High-Fidelity, Low-Hysteresis Bionic Flexible Strain Sensors for Soft Machines.

Stretchable flexible strain sensors based on conductive elastomers are rapidly emerging as a highly promising candidate for popular wearable flexible electronic and soft-mechanical sensing devices. However, due to the intrinsic limitations of low fidelity and high hysteresis, existing flexible strain sensors are unable to exploit their full application potential. Herein, a design strategy for a successive three-dimensional crack conductive network is proposed to cope with the uncoordinated variation of the output resistance signal arising from the conductive elastomer. The electrical characteristics of the sensor are dominated by the successive crack conductive network through a greater resistance variation and a concise sensing mechanism. As a result, the developed elastomer bionic strain sensors exhibit excellent sensing performance in terms of a smaller overshoot response, a lower hysteresis (∼2.9%), and an ultralow detection limit (0.00179%). What's more, the proposed strategy is universal and applicable to many conductive elastomers with different conductive fillers (including 0-D, 1-D, and 2-D conductive fillers). This approach improves the sensing signal accuracy and reliability of conductive elastomer strain sensors and holds promising potential for various applications in the fields of e-skin and soft robotic systems.

A Selective-Response Hypersensitive Bio-Inspired Strain Sensor Enabled by Hysteresis Effect and Parallel Through-Slits Structures.

Flexible strain sensors are promising in sensing minuscule mechanical signals, and thereby widely used in various advanced fields. However, the effective integration of hypersensitivity and highly selective response into one flexible strain sensor remains a huge challenge. Herein, inspired by the hysteresis strategy of the scorpion slit receptor, a bio-inspired flexible strain sensor (BFSS) with parallel through-slit arrays is designed and fabricated. Specifically, BFSS consists of conductive monolayer graphene and viscoelastic styrene-isoprene-styrene block copolymer. Under the synergistic effect of the bio-inspired slit structures and flexible viscoelastic materials, BFSS can achieve both hypersensitivity and highly selective frequency response. Remarkably, the BFSS exhibits a high gage factor of 657.36, and a precise identification of vibration frequencies at a resolution of 0.2 Hz through undergoing different morphological changes to high-frequency vibration and low-frequency vibration. Moreover, the BFSS possesses a wide frequency detection range (103 Hz) and stable durability (1000 cycles). It can sense and recognize vibration signals with different characteristics, including the frequency, amplitude, and waveform. This work, which turns the hysteresis effect into a "treasure," can provide new design ideas for sensors for potential applications including human-computer interaction and health monitoring of mechanical equipment.

Ultrasensitive, Highly Stable, and Flexible Strain Sensor Inspired by Nature.

For advanced flexible strain sensors, it is not difficult to achieve high sensitivity only. However, integrating high sensitivity, high stability, and high durability into one sensor still remains a great challenge. Fortunately, natural creatures with diversified excellent performances have given us a lot of ready-made solutions. Here, scorpion and spiderweb are selected as coupling bionic prototypes, which are famous for their ultrasensitive sensing capacity and excellent structural durability, respectively. Based on that, a bioinspired strain sensor is successfully fabricated. The results demonstrate that the bioinspired strain sensor has a sensitivity of 940.5 in the strain range of 0-1.5% and a sensitivity of 2742.3 between 1.5 and 2.5%. Meantime, this sensor with a spiderweb-like reticular structure has a great improvement in stability and durability. Specifically, the sensor exhibits excellent stability during bending and stretching cycles over 80,000 times. Moreover, the response time and recovery time of the sensor are 169 and 195 ms, respectively. Besides, the sensor also has functions such as vibrating frequency identification due to its low hysteresis. Based on the excellent performance, the sensor can be applied to monitor human body motions serving as wearable electronics.

Accelerated kinetic Monte Carlo: A case study; vacancy and dumbbell interstitial diffusion traps in concentrated solid solution alloys.

Vacancy and self-interstitial atomic diffusion coefficients in concentrated solid solution alloys can have a non-monotonic concentration dependence. Here, the kinetics of monovacancies and ⟨100⟩ dumbbell interstitials in Ni-Fe alloys are assessed using lattice kinetic Monte Carlo (kMC). The non-monotonicity is associated with superbasins, which impels using accelerated kMC methods. Detailed implementation prescriptions for first passage time analysis kMC (FPTA-kMC), mean rate method kMC (MRM-kMC), and accelerated superbasin kMC (AS-kMC) are given. The accelerated methods are benchmarked in the context of diffusion coefficient calculations. The benchmarks indicate that MRM-kMC underestimates diffusion coefficients, while AS-kMC overestimates them. In this application, MRM-kMC and AS-kMC are computationally more efficient than the more accurate FPTA-kMC. Our calculations indicate that composition dependence of migration energies is at the origin of the vacancy's non-monotonic behavior. In contrast, the difference between formation energies of Ni-Ni, Ni-Fe, and Fe-Fe dumbbell interstitials is at the origin of their non-monotonic diffusion behavior. Additionally, the migration barrier crossover composition-based on the situation where Ni or Fe atom jumps have lower energy barrier than the other one-is introduced. KMC simulations indicate that the interplay between composition dependent crossover of migration energy and geometrical site percolation explains the non-monotonic concentration-dependence of atomic diffusion coefficients.

