.

The random Raman fiber laser (RRFL) has attracted great attention due to its wide applications in optical telecommunication, sensing, and imaging. The quantum defect (QD), as the main source of thermal load in fiber lasers, could threaten the stability and reliability of the RRFL. Conventional RRFLs generally adopt silica fiber to provide Raman gain, and the QD exceeds 4%. In this letter, we propose and demonstrate a phosphosilicate-fiber-based low-QD RRFL. There is a strong boson peak located at the frequency shift of 3.65 THz in the phosphosilicate fiber we employed. By utilizing this boson peak to provide Raman gain, we demonstrated an 11.71 W temporally stable random Raman laser at 1080 nm under a pump wavelength of 1066 nm. The corresponding QD is 1.3%, less than one third of the QD of the common silica-fiber-based RRFL. Compared with the full-cavity low-QD Raman fiber laser, this cavity-less low-QD RRFL has lower and flatter noise in the high frequency area (>100 kHz). This work provides a reference for suppressing thermal-induced effects, such as thermal-induced mode instability, thermal noise, and even fiber fusing in RRFLs.

Seeing the beam cleanup effect in a high-power graded-index-fiber Raman amplifier based on mode decomposition.

Due to the beam cleanup effect, brightness enhancement (BE) can be achieved in a Raman fiber amplifier (RFA) based on multimode (MM) graded-index (GRIN) fiber. In this Letter, a novel, to the best of our knowledge, diagnostic tool of mode decomposition (MD) based on a stochastic parallel gradient descent algorithm is demonstrated to observe the beam cleanup effect in a GRIN-fiber-based RFA for the first time, to our knowledge. During output power boosting up to 405 W at 1130 nm, the output beam quality factor M2 improves from 3.45 to 2.88, with a BE factor of 10.5. The MD results based on the near-field beam profiles from RFA indicate that the modal weight of the fundamental mode increases from 74.5% to 87%, confirming that the fundamental mode dominates with higher Raman gain. Moreover, the beam quality is found to be limited by the existence of a higher-order (Laguerre-Gaussian) LG10 mode, which is insensitive to the beam cleanup effect. The correlation coefficient reaches over 0.98 for all MD results. Thus, the accuracy of the MD method is high enough to provide further valuable insight into the physics of spatiotemporal beam dynamics in MM GRIN fiber.

Kilowatt level Raman amplifier based on 100 µm core diameter multimode GRIN fiber with M2 = 1.6.

In this Letter, we demonstrate a high-power Raman fiber amplifier with excellent beam quality based on graded-index fiber. The Yb-doped fiber laser (YDFL) and bandwidth-tunable amplified spontaneous emission (ASE) source are employed as the pump source to compare the laser performance separately. When the ASE with a bandwidth of 8 nm is employed, a maximum power of 943 W at 1130 nm is achieved, which is twice that pumped by YDFL. The beam quality factor M2 at maximum output power is 1.6, with a brightness enhancement (BE) factor of 27. To the best of our knowledge, this is the best beam quality and BE factor based on pure Raman gain with output power of over 100 W.

Over 400 W graded-index fiber Raman laser with brightness enhancement.

The power scaling on all-fiberized Raman fiber oscillator with brightness enhancement (BE) based on multimode graded-index (GRIN) fiber is demonstrated. Thanks to beam cleanup of GRIN fiber itself and single-mode selection properties of the fiber Bragg gratings inscribed in the center of GRIN fiber, the efficient BE is realized. For the laser cavity with single OC FBG, continuous-wave power of 334 W with an M2 value of 2.8 and BE value of 5.6 were obtained at a wavelength of 1120 nm with an optical-to-optical efficiency of 49.6%. Furthermore, the cavity reflectivity is increased by employing two OC FBGs to scale the output power up to 443 W, while the corresponding M2 is 3.5 with BE of 4.2. To our best knowledge, it is the highest power in Raman oscillator based on GRIN fiber.

High power tunable multiwavelength random fiber laser at 1.3 µm waveband.

