ABSTRACT
Side reactions and dendrite growth on the zinc metal anode surface seriously damage the shelf life and calendar life of Zn-based batteries. Here, an Al-complexed artificial interfacial layer is constructed on the Zn surface (denoted as Al-complex@Zn) by a low-cost, facile, and scalable chemical method. The Al-complex interfacial layer improves the wettability of the electrolyte. Meanwhile, the Al-complex layer not only inhibits the side reaction by a physical barrier on the Zn surface but also regulates the zinc-ion flux to realize the uniform deposition of Zn2+. The Zn//Zn symmetric cell with an Al-complex layer has realized an ultralong cycle life of 2400 h and an extremely low polarization voltage of 20 mV (1 mA cm-2, 0.5 mAh cm-2), surpassing those reported in most literature. Furthermore, when an Al-complex@Zn//NaV3O8·1.5H2O (NVO) full cell is assembled, a high capacity retention of 92.5% is achieved over 1000 cycles at a current density of 4 A g-1. This work provides a facile and low-cost strategy on the modification of zinc anode to realize long-cycled aqueous Zn-ion batteries.
ABSTRACT
The lithium-sulfur (Li-S) battery has received a lot of attention because it is characterized by high theoretical energy density (2,600 Wh/kg) and low cost. Though many works on the "shuttle effect" of polysulfide have been investigated, lithium metal anode is a more challenging problem, which leads to a short life, low coulombic efficiency, and safety issues related to dendrites. As a result, the amelioration of lithium metal anode is an important means to improve the performance of lithium sulfur battery. In this paper, improvement methods on lithium metal anode for lithium sulfur batteries, including adding electrolyte additives, using solid, and/or gel polymer electrolyte, modifying separators, applying a protective coating, and providing host materials for lithium deposition, are mainly reviewed. In addition, some challenging problems, and further promising directions are also pointed out for future research and development of lithium metal for Li-S batteries.
