Advanced application of tea residue extracts rich in polyphenols for enhancing sludge dewaterability: Unraveling the role of pH regulation.

Tea polyphenols (TPs), as a kind of derivatives from tea waste, were employed as a novel environmentally friendly bio-based sludge conditioner in this study. The findings showed that when TPs were applied at a dosage of 300 mg g-1 DS, the sludge CST0/CST ratio significantly increased to 1.90. pH regulation was found to markedly affect the dewatering efficiency of sludge. At pH 4, the CST0/CST rose to 2.86, coupled with a reduction in the specific resistance to filtration (SRF) from 6.69 × 1013 m kg-1 to 1.43 × 1013 m kg-1 and a decrease in the moisture content (MC) from 90.57% to 68.75%. TPs formed complexes and precipitated sludge proteins, as demonstrated by changes in the extracellular polymeric substances (EPS), viscosity, zeta potential, and particles size distribution. The optimization significance of acidification treatment on sludge structure disintegration, the interaction of TPs with EPS, and the removal of sludge proteins were elucidated. The research provided an ideal approach for the integrated utilization of biomass resources from tea waste and highlighted the potential application of TPs as an environmentally friendly conditioner in sludge dewatering.

Leachate from municipal solid waste landfills: A neglected source of microplastics in the environment.

Over the past decade or so, microplastics (MPs) have received increasing attention due to their ubiquity and potential risk to the environment. Waste plastics usually end up in landfills. These plastics in landfills undergo physical compression, chemical oxidation, and biological decomposition, breaking down into MPs. As a result, landfill leachate stores large amounts of MPs, which can negatively impact the surrounding soil and water environment. However, not enough attention has been given to the occurrence and removal of MPs in landfill leachate. This lack of knowledge has led to landfills being an underestimated source of microplastics. In order to fill this knowledge gap, this paper collects relevant literature on MPs in landfill leachate from domestic and international sources, systematically summarizes their presence within Asia and Europe, assesses the impacts of landfill leachate on MPs in the adjacent environment, and particularly discusses the possible ecotoxicological effects of MPs in leachate. We found high levels of MPs in the soil and water around informal landfills, and the MPs themselves and the toxic substances they carry can have toxic effects on organisms. In addition, this paper summarizes the potential impact of MPs on the biochemical treatment stage of leachate, finds that the effects of MPs on the biochemical treatment stage and membrane filtration are more significant, and proposes some novel processes for MPs removal from leachate. This analysis contributes to the removal of MPs from leachate. This study is the first comprehensive review of the occurrence, environmental impact, and removal of MPs in leachate from landfills in Asia and Europe. It offers a comprehensive theoretical reference for the field, providing invaluable insights.

Progress of improving waste activated sludge dewaterability: Influence factors, conditioning technologies and implications and perspectives.

Large amounts of waste activated sludge (WAS) as a by-product generated from the biological treatment in wastewater treatment plants (WWTPs) is of high moisture content (MC), organic pollutants, heavy metals and pathogenic bacteria, it may cause serious environmental ecological risk without appropriate disposal. More than one half of the total operation cost is accounted for sludge disposal in a WWTP. Dewatering is an essential and important step during the sludge treatment and disposal process for it could efficiently reduce its volume, and be beneficial to the subsequent treatment and disposal of sludge. However, sludge should be conditioned before mechanical dewatering because of its high hydrophilicity. In this work, it presented a comprehensive review on sludge dewatering including summarizing the dewaterability measurement indexes, affecting factors, conditioning technologies, the improvement mechanisms. Finally, based on the eventual disposal and low carbon emission target, the implications and perspectives development of sludge conditioning were discussed. Based on the above discussion, there is no unified theoretical insight of the improvement mechanism of sludge dewaterability. In addition, the relationship between the microstructure of organic matters in sludge floc and the dewaterability should be deepened. Especially, how to choose the optimal conditioning technology for sludge dewatering lies in the physical and chemical properties of sludge, however, the carbon emission of the conditioning and dewatering process also needs to be considered. Accordingly, green, low-cost and organic conditioning agents are the direction of future research, and the establishment of automatic operating system and real-time evaluation index system is the key challenge.

Synergetic Theory of Information Entropy Based on Failure Approach Index for Stability Analysis of Surrounding Rock System.