Multiwavelength fiber lasers, especially those operating at optical communication wavebands such as 1.3 µm and 1.5 µm wavebands, have huge demands in wavelength division multiplexing communications. In the past decade, multiwavelength fiber lasers operating at 1.5 µm waveband have been widely reported. Nevertheless, 1.3 µm waveband multiwavelength fiber laser is rarely studied due to the lack of proper gain mechanism. Random fiber laser (RFL), owing to its good temporal stability and flexible wavelength tunability, is a great candidate for multiwavelength generation. Here, we reported high power multiwavelength generation at 1.3 µm waveband in RFL for the first time. At first, we employed a section of 10 km G655C fiber to provide Raman gains, as a result of which, 1.07 W multiwavelength generation at 1.3 µm waveband with an optical to signal noise ratio of ∼33 dB is demonstrated. By tuning the pump wavelength from 1055 nm to 1070 nm, tunable multiwavelength output covering the range of 1300-1330 nm can be achieved. Furtherly, we realized 4.67 W multiwavelength generation at 1.3 µm waveband by shortening the fiber length to 4 km. To the best of our knowledge, this is the highest output power ever reported for multiwavelength fiber lasers.

Brightness enhancement in random Raman fiber laser based on a graded-index fiber with high-power multimode pumping.

A brightness-enhanced random Raman fiber laser (RRFL) with maximum power of 306 W at 1120 nm is demonstrated. A half-open cavity is built based on a graded-index (GRIN) passive fiber and single high-reflective fiber Bragg grating written in it directly. Due to the beam cleanup effect in the GRIN fiber enhanced in the half-open RRFL cavity, the output beam quality factor M2 is improved from 9.15 (pump) to 1.76-2.35 (Stokes) depending on power, while the pump-Stokes brightness enhancement (BE) factor increases proportionally to output power reaching 6.1 at maximum. To the best of our knowledge, this is the highest power GRIN RRFL with BE.

Cascaded telecom fiber enabled high-order random fiber laser beyond zero-dispersion wavelength.

Four-wave mixing induced spectral broadening near the zero-dispersion wavelength (ZDW) of the fiber is a bottleneck factor that limits the further wavelength extending in cascaded random fiber lasers (RFLs). In this Letter, we successfully suppress the spectral broadening near the ZDW of the fiber in the cascaded RFL by simply combining two kinds of commercial telecom fibers with different ZDWs, G655C fiber with ZDW around 1.52 µm and G652D fiber with ZDW around 1.31 µm. As a result, an 8th order Stokes light component at 1721 nm with a maximum output power of 2.1 W and a spectral purity of 96.94% is realized in this telecom-fiber-based cascaded RFL. This work provides a reference of nonlinear effect management in fiber lasers as well as affords a cost-effective way with great potential of realizing high-power widely tunable fiber lasers.

Power scaling of Raman fiber amplifier based on the optimization of temporal and spectral characteristics.

We comprehensively study the effects of temporal and spectral optimization on single-mode Raman fiber amplifiers. Amplified spontaneous emission sources and ytterbium-doped fiber lasers are employed as seed or pump lasers for comparison, and passive fibers are utilized as gain media. The influences of various parameters of the laser on 2nd order Raman threshold and maximum output power are investigated experimentally, including bandwidth, seed power, wavelength separation between pump and seed laser, and temporal stability. With the 190 m passive fiber, the output power increases from 99.5 W to 142.4 W, corresponding to 43.1% improvement through the optimization of seed laser power, pump wavelength and temporal performance of pump source in this amplifier, which has guidance on the establishment of high-power single-mode Raman fiber amplifiers.

High-power cladding pumped Raman fiber amplifier with a record beam quality.

In this Letter, a high-power, high-brightness all-fiberized Raman amplifier based on a cladding-pumping scheme is presented for the first time, to the best of our knowledge. The triple-clad passive fiber is employed as Raman gain fiber in the laser system. The maximum output power is 762.6 W emitting at 1130 nm. To the best of our knowledge, this is the highest power in the fields of cladding-pumped Raman amplifiers. Through a cladding-pumping process, the beam quality parameter ${{\rm M}^2}$M2 improves from 6.12 of seed laser to 2.24 at maximum output power of 762.6 W, while the best ${{\rm M}^2}$M2 is 1.9 at 267.2 W. It is also the best beam quality of Raman laser with brightness enhancement in any kind of configuration (graded-index fiber or multi-clad fiber, laser or amplifier, all-fiber or free-space configuration) with power of over 100 W.

Dual-wavelength random distributed feedback fiber laser with wavelength, linewidth, and power ratio tunability.