Effect of He on the Order-Disorder Transition in Ni_{3}Al under Irradiation.

The order-disorder transition in Ni-Al alloys under irradiation represents an interplay between various reordering processes and disordering due to thermal spikes generated by incident high energy particles. Typically, ordering is enabled by diffusion of thermally generated vacancies, and can only take place at temperatures where they are mobile and in sufficiently high concentration. Here, in situ transmission electron micrographs reveal that the presence of He-usually considered to be a deleterious immiscible atom in this material-promotes reordering in Ni_{3}Al at temperatures where vacancies are not effective ordering agents. A rate-theory model is presented, that quantitatively explains this behavior, based on parameters extracted from atomistic simulations. These calculations show that the V_{2}He complex is an effective agent through its high stability and mobility. It is surmised that immiscible atoms may stabilize reordering agents in other materials undergoing driven processes, and preserve ordered phases at temperature where the driven processes would otherwise lead to disorder.

Effect of Shear Strain Rate on Microstructure and Properties of Austenitic Steel Processed by Cyclic Forward/Reverse Torsion.

In this work, commercial AISI 304 stainless steel rods were subjected to cyclic forward/reverse torsion (CFRT) treatments at low-speed and high-speed torsion at room temperature. Microstructures in the core and surface layers of the CFRT-treated samples were systematically characterized. Results show that the CFRT treatment can introduce martensite phase on the surface of the rods via strain-induced martensitic transformation. High-speed twisting is more effective in inducing martensite in the surface layer compared to low-speed twisting. During the stretching process, the overall strain-hardening behavior of the gradient material is related to the content of its gradient defects. Higher gradient martensite content results in a higher surface hardness of the material, but less overall tensile properties. The effect of twisting speed on torsion behavior and the strain-hardening mechanisms in tensile of the gradient structured steels was also addressed.

Spectral and raw quasi in-situ energy dispersive X-ray data captured via a TEM analysis of an ODS austenitic stainless steel sample under 1 MeV Kr2+ high temperature irradiation.

The data presented in this article is related to the research experiment, titled: 'Quasi in-situ energy dispersive X-ray spectroscopy observation of matrix and solute interactions on Y-Ti-O oxide particles in an austenitic stainless steel under 1 MeV Kr2+ high temperature irradiation' (Brooks et al., 2017) [1]. Quasi in-situ analysis during 1 MeV Kr2+ 520 °C irradiation allowed the same microstructural area to be observed using a transmission electron microscope (TEM), on an oxide dispersion strengthened (ODS) austenitic stainless steel sample. The data presented contains two sets of energy dispersive X-ray spectroscopy (EDX) data collected before and after irradiation to 1.5 displacements-per-atom (~1.25×10-3 dpa/s with 7.5×1014 ions cm-2). The vendor software used to process and output the data is the Bruker Esprit v1.9 suite. The data includes the spectral (counts vs. keV energy) of the quasi in-situ scanned region (512×512 pixels at 56k magnification), along with the EDX scanning parameters. The.raw files from the Bruker Esprit v1.9 output are additionally included along with the.rpl data information files. Furthermore included are the two quasi in-situ HAADF images for visual comparison of the regions before and after irradiation. This in-situ experiment is deemed 'quasi' due to the thin foil irradiation taking place at an external TEM facility. We present this data for critical and/or extended analysis from the scientific community, with applications applying to: experimental data correlation, confirmation of results, and as computer based modeling inputs.

In situ transmission electron microscopy and ion irradiation of ferritic materials.

The intermediate voltage electron microscope-tandem user facility in the Electron Microscopy Center at Argonne National Laboratory is described. The primary purpose of this facility is electron microscopy with in situ ion irradiation at controlled sample temperatures. To illustrate its capabilities and advantages a few results of two outside user projects are presented. The motion of dislocation loops formed during ion irradiation is illustrated in video data that reveals a striking reduction of motion in Fe-8%Cr over that in pure Fe. The development of extended defect structure is then shown to depend on this motion and the influence of nearby surfaces in the transmission electron microscopy thin samples. In a second project, the damage microstructure is followed to high dose (200 dpa) in an oxide dispersion strengthened ferritic alloy at 500 degrees C, and found to be qualitatively similar to that observed in the same alloy neutron irradiated at 420 degrees C.