It is generally acknowledged that the stability evaluation of surrounding rock denotes nonlinear complex system engineering. In order to accurately and quantitatively assess the safety states of surrounding rock and provide a scientific basis for the prevention and control of surrounding rock stability, the analysis method of the synergetic theory of information entropy using the failure approach index has been proposed. By means of deriving the general relationship between the total two-dimensional plastic shear strain and the total three-dimensional plastic shear strain and obtaining the numerical limit analysis step of the plastic shear strain, the threshold value of the ultimate plastic shear strain can be determined, which has provided the key criterion for the calculation of the information entropy based on the failure approach index. In addition, combining with the synergetic theory of the principle of maximum information entropy, the evolution equation of the excavation step and information entropy based on the failure approach index of the surrounding rock system in underground mining space are established, and the equations of the general solution and particular solution as well as the expression of the destabilizing excavation step are given. To account for this, the method is applied to analyze the failure states of the floor surrounding rock after the mining of the 71 coal seam in Xutuan Coal Mine and involve the disturbance effect and stability control method of the underlying 72 coal seam roof from the macroscopic and microscopic aspects. Consequently, the validity of the analysis method of synergetic theory of information entropy based on the failure approach index has been verified, which presents an updated approach for the stability evaluation of surrounding rock systems that is of satisfactory capability and value in engineering applications.

Distribution, removal and ecological risk assessment of antibiotics in leachate from municipal solid waste incineration plants in Shanghai, China.

Leachate from Municipal Solid Waste (MSW) incineration plants contains multiple antibiotics. However, current knowledge of antibiotics in such leachate is very limited compared to landfill leachate. In this study, the distribution, removal and ecological risks of 8 sulfonamides (SAs), 4 quinolones (FQs), and 4 macrolides (MLs) antibiotics in leachate from three MSW incineration plants in Shanghai were investigated. The results showed that 12 types of target antibiotics were detected at high concentrations (7737.3-13,758.7 ng/L) in the fresh leachate, exceeding the concentrations reported for landfill leachate. FQs were the dominant antibiotics detected in all three fresh leachates, accounting for >60 % of the total detected concentrations. The typical "anaerobic-anoxic/aerobic-anoxic/aerobic-ultrafiltration" treatment process removed the target antibiotics effectively (89.0 %-93.4 %), of which the anaerobic unit and the primary anoxic/aerobic unit were the most important antibiotic removal units. Biodegradation was considered to be the dominant removal mechanism, removing 78.11 %-92.37 % of antibiotics, whereas sludge adsorption only removed 1.02 %-10.89 %. Antibiotic removal was significantly correlated with leachate COD, pH, TN, and NH3-N, indicating that they may be influential factors for antibiotic removal. Ecological risk assessment revealed that ofloxacin (OFX) and enrofloxacin (EFX) in the treated leachate still posed high risks to algae and crustaceans. This research provides insights into the fate of antibiotics in leachate.

Effect of thermal hydrolysis pretreatment on the stabilization of sludge with different solid contents during autothermal thermophilic aerobic digestion.

Sludge stabilization was affected by solid content during autothermal thermophilic aerobic digestion (ATAD). Thermal hydrolysis pretreatment (THP) could alleviate the issues of high viscosity, slow solubilization and low ATAD efficiency caused by increased solid content. The influence of THP on the stabilization of sludge with different solid contents (5.24%-17.14%) during ATAD was investigated in this study. The results demonstrated that stabilization was achieved with volatile solid (VS) removal of 39.0%-40.4% after 7-9 days of ATAD for sludge with solid content of 5.24%-17.14%. The solubilization of sludge with different solid contents reached 40.1%-45.0% after THP. The rheological analysis indicated that the apparent viscosity of sludge was obviously reduced after THP at different solid contents. The increase in fluorescence intensity of fulvic acid-like organics, soluble microbial by-products and humic acid-like organics in the supernatant after THP and the decrease in fluorescence intensity of soluble microbial by-products after ATAD were detected by excitation emission matrix (EEM). The molecular weight (MW) distribution in the supernatant elucidated that the proportion of 50 kDa < MW < 100 kDa increased to 16%-34% after THP and the proportion of 10 kDa < MW < 50 kDa decreased to 8%-24% after ATAD. High throughput sequencing showed that the dominant bacterial genera shifted from Acinetobacter, Defluviicoccus and Norank_f__norank_o__PeM15 to Sphaerobacter and Bacillus during ATAD. This work revealed that solid content of 13%-17% was appropriate for efficient ATAD and rapid stabilization under THP.

Roles of catalytic ozonation by bimetallic Fe/Ce loading sludge-derived biochar in amelioration of sludge dewaterability: Performance and implementation mechanisms.

