Thermal activation energy on electrical degradation process in BaTiO3 based multilayer ceramic capacitors for lifetime reliability.

For a high capacitance and high lifetime reliability of multilayer ceramic capacitors for automotive applications, the activation energy on thermal activation process can typically be calculated by using Arrhenius based Prokopowicz-Vaskas equation as a method for lifetime prediction. In this study, it is clearly observed that the activation energy shows to be constant in the range of ~ 1.5 eV for the prototype MLCCs, higher than the activation energy values of ~ 1.0 eV related to the motion or diffusion of oxygen vacancies reported in the previous literature. The activation energy value of ~ 1.5 eV for three prototype MLCCs is close to a half the energy band gap (Eg/2 ≈ 1.6 eV) of BaTiO3 obtained from specific environment, where oxygen vacancies are stabilized by external containment such as the effect of rare earth oxide additives. Due to an obvious difference in activation energy values, it difficult to explain the conduction mechanism for failure by only oxygen vacancy migration. Therefore, the concepts of electronic processes and oxygen vacancy should be considered together to understand conduction mechanism for failure of BaTiO3-based MLCCs in thermal activation processes. It can be useful as an indicator for future MLCC development with high lifetime reliability.

Photo-stimulated triboelectric generation.

A new photo-stimulated triboelectric generation occurring between a metal-oxide and polyimide during friction was demonstrated. The output currents of the triboelectric nanogenerator were significantly enhanced, under light illumination, up to approximately 5 times depending on the wavelength of the light, providing a new route for energy harvesting devices as well as self-powered selective photodetectors.

Boosted output performance of triboelectric nanogenerator via electric double layer effect.

For existing triboelectric nanogenerators (TENGs), it is important to explore unique methods to further enhance the output power under realistic environments to speed up their commercialization. We report here a practical TENG composed of three layers, in which the key layer, an electric double layer, is inserted between a top layer, made of Al/polydimethylsiloxane, and a bottom layer, made of Al. The efficient charge separation in the middle layer, based on Volta's electrophorus, results from sequential contact configuration of the TENG and direct electrical connection of the middle layer to the earth. A sustainable and enhanced output performance of 1.22 mA and 46.8 mW cm-2 under low frequency of 3 Hz is produced, giving over 16-fold enhancement in output power and corresponding to energy conversion efficiency of 22.4%. Finally, a portable power-supplying system, which provides enough d.c. power for charging a smart watch or phone battery, is also successfully developed.

Parallel Aligned Mesopore Arrays in Pyramidal-Shaped Gallium Nitride and Their Photocatalytic Applications.

Parallel aligned mesopore arrays in pyramidal-shaped GaN are fabricated by using an electrochemical anodic etching technique, followed by inductively coupled plasma etching assisted by SiO2 nanosphere lithography, and used as a promising photoelectrode for solar water oxidation. The parallel alignment of the pores of several tens of micrometers scale in length is achieved by the low applied voltage and prepattern guided anodization. The dry etching of single-layer SiO2 nanosphere-coated GaN produces a pyramidal shape of the GaN, making the pores open at both sides and shortening the escape path of evolved gas bubbles produced inside pores during the water oxidation. The absorption spectra show that the light absorption in the UV range is ∼93% and that there is a red shift in the absorption edge by 30 nm, compared with the flat GaN. It also shows a remarkable enhancement in the photocurrent density by 5.3 times, compared with flat GaN. Further enhancement (∼40%) by the deposition of Ni was observed due to the generation of an electric field, which increases the charge separation ratio.

Visible Color Tunable Emission in Three-Dimensional Light Emitting Diodes by MgO Passivation of Pyramid Tip.

