Chemically modified flubendazole carbon electrochemical sensor for aluminum determination in food stuff, Multivitamin syrup and real water samples supported by DFT calculations, IR and morphological tools.

Aluminum is a key component in nearly nourishment stuffs and medications. It is also found in treated drinking water in the form of reactive species, and aluminum salts are commonly utilized as flocculants in water treatment. Meanwhile, it was not thought to be a dangerous metal for people, but research showed a possible link with Alzheimer's disease, breast cancer, autism, and aluminum. Controlling the amount of aluminum in food processing, agriculture, and drinking water is crucial, thus newly synthesized Al(III) ion selective electrode based on innocuous reagent, flubendazole drug, has been developed. The electrode displayed Nernstian slopes of 20.11 0.47 mV decade-1 at 25 ± 1 °C, covering a wide concentration range of Al(III) from 1 × 10-7 to 1 × 10-1 mol L-1. The response mechanism is studied using IR, computational calculations, morphological tools. The developed sensor has been utilized to accurately measure Al(III) ions in genuine water samples, multivitamin syrup, and food stuff.

A validated potentiometric method for the rapid determination of chromium ions content in food samples using a portable graphite sensor.

Cr(III) has a vital role in the biological systems, and in many industrial and environmental processes, so the development of a selective, sensitive, and rapid method for its determination is a challenging goal. In this paper, an effective, selective, and inexpensive Cr(III) ions modified carbon paste electrode (MCPE) based on a simple ionophore named benazepril (BNZ) was developed and described. The proposed technique was validated using the EURACHEM guidelines. Our sensor shows a Nernstian slope of 19.20 ± 0.39 mV/decade in the range of 8.0 × 10-6-1.0 × 10-1 mol L-1with a quick response time (10 s) and can be applied for the measurements for at least 54 days with negligible change in the results. The proposed sensor has a stable potentiometric response in the pH range of 2.5-6.5 and has great selectivity towards Cr(III) ions over numerous inorganic cations. The Cr(III)-BNZ surface interaction was scrutinized by a scanning electron microscope (SEM). Lastly, the proposed electrode was applied for the determination of Cr(III) ions in various food samples, and the results were compared with the results of the inductively coupled plasma-optical emission spectroscopy (ICP-OES).