1.
Org Biomol Chem
; 8(3): 600-6, 2010 Feb 07.
Article
in English
| MEDLINE
| ID: mdl-20090976
ABSTRACT
A general method for the synthesis of a novel class of oligomers, comprising alpha-hydroxy phenylphosphinic acid building blocks, is reported. A series of dimeric alpha-hydroxy phenylphosphinates are analyzed by a combination of NMR spectroscopy, X-ray crystallography and computational methods.
Subject(s)
Dimerization , Molecular Conformation , Organophosphorus Compounds/chemistry , Polymers/chemistry , Polymers/chemical synthesis , Carbon/chemistry , Hydrogen Bonding , Models, Molecular , Phosphorus/chemistry , Protein Folding , Stereoisomerism , Thermodynamics
2.
J Org Chem
; 69(19): 6500-3, 2004 Sep 17.
Article
in English
| MEDLINE
| ID: mdl-15357619
ABSTRACT
Alpha-ketophosphonates are prepared by a [3,3]-sigmatropic shift of enolphosphonates.