Owing to the special power distribution property, a random distributed feedback Raman fiber laser can achieve a high power spectrally flexible output with a low power spectrally tuning device. Here, an all-fiberized linearly polarized dual-wavelength random distributed feedback Raman laser with wavelength, linewidth, and power ratio tunability is demonstrated. By adopting two watt-level bandwidth adjustable optical filters, a spectrum-manipulable dual-wavelength output with nearly a 10 W output power is achieved. The wavelength separation can be tuned from 2.5 to 13 nm, and the 3 dB linewidth of the output can be doubled by increasing the bandwidth of the optical filter. The power ratio of each laser line can be tuned from 0 to nearly 100% with the help of two variable optical attenuators. A maximum output power of 9.46 W is realized, with a polarization extinction ratio up to 20.5 dB. The proposed dual-wavelength fiber laser can be employed as a pump source in frequency tunable, bandwidth adjustable terahertz microwave generation, and mid-infrared optical parametric oscillators.

Broadband pumping enabled flat-amplitude multi-wavelength random Raman fiber laser.

A flat-amplitude multi-wavelength random Raman fiber laser with broad spectral coverage and a high optical signal-to-noise ratio (OSNR) is challenging and of great interest. In this Letter, we theoretically and experimentally proved that broadband pumping can help realize a broader, flat-amplitude multi-wavelength random Raman fiber laser. The influence of pump bandwidth, tunability of the spectral envelope, and channel spacing are investigated. As a result, with a 40 nm pump bandwidth, a spectral coverage of 1116-1125 nm with 19 laser lines and 31 dB OSNR is achieved, and the standard deviation in the peak intensities of the central nine lines is ${\sim}{1}.{1}\;{\rm dBm}$∼1.1dBm. This technique can also be applied to the multi-wavelength Raman (or random Raman) fiber lasers at other wavelengths and provide a reference for multi-wavelength applications in sensing, communication, and optical component testing.

2†kW high-efficiency Raman fiber amplifier based on passive fiber with dynamic analysis on beam cleanup and fluctuation.

In this paper, we study the power scaling in high power continuous-wave Raman fiber amplifier employing graded-index passive fiber. The maximum output power reaches 2.087 kW at 1130 nm with an optical conversion efficiency of 90.1% (the output signal power versus the depleted pump power). To the best of our knowledge, this is the highest power in the fields of Raman fiber lasers based merely on Stokes radiation. The beam quality parameter M2 improves from 15 to 8.9 during the power boosting process, then beam spot distortion appears at high power level. This is the first observation and analysis on erratic dynamic properties of the transverse modes in high power Raman fiber amplifier.

All-fiberized cascaded random Raman fiber laser with high spectral purity based on filtering feedback.

Cascaded random Raman fiber lasers (CRRFLs) with simple configuration and high spectral purity have become a great candidate for power scaling over the 1.1 µm-2 µm spectral band. Recently, CRRFLs with high spectral purity over 90% have been proposed by applying a highly temporal-stable pump source or a free-space short-pass filter, at the cost of increased system complexity. In this work, pumped directly by a Yb-doped fiber oscillator at 1080 nm, an all-fiberized and simplified CRRFL with a short-pass optical filter based on bending fiber and a thin-film wavelength division multiplexer is demonstrated. The transmission loss of the filter for 5th Stokes order at 1440 nm is up to 70 dB. Spectral purity over 92% for all the first four Stokes orders is achieved. The highest output power is 15 W for the 4th Stokes order at 1341 nm.

Tunable random Raman fiber laser at 1.7 µm region with high spectral purity.

We demonstrate a tunable, high order cascaded random Raman fiber laser (RRFL) with high purity at 1.7 µm band by using a high power amplified spontaneous emission source (ASE) with both wavelength and linewidth tunability as pump source. The influence of the spectral bandwidth of the ASE source on the spectral purity of the output at 1.7 µm band is investigated. By adjusting the spectral bandwidth of the ASE source to the optimized 20 nm, output power >14 W with spectral purity up to 98.29% at 1715 nm is achieved. As far as we know, this is the highest spectral purity ever reported for a RRFL at 1.7 µm region. Furthermore, by adjusting the central wavelength of ASE source, the output of the RRFL can be tuned from 1695 to 1725 nm with >10 W output power. What's more, the spectral purity is above 92% over a tuning range from 1705 to 1725 nm.