ABSTRACT
The present study focuses on enhancing the mechanical, thermal, and degradation behavior of polylactic acid (PLA) by adding carbon nanotubes (CNTs) with different concentrations of 0.5, 1, 3, and 5%. The CNTs were prepared using catalytic chemical vapor deposition, and the prepared PLA/CNTs nanocomposite films were characterized using techniques such as FT-IR, Raman spectroscopy, TGA, SEM, and XRD. The distinct diffraction patterns of multi-walled carbon nanotubes (MWCNTs) at 2θ angles of 25.7° and 42.7° were no longer observed in the prepared nanocomposites, indicating uniform dispersion of MWCNTs within the PLA matrix. The presence of MWCNTs enhanced the crystallinity of PLA as the CNT loading increased. Mechanical tests demonstrated that incorporating CNTs positively influenced the elongation at the break while decreasing the ultimate tensile strength of PLA. The PLA-3%CNTs composition exhibited the highest elongation at break (51.8%) but the lowest tensile strength (64 MPa). Moreover, thermal gravimetric analysis confirmed that the prepared nanocomposites exhibited greater thermal stability than pure PLA. Among the nanocomposites, PLA-5% CNTs exhibited the highest thermal stability. Furthermore, the nanocomposites demonstrated reduced surface degradation in accelerated weathering tests, with a more pronounced resilience to UV radiation and moisture-induced deterioration observed in PLA-3% CNTs.
ABSTRACT
Facile solvothermal techniques were used to manufacture ZnS/1T-2H MoS2 nanocomposite (ZMS) with outstanding adsorption-photocatalytic activity. The formed catalyst was characterized by different tools; XRD, HR-TEM, EDX, FTIR, Raman, N2adsorprion/desorption, Zeta potential, PL,and XPS. The analysis provided the formation on mixed phase of metallic 1Tand 2H phases. ZMS has a high porosity and large specific surface area, and it has a high synergistic adsorption-photocatalytic degradation effect for MB, with a removal efficiency of ≈100% in 45 minutes under visible light irradiation. The extraordinary MB removal efficiency of ZMS was attributed not only to the high specific surface area (49.15 m2/g) and precious reactive sites generated by ZMS, but also to the formation of 1T and 2H phases if compared to pristine MoS2 (MS). The best adsorption affinity was induced by the existance of 1T phase. The remarkably enhanced photocatalytic activity of ZMS nanocomposite can be ascribed to the 2D heterostructure which enhances the adsorption for pollutants, provides abundant reaction active sites, extends the photoresponse to visible light region.
