ABSTRACT
Self-powered devices based on piezoelectric nanogenerators (PENGs) are becoming crucial in the upcoming smart societies as they can integrate multifunctional applications, especially sensing, energy storage, etc. In this work, we explore the piezoelectric voltage generation happening in polyvinylidene fluoride (PVDF) nanocomposites developed by phase separation. The simple method adopted for the nanocomposite synthesis rules out the high voltage required for the normal electrospun PENGs and adds to their cost-effectiveness. Zinc-doped iron oxide (Zn-Fe2O3) nanomaterials influence the piezoelectric properties by enhancing the crystallinity and structural properties of the polymer. The phase separation process causes structural rearrangements within the PVDF by inducing the directional alignment of -CH2- and -CF2-chains and is the major reason for electroactive phase enhancement. Layers of Zn-Fe2O3 were uniformly distributed in the phase-separated PVDF without being negatively influenced by the solvent-non-solvent interactions during phase separation. At 3 wt%, the Zn-Fe2O3 induced an open circuit voltage of 0.41 volts, about 12 times greater than that of the neat PVDF film. Nanoparticles affected the thermal degradation and crystallinity of the polymer composites most effectively, and the dielectric properties of the PVDF/Zn-Fe2O3 composite microfilms were also pronounced. The proposed simple and cost-effective approach to flexible microfilm fabrication suggests significant applications in wearable electronics.
ABSTRACT
Simplified and flexible fabrication methods, high output performance, and extreme flexibility of polymer-based nanocomposites represent versatile designs in self-powering devices for wearable electronics, sensors, and smart societies. Examples include polyvinylidene fluoride and its copolymers-based piezoelectric nanogenerators, green and recyclable triboelectric nanogenerators, etc. Advanced functionalities, multi-functional properties, and the extensive lifetime required for nanogenerators inspire researchers to focus on structural modifications of the polymeric materials, to fully exploit their performances. Phase separation is a physicochemical process in which polymeric phases rearrange, resulting in specific structures and properties, that ultimately influence mechanical, electronic, and other functional properties. This article will study the phase separation strategies used to modify the polymeric base, both physically and chemically, to generate the maximum electric power upon mechanical and frictional deformation. The effect of interfacial modification on the efficiency of the nanogenerators, chemical and mechanical stability, structural integrity, durable performance, and morphological appearance will be extensively covered in this review. Moreover, piezo- and triboelectric power generation have numerous challenges, such as poor resistance to mechanical deformation, reduced cyclic performance stability, and a high cost of production. These often depend on the method of developing the nanogenerators, and phase separation provides a unique advantage in reducing them. The current review provides a one-stop solution to understand and disseminate the phase separation process, types and mechanisms, advantages, and role in improving the piezoelectric and triboelectric performances of the nanogenerators.
ABSTRACT
The field of strain sensing involves the ability to measure an electrical response that corresponds to a strain. The integration of synthetic and conducting polymers can create a flexible strain sensor with a wide range of applications, including soft robotics, sport performance monitoring, gaming and virtual reality, and healthcare and biomedical engineering. However, the use of insulating synthetic polymers can impede the semiconducting properties of sensors, which may reduce sensor sensitivity. Previous research has shown that the doping process can significantly enhance the electrical performance and ionic conduction of conducting polymers, thereby strengthening their potential for use in electronic devices. However the full effects of secondary doping on the crystallinity, stretchability, conductivity, and sensitivity of conducting polymer blends have not been studied. In this study, we investigated the effects of secondary doping on the properties of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)/poly(vinyl alcohol) (PEDOT:PSS/PVA) polymer blend thin films and their potential use as strain sensors. The thin films were prepared using a facile drop-casting method. Morphology analysis using profilometry and atomic force microscopy confirmed the occurrence of phase segregation and revealed surface roughness values. This evidence provided a comprehensive understanding of the chemical interactions and physical properties of the thin films, and the effects of doping on these properties. The best films were selected and applied as sensitive strain sensors. EG-PEDOT:PSS/PVA thin films showing a significant increase of conductivity values from the addition of 1 vol% to 12 vol% addition, with conductivity values of 8.51 × 10-5 to 9.42 × 10-3 S cm-1. Our 12% EG-PEDOT:PSS/PVA sensors had the highest GF value of 2000 too. We compared our results with previous studies on polymeric sensors, and it was found that our sensors quantitatively had better GF values. Illustration that demonstrates the DMSO and EG dopant effects on PEDOT:PSS structure through bonding interaction, crystallinity, thermal stability, surface roughness, conductivity and stretchability was also provided. This study suggests a new aspect of doping interaction that can enhance the conductivity and sensitivity of PEDOT:PSS for device applications.
ABSTRACT
Theoretically, it is more challenging to anticipate the conversion and selectivity of a photochemical experiment compared to thermally generated reactivity. This is due to the interaction of light with a photoreactive substrate. Photochemical reactions do not yet receive the same level of broad analytical study. Here, we close this research gap by presenting a methodology for statistically forecasting the time-dependent progression of photoreactions using widely available LEDs. This study uses NiS/ZnO in perovskite (MAPbI3) solar cells as an additive (5 volume %). The effect of monolithic perovskite solar cells (mPSCs) on forecasting the wavelength of LEDs has been carefully investigated using various characterization methods, including X-ray diffraction (XRD) and Transmission electron microscopy (TEM). The photocatalytic activity was analyzed by measuring the voltage produced. Various factors like selectivity, stability and sensitivity were also examined. This work provides a new perspective to validate NiS/ZnO photocatalysts for predicting the wavelength of different light sources and to apply in photolithography.