In this study, an environmentally friendly alternative was developed using catalytic ozonation by sludge-derived biochar loaded with bimetallic Fe/Ce (O3/SBC-FeCe) for enhanced sludge dewatering. The results indicated that the lowest capillary suction time (CST) of 20.9 s and water content of dewatered sludge cake (Wc) of 64.09% were achieved under the dosage of 40 mg O3/g dry solids (DS) and 0.4 g SBC-FeCe/g DS which were considered as the optimum condition. In view of excellent electron exchanging capacity of SBC-FeCe with rich Lewis acid sites and conversions of valence sates of Fe and Ce, more O3 were decomposed into reactive oxygen species under the catalytic action of SBC-FeCe, which strengthened oxidizing capacity. Enhanced oxidation rendered sludge cells inactivation and compact network structure rupture releasing intracellular water and organic substances. Subsequently, hydrophilic organic matters were attacked and eliminated lessening sludge viscosity and colloidal forces and intensifying hydrophobicity and flowability. In addition, changes of sludge morphology suggested that sludge roughness was alleviated, structural strength and compressibility were raised and porous and retiform structure was constructed providing channels for water outflow by adding skeleton builder of SBC-FeCe. Overall, the synergistic interaction of strengthened oxidation and skeleton construction improved sludge dewaterability.

Successive choline addition enhancing the methanogenesis of waste activated sludge anaerobic digestion: Insight from hydrophilicity, electrochemical performance and microbial community.

Anaerobic digestion (AD) is a promising technology to treat waste-activated sludge, previous study proved that methane production could be enhanced with the addition of choline, this work aimed to solve the problem of rapid biodegradability of choline in the AD process by changing its dosing method. With 0.75 g/L as the optimal choline dosing concentration, experimental results showed that successive choline dosing during the first 3-6 days of AD (experimental groups, EGs) performed better than the single dosing. The accumulative biogas production in EGs was increased by 35.55-36.73%, which could be caused by the simultaneous promotion of hydrolysis-acidification and methanogenesis processes. Especially, the electron exchange capacity of digested sludge in EGs was increased by 16.71-34.58%. In addition, the surface Gibbs free energy (△GSL) of sludge in EGs was 105.51-172.21% higher (corresponding to stronger hydrophilicity and repulsion), which might help disperse sludge flocs and improve mass transfer efficiency, and the △GSL values were positively correlated with the accumulative methane production (R2 = 0.7029). Microbiological analysis showed that microbial communities in EGs were richer and Methanosaeta was regarded as the dominant species with 15.93-30.08% higher relative abundance with choline addition. According to Kyoto Encyclopedia of Genes and Genomes (KEGG) pathway analysis, EGs were found to be more active in metabolism clusters. Collectively, these findings demonstrated that successive choline dosing during the first 3-6 days is an effective and novel method to enhance methane production in AD process.

Evaluation method of surrounding rock stability: Failure approach index theory of strain limit analysis for engineering applications.

In general, the ultimate parameter selection method of the failure approach index theory among the three-dimensional problems in geotechnical engineering is unclear in theory, and the symbol convention of the failure approach index in engineering calculation is contrary to the stipulation of the numerical simulation software. Hence, the values of the ultimate plastic shear strain are difficult to determine. To solve this problem, the criterion of positive tension and negative compression and the sequence of the principal stress σ1 ≤ σ2 ≤ σ3 are defined in this paper, and the expression of Mohr-Coulomb yield approach index id deduced. Under the condition of the principal strain sequence ε1 ≤ ε2 ≤ ε3, the formula of the ultimate shear strain is derived using the method of the ultimate strain analysis so as to obtain the simple expression and calculation method of the ultimate plastic shear strain, which has provided the calculation parameters for the three-dimensional ultimate plastic shear strain in the Mohr-Coulomb strain softening model and improved the failure approach index theory. In the light of the aforementioned theory, the ultimate strains of cubic concrete specimens are analyzed, and the obtained ultimate strain values are found consistent with previous research findings, which verifies the correctness and reliability of the ultimate strain analysis method. In addition, it is applied to the quantitative elastic-plastic failure analysis of the section coal pillar in Hengjin coal industry for determining its reasonable retainment width. Consequently, the research results can be embraced as the theoretical basis for the stability analysis of geotechnical materials and exhibits engineering application potential.

A novel conditioning approach for amelioration of sludge dewaterability using activated carbon strengthening electrochemical oxidation and realized mechanism.

