1.
Inorg Chem
; 48(18): 8659-61, 2009 Sep 21.
Article
in English
| MEDLINE
| ID: mdl-19689104
ABSTRACT
A rare in situ metal/ligand reaction has been observed during the assembly of a manganese-coordination polymer under solvothermal conditions, which leads to double C-C coupling on CHCl(3) involving cleavage of three C-Cl bonds and the formation of two new C-C bonds at the same carbon center.
Subject(s)
Carbon/chemistry , Chloroform/chemistry , Manganese/chemistry , Organometallic Compounds/chemistry , Polymers/chemistry , Ligands , Magnetic Resonance Spectroscopy , Methylation , Molecular Structure , Pyridines/chemistry , Solvents/chemistry , Spectrometry, Mass, Electrospray Ionization , Temperature
2.
3.
Inorg Chem
; 46(15): 5814-6, 2007 Jul 23.
Article
in English
| MEDLINE
| ID: mdl-17256851
ABSTRACT
Reaction of a semirigid ligand with two octahedral metal ions with restricted coordination symmetry afforded metalated container complexes showing trigonal or tetragonal outer shapes and inner cavities.