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1.
ACS Appl Mater Interfaces ; 13(18): 21748-21755, 2021 May 12.
Article in English | MEDLINE | ID: mdl-33913316

ABSTRACT

We demonstrate CuCrO2 (CCO) nanoparticle (NP)-polyimide (PI) composite film as a saturable absorber (SA) to regulate the output characteristics of passively Q-switched fiber laser at 1.55 µm. Based on the reverse saturable and saturable absorptions of the CCO NP-PI film, the passively Q-switched fiber laser expressed two stages with the increase of pump power for substantial performance enhancement. Reverse saturation absorption is observed to introduce appropriate cavity loss, which constructs effective pathways for promoting both the modulation depth and over threshold degree, as well as reducing the photon lifetime. In particular, our results realized the pulse duration and repetition rate compressing simultaneously for the first time. The second stage output laser exhibits a peak power of 1016 mW and a single pulse energy of 183 nJ, which are about 88 and 9 times higher than those of the first stage. Furthermore, the optical-optical conversion efficiency is up to 1270%. All of these can evidently demonstrate the importance of the appropriate cavity loss design for optimizing the Q-switched pulse laser output characteristics.

2.
Opt Express ; 27(18): 25718-25730, 2019 Sep 02.
Article in English | MEDLINE | ID: mdl-31510439

ABSTRACT

A passively Q-switched Er3+ doped fiber laser has been realized by using Zn doped hexagonal CuGaO2 (CGZO) nanoplates (NPs) as a saturable absorber (SA) for the first time. The CGZO NPs SA film exhibits strong saturable absorption property, meanwhile with a small nonsaturable loss of 5.179%, and the modulation depth is up to 40.821%. A stable passively Q-switched laser, which was centered at 1559.75 nm, was achieved, and the threshold was as low as 42 mW. With an increase of the pump power from 42mW to 361mW, the pulse duration decreases from 36 µs to 1.71 µs, and the maximum output power of 12.1 mW is achieved. Particularly, the optical-optical conversion efficiency of the Q-Switched laser based on CGZO NPs reached 3.76%. Due to whispering-gallery-mode (WGM) resonance in CGZO NPs, the nonlinear optical response of CGZO NPs has been enhancement. These findings demonstrate that CGZO NPs are promising SA for fabricating high-efficiency and low-threshold pulse lasers.

3.
Nanoscale ; 10(11): 5302-5308, 2018 Mar 15.
Article in English | MEDLINE | ID: mdl-29498730

ABSTRACT

In this paper, electrically driven whispering gallery mode (WGM) lasing was observed from ZnO single microwire (SMW)/p-Si heterojunctions operated at reverse bias. Current-voltage curve exhibits a non-ideal rectification characteristic with a turn-on voltage of about 0.8 V. When the reverse current of 20 mA was applied, several sharp lasing peaks with FWHM as narrow as ∼2 nm appeared in the spectra, which demonstrated that the gain was now large enough to enable the cavity resonant in ZnO SMW. The resonant process, lasing mode and quality factor (Q) were investigated via experiments and theory. The observed discrete lasing peak positions effectively matched the simulated lasing modes. The carrier transport process and light emission mechanism in heterojunctions are also discussed by energy band theory and interface defect.

4.
Phys Chem Chem Phys ; 18(30): 20812-8, 2016 Jul 27.
Article in English | MEDLINE | ID: mdl-27418413

ABSTRACT

This paper presents a systematic investigation of a ZnMgO/InN core-shell nanorods heterojunction device on a p-Si substrate. Here we demonstrated the heteroepitaxial growth of the well-aligned ZnMgO/InN core-shell nanorods structure, which enabled an increased heterojunction area to improve the carrier injection efficiency of nanodevices by plasma-assisted molecular beam epitaxy combined with metal-organic chemical vapor deposition. In situ X-ray photoelectron spectroscopy measurements were performed on the ZnMgO nanorods, the interface of ZnMgO/InN and the InN core-shell nanorods to fully understand the structure and working mechanism of the heterojunction device. The current transport mechanism has been discussed in terms of the characteristics of current-voltage and the energy band diagram of the n-InN/ZnMgO/p-Si heterojunction. At a low forward voltage, the current transport followed the dependence of I ∼ V(1.47), which was attributed to the deep-level assisted tunneling. When the forward voltage was larger than 10 V, the current followed the relation of I ∼ V(2) because of the radiative recombination process. In accordance with the above conclusion, the near-infrared electroluminescence of the diode could be observed after the forward bias voltage up to 11.6 V at room temperature. In addition, the size quantization effect and the intrinsic electron accumulation of the InN core-shell nanorods were investigated to explain the blueshift and broadened bandwidth. Furthermore, the light output power of about 0.6 microwatt at a fixed wavelength of 1500 nm indicated that our study will further provide a useful route for realizing the near-infrared electroluminescence of InN on Si substrate.

5.
Nanotechnology ; 26(13): 135201, 2015 Mar 27.
Article in English | MEDLINE | ID: mdl-25751419

ABSTRACT

Single layer graphene was employed as the electrode in quantum dot-light emitting diodes (QD-LEDs) to replace indium tin oxide (ITO). The graphene layer demonstrated low surface roughness, good hole injection ability, and proper work function matching with the poly (3,4-ethylenedioxythiophene):poly (styrenesulfonate) layer. Together with the hole transport layer and electron transport layer, the fabricated QD-LED showed good current efficiency and power efficiency, which were even higher than an ITO-based similar device under low current density. The result indicates that graphene can be used as anodes to replace ITO in QD-LEDs.

6.
Anal Chem ; 86(22): 11312-8, 2014 Nov 18.
Article in English | MEDLINE | ID: mdl-25367172

ABSTRACT

Multigas sensing is highly demanded in the fields of environmental monitoring, industrial production, and coal mine security. Three near-infrared emission wavelengths from PbSe quantum dots (QDs) were used to analyze the concentration of three gases simultaneously through direct absorption spectroscopy, including acetylene (C2H2), methane (CH4), and ammonia (NH3). The corresponding lower detection limits for the three gases were 20, 100, and 20 ppm, respectively, with an accuracy of 2%. This study demonstrates that QDs with tunable emissions have great potential for simultaneous and uninterfered multiplex gas analysis and detection due to the advantages of the easy tunability of multiplex emitting wavelengths from QDs.

7.
Nanotechnology ; 25(28): 285501, 2014 Jul 18.
Article in English | MEDLINE | ID: mdl-24971936

ABSTRACT

This work describes a micrometer resolution and plane-array temperature-sensing method using the photoluminescence (PL) of ZnCuInS/ZnSe/ZnS quantum dots (QDs). Heavy-metal-free QDs were directly deposited on a printed circuit board to analyze the surface temperature of the devices on the board. An optical fiber monochromator and a high-powered microscope were employed to fabricate a system which could collect temperature-dependent QD emissions from the micrometer area for the temperature measurements. This system realizes the imaging of the surface temperature distribution in the planar micrometer area. Temperature sensitivity of the PL intensity reached 0.66% °C(-1), and the relative error was less than 2%.

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