Sludge dewatering is an essential process for reduction of sludge volume to decrease cost of ultimate disposal. In this study, a novel method using activated carbon (AC) strengthening electrochemical (EC) treatment (EC/AC) was adopted to improve greatly sludge dewaterability. It was shown that capillary suction time (CST) and water content of dewatered sludge cake (Wc) were reduced to 55.9 ± 1.24 s and 64.3 ± 1.23%, respectively, under the optimal conditions of EC voltage 20 V, EC time 30 min and 0.2 g/g dry solid (DS) AC. AC with rich functional groups as "the third electrode" intensified electrooxidation by forming multiple microelectrodes and electron transfer capacity and conductivity of sludge were strengthened by AC in EC system, which were illustrated by electrochemical analysis. It could be found that zeta potential and particle size were increased and surface roughness was reduced after EC/AC treatment intensifying sludge hydrophobicity. Form the results of rheological behaviors of sludge, flowability was strengthened and viscosity was weakened under the conditioning of EC/AC. Besides, colloidal force and gel-like network strength were lessened, which was also verified by organic matters and percentage of inviable cells. At the same time, intracellular matters were released and degraded and bound water was released converting into free water. In addition, sludge compressibility and structural strength were increased and porous structure was formed facilitating water outflow via addition of mesoporous AC as skeleton builder, which eventually led to an improved separation efficiency of solid-water and sludge dewaterability. The results of heavy metals suggested that sludge cake after EC/AC treatment was favorable for land application.

Accelerated stabilization of high solid sludge by thermal hydrolysis pretreatment in autothermal thermophilic aerobic digestion (ATAD) process.

Autothermal thermophilic aerobic digestion (ATAD) is a rapid biological treatment technology for sludge stabilization. To improve digestion efficiency and shorten stabilization time, thermal hydrolysis pretreatment was employed before ATAD of high solid sludge. The results showed that accelerated stabilization of high solid sludge (total solid = 10.1%) was achieved by thermal hydrolysis pretreatment with volatile solid removal efficiency of 40.3% after 8 days of ATAD, 11 days earlier than unpretreated sludge. The enhanced release and hydrolysis of intracellular organics resulted in a solubilization degree of 45.3%. The reduced sludge viscosity and improved fluidity after thermal hydrolysis facilitated mixing, aeration and organics degradation during ATAD. Excitation emission matrix analysis indicated that the fluorescence intensity of soluble microbial byproduct and tyrosine-like protein increased markedly after thermal hydrolysis and decreased after ATAD. The proportion of high molecular weight (MW > 10 kDa) substances in the supernatant increased significantly after thermal hydrolysis, while the low MW (MW < 1 kDa) substances decreased after ATAD. The significant difference in microbial composition between the pretreatment and control groups elucidated the accelerated sludge stabilization under thermal hydrolysis. This work provides an efficient and practical strategy to achieve rapid stabilization of high solid sludge.

A comprehensive study on simultaneous enhancement of sludge dewaterability and elimination of polycyclic aromatic hydrocarbons by Fe2+ catalyzing O3 process.

Simultaneous removal of polycyclic aromatic hydrocarbons (PAHs) in the process of enhancement of sludge dewaterability via oxidation of hydroxyl radicals (•OH) and flocculation of Fe3+ by Fe2+-catalyzing O3 were investigated as a novel research focus. The results showed that capillary suction time (CST) and water content of dewatered sludge cake (Wc) were reduced from 57.9 s and 85.1% to 13.6 s and 69.65% under the optimum usage of 60 mg/g dry solids (DS) O3 and 80 mg/g DS FeSO4, respectively. The relevant dewatering mechanism of Fe2+-catalyzing O3 treatment was elucidated. It was found that extracellular polymeric substances-bound (EPS-bound) and intracellular water was dramatically released through destroying sludge cells and EPS gel-like structure by produced •OH. In addition, the results of X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) and 13C NMR spectroscopy revealed that •OH oxidized and mineralized hydrophilic organic matters intensifying hydrophobicity of sludge surface. Moreover, Fe3+ generated by oxidation of Fe2+ agglomerated fragmented fine particles into large aggregates and decreased exposure of hydrophilic sites by neutralizing negative charge, which promoted water-solids separation. Meanwhile, sludge surface roughness was decreased which was determined by material type upright confocal laser microscope (CLM). As a consequence, •OH and Fe3+ were mainly responsible for enhancement of sludge dewaterability. Moreover, more than 40% of removal rate of PAHs was accomplished by Fe2+-catalyzed O3 treatment mitigating the environmental risks of PAHs spread.

Enhanced waste activated sludge dewaterability by the ozone-peroxymonosulfate oxidation process: Performance, sludge characteristics, and implication.

Dewatering treatment is an essential step to diminish sludge volume, cut down transportation costs, and improve subsequent disposal efficiