Shock or opportunity? Unveiling the effect of low-carbon transition on employment.

The stabilization of growth and preservation of employment are the primary objectives of the current new economic normal. Investigating whether the low-carbon transition can be an opportunity or a shock for employment expansion in green development requires thorough examination. This study utilizes multi-temporal difference-in-difference (DID) models, analyzing comprehensive panel data from China (2007-2019) to assess the impact of the Low-carbon City Pilot (LCCP) policy on employment at meso-regional and micro-firm levels. Empirical findings robustly reveal that LCCP significantly boosts employment, with average treatment effects of approximately 0.548% and 5.892% at regional and firm scales, respectively. Positive impacts vary based on ownership, location, industry type, and energy consumption within enterprises. Notably, state-owned enterprises, those in the eastern region, engaged in secondary industries, and with high energy consumption experience pronounced positive effects. Mechanism analysis further reveals that LCCP boosts employment via promoting government environmental subsidies and expanding enterprise investment scale to create more jobs. These findings provide policy recommendations for further promoting low-carbon transition and expanding employment to achieve the win-win goal of sustainable development.

Lattice dynamics and heat transport in zeolitic imidazolate framework glasses.

The glassy state of zeolitic imidazolate frameworks (ZIFs) has shown great potential for energy-related applications, including solid electrolytes. However, their thermal conductivity (κ), an essential parameter influencing thermal dissipation, remains largely unexplored. In this work, using a combination of experiments, atomistic simulations, and lattice dynamics calculations, we investigate κ and the underlying heat conduction mechanism in ZIF glasses with varying ratios of imidazolate (Im) to benzimidazolate (bIm) linkers. The substitution of bIm for Im tunes the node-linker couplings but exhibits only a minor impact on the average diffusivity of low-frequency lattice modes. On the other hand, the linker substitution induces significant volume expansion, which, in turn, suppresses the contributions from lattice vibrations to κ, leading to decreased total heat conduction. Furthermore, spatial localization of internal high-frequency linker vibrations is promoted upon substitution, reducing their mode diffusivities. This is ascribed to structural deformations of the bIm units in the glasses. Our work unveils the detailed influences of linker substitution on the dual heat conduction characteristics of ZIF glasses and guides the κ regulation of related hybrid materials in practical applications.

Heat Transport in Clathrate Hydrates Controlled by Guest Frequency and Host-Guest Interaction.

The underlying mechanism of common limited lattice thermal conductivity (κ) in energy-related host-guest crystalline compounds has been an ongoing topic in recent decades. Here, the guest-triggered intrinsic ultralow κ of the representative xenon clathrate hydrate was investigated using the time domain thermoreflectance technique and theoretical calculations. The localized guest modes were observed to hybridize with acoustic branches and severely limit the acoustic κ contribution. Besides, the strong mode coupling enables the reshaping of the overall lattice dynamics, especially for optical branches. More importantly, we identified that guest fillers prompt great phonon scattering in wide frequencies, which originates from both the guest-frequency-controlled enhancement of phase space and the host-guest-interaction-governed lattice anharmonicity. The extremely low guest frequency and strong host-guest interaction and coupling were thereby underlined to play vital but distinct roles in κ minimization. Our results unveil the dominant factors of guest reduction effects and facilitate the design of efficient thermoelectric or other thermal-related materials.