ABSTRACT
Molecular trimeric ruthenium carboxylate clusters (Ru3 clusters) have been introduced into the pore channels of mesoporous metal-organic framework chromium terephthalate [MIL-101(Cr)] by employing a facile two-step post-synthetic strategy in which diamine hooks anchored on the framework metal nodes of the MOF are used to covalently immobilize the Ru3 clusters. The catalytic activity of the isolated Ru3 clusters in the pore channels of the MOF was significantly improved compared to the bulk counterpart.
ABSTRACT
PURPOSE: The role of herniation pits as a radiographic indicator is still debated. This case-control study was to determine (1) the prevalence and sizes of herniation pits and (2) the relationship between herniation pits and femoral and acetabular bony morphology consistent with femoroacetabular impingement. METHODS: This comparative study was performed on 151 patients (151 hips; median patient age 46 years; range 16-73 years) with mechanical symptoms, who underwent multi-detector computed tomography (MDCT) arthrography (the symptomatic group), and an age-, gender-, site (left or right)-, and time (at diagnosis)-matched group of control patients that underwent multi-detector computed tomography due to an ureter stone (the asymptomatic group). Two orthopaedic surgeons reviewed images to evaluate the prevalence, sizes of herniation pits, and relationship with morphological abnormality. RESULTS: The prevalences of herniation pits in symptomatic and asymptomatic groups were 23.8 % (36/151) and 3.3 % (5/151), respectively (OR 9.14, 95 % CI 3.47-24.30; p < 0.001). Herniation pits were found to be significantly associated with pincer-type abnormality (p = 0.034), especially central acetabular retroversion (p < 0.001). CONCLUSIONS: This study shows that the prevalence of herniation pits is higher in symptomatic patients with femoroacetabular impingement, and herniation pits are associated with central acetabular retroversion. Furthermore, herniation pits were also found to be a useful predictor of pincer-type femoroacetabular impingement.
Subject(s)
Acetabulum/diagnostic imaging , Femoracetabular Impingement/diagnostic imaging , Femur Neck/diagnostic imaging , Adolescent , Adult , Aged , Arthrography , Case-Control Studies , Female , Femoracetabular Impingement/diagnosis , Humans , Male , Middle Aged , Multidetector Computed Tomography , Prevalence , Young AdultABSTRACT
PCM-10 is a porous phosphine coordination material based on Ca(II) and tris(p-carboxylated) triphenylphosphine. The material provides a unique 3-dimensional surface of P(III) Lewis base sites, which is ideal for post-synthetic functionalization. The addition of Au(I) yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature.
ABSTRACT
Among patients that underwent total knee arthroplasty from June, 1990 to January, 1999, 61 cases (44 patients) that could be followed for more than 10 years were included in this study. The patients were divided into a patellar retention group and a patellar resurfacing group, and were compared with regard to their clinical and radiological outcomes. In patients undergoing primary TKA, a selective patellar resurfacing protocol was used. The indications for patellar retention were a small patella, nearly normal articular cartilage, minimal preoperative patellofemoral pain, poor patellar bone quality, and young patient age. When patellar retention was performed, osteophytes of the patella were removed and marginal electrocauterization was carried out. There were 25 cases (20 patients) in the patellar retention group and 36 cases (29 patients) in the patellar resurfacing group. The mean follow-up period was 140.7 months in the patellar retention group and 149.0 months in the patellar resurfacing group. The selective patellar resurfacing with total knee arthroplasty had a favorable outcome;there were a significant difference noted between the 2 groups in the functional scores, which showed better outcomes in the patellar resurfacing group than in the patellar retention group.
