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Int J Biol Macromol ; 256(Pt 1): 128114, 2024 Jan.
Article in English | MEDLINE | ID: mdl-37979750

ABSTRACT

In this study, waterborne UV-curable coatings with self-healing properties based on transesterification were prepared using renewable biomass resources for anti-corrosion application. Tung oil (TO)-based oligomer (TMHT) was synthesized through Diels-Alder reaction of TO with maleic anhydride, subsequent ring opening reaction with hydroxyethyl acrylate (HEA), and final neutralize reaction with triethylamine. A series of waterborne UV-curable coatings were prepared from cellulose nanofibrils (CNF) stabilized TMHT-based Pickering emulsions after drying and UV light-curing processes. It is suggested that CNF significantly improved the storage stability of Pickering emulsions. The obtained waterborne UV-curable coatings with CNF of 1-3 wt% exhibited remarking coating and mechanical performance (pencil hardness up to 5 H, adhesion up to 2 grade, flexibility of 2 mm, tensile strength up to 11.6 MPa, etc.), great transmittance (82.3 %-80.8 %) and great corrosion resistance (|Z|0.01Hz up to 5.4 × 106 Ω·cm2). Because of the presence of the dynamic ester bonds in TMHT, the coatings exhibited excellent self-healing performance (78.05 %-56.34 %) at 150 °C without catalyst and external force. More importantly, the |Z|0.01Hz of the self-healing coating was higher than that of the scratched coating, indicating that the self-healing performance could extend the service life of the coating in corrosion resistant application.


Subject(s)
Plant Oils , Prunella , Emulsions , Biomass , Cellulose
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