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Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications.
Mohapatra, Aiswarya Abhisek; Yual, Waleed Kuar; Zhang, Yadong; Samoylov, Anton Aleksandrovich; Thurston, Jonathan; Davis, Casey M; McCarthy, Declan P; Printz, Adam D; Toney, Michael F; Ratcliff, Erin L; Armstrong, Neal R; Greenaway, Ann L; Barlow, Stephen; Marder, Seth R.
Chem Commun (Camb) ; 60(8): 988-991, 2024 Jan 23.
Article in English | MEDLINE | ID: mdl-38167668

ABSTRACT

Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

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