We demonstrated visible color tunable three-dimensional (3D) pyramidal light emitting diodes by depositing the MgO on and near the tip of the pyramid as an insulating layer. Here, we show that the degradation of the materials (i.e., p-GaN) crystallinity and the built-in electric field due to the nanoscale geometry of the tip region is responsible for the large leakage current observed in LEDs. Confocal scanning electroluminescence microscopy images clearly showed that the intensity of the light emitted out of the side facet of the pyramid is much higher than that of the light extracted out of the tip surface, indicating that the MgO layer prohibited the carrier injection to the MQWs layer, suppressing the leakage occurring at or near the tip region of the pyramids. The color range of the LEDs can be also tuned by using the MgO layer, a blue-shift by 10.3 nm in the wavelength. This technique is simple and scalable, providing a promising solution for developing 3D pyramidal LEDs with low leakage current and controllable light emission.

Correction: Electrospun ion gel nanofibers for flexible triboelectric nanogenerator: electrochemical effect on output power.

Correction for 'Electrospun ion gel nanofibers for flexible triboelectric nanogenerator: electrochemical effect on output power' by Byeong Uk Ye et al., Nanoscale, 2015, 7, 16189-16194.

Electrospun ion gel nanofibers for flexible triboelectric nanogenerator: electrochemical effect on output power.

A simple fabrication route for ion gel nanofibers in a triboelectric nanogenerator was demonstrated. Using an electrospinning technique, we could fabricate a large-area ion gel nanofiber mat. The triboelectric nanogenerator was demonstrated by employing an ion gel nanofiber and the device exhibited an output power of 0.37 mW and good stability under continuous operation.

Structural Evolution of Chemically-Driven RuO2 Nanowires and 3-Dimensional Design for Photo-Catalytic Applications.

Growth mechanism of chemically-driven RuO2 nanowires is explored and used to fabricate three-dimensional RuO2 branched Au-TiO2 nanowire electrodes for the photostable solar water oxidation. For the real time structural evolution during the nanowire growth, the amorphous RuO2 precursors (Ru(OH)3 · H2O) are heated at 180 (°)C, producing the RuO2 nanoparticles with the tetragonal crystallographic structure and Ru enriched amorphous phases, observed through the in-situ synchrotron x-ray diffraction and the high-resolution transmission electron microscope images. Growth then proceeds by Ru diffusion to the nanoparticles, followed by the diffusion to the growing surface of the nanowire in oxygen ambient, supported by the nucleation theory. The RuO2 branched Au-TiO2 nanowire arrays shows a remarkable enhancement in the photocurrent density by approximately 60% and 200%, in the UV-visible and Visible region, respectively, compared with pristine TiO2 nanowires. Furthermore, there is no significant decrease in the device's photoconductance with UV-visible illumination during 1 day, making it possible to produce oxygen gas without the loss of the photoactvity.

Unprecedented colorimetric responses of polydiacetylenes driven by plasma induced polymerization and their patterning applications.

We report for the first time that polydiacetylenes (PDAs) can be alternatively prepared via a plasma induced polymerization process. The degree of polymerization and colorimetric transitions could be manipulated by controlling the power of plasma radiofrequency, exposure time and by using an acrylic mask, resulting in their great potential for patterning applications.

ZnO nanowire-based antireflective coatings with double-nanotextured surfaces.

High-aspect-ratio nanotextured surfaces with different morphologies (straight, core-shell type, and core-branch type nanowires) are prepared by a hydrothermal method of ZnO nanowires, followed by means of RF sputtering for core-shell type nanowires and e-beam evaporation for branch-type nanowires. The structural analysis showed that the MgO has highly preferred orientation along the ⟨111⟩ and ⟨200⟩ direction, respectively, and the crystalline continuity between the ZnO and MgO layers were also showed. Compared with ZnO nanowires, the MgO/ZnO samples drastically suppress broad and omnidirection reflection, which ascribes to the refractive-index modulation along the lateral direction of nanowires growth as well as the vertical direction. It was also shown that morphology could have a substantial influence on the antireflection property. These results suggest that double-nanotextured surface is one of the promising structures for antireflective surfaces without fine control in nanowire morphology.