3D-printable, lightweight, and electrically conductive metal inks based on evaporable emulsion templates jammed with natural rheology modifiers.

Conductive metal inks with 3D-printable rheological properties have gained considerable attention, owing to their potential for manufacturing 3D electronics. Typically, such inks are formulated with high volume fractions of metal particles to achieve both rheological and electrical percolation. However, this leads to a high product cost and weight, making this approach potentially undesirable for practical application. In this study, naturally occurring ingredients, i.e., bee pollen microparticles (BPMPs) and citric acids (CAs), are used to produce a jammed hexane-in-aqueous suspension-type emulsion with controllable viscoelasticity as a template for conductive metal particles. Correspondingly, it is possible to develop 3D-printable, lightweight, and conductive inks. The BPMPs and CAs, as rheology modifiers, facilitate the 3D printability of the ink. After drying, the ink forms 3D networks without macroscopic discontinuities. Hexanes co-dispersed with BPMPs and CAs in the aqueous continuous phase improve the ink rheological processability and create internal macropores within the 3D-printed structure upon evaporation under ambient conditions, decreasing the product density. A conductive copper ink based on the emulsion template shows excellent 3D printability and electrical percolation at low metal loadings (<10 vol%); moreover, the printed ink with the optimized formulation has a remarkably low density (<2 g âˆ™ cm-3).

A pickering emulsion stabilized by chlorella microalgae as an eco-friendly extrusion-based 3D printing ink processable under ambient conditions.

Three-dimensional (3D) printing technology is actively utilized in various industrial fields because it facilitates effective and customizable fabrication of complex structures. An important processing route for 3D printing is the extrusion of inks in the form of colloidal suspensions or emulsions, which has recently attracted considerable attention because it allows for selection of a wide range of printing materials and is operable under ambient processing conditions. Herein, we investigate the 3D printability of complex fluids containing chlorella microalgae as an eco-friendly material for 3D printing. Two possible ink types are considered: aqueous chlorella suspensions and emulsions of oil and water mixtures. While the aqueous chlorella suspensions at high particle loading display the 3D-printable rheological properties such as high yield stress and good shape retention, the final structures after extruding and drying the suspensions under ambient conditions show a significant number of macroscopic defects, limiting their practical application. In contrast, the 3D structures produced from the oil-in-water Pickering emulsions stabilized by chlorella microalgae, which are amphiphilic and active at the oil-water interface, show significantly reduced defect formation. Addition of a fast-evaporable oil phase, hexane, is crucial in the mechanisms of enhanced cementation between the individual microalgae via increased inter-particle packing, capillary attraction, and hydrophobic interaction. Furthermore, addition of solid paraffin wax, which is crystalline but well-soluble in the hydrocarbon oil phase under ambient conditions, completely eliminates the undesirable defect formation via enhanced inter-particle binding, while maintaining the overall rheological properties of the emulsion. The optimal formulation of the Pickering emulsion is finally employed to produce a 3D scaffold of satisfactory structural integrity, suggesting that the chlorella-based ink, in the form of an emulsion, has potential as an eco-friendly 3D printing ink processable under ambient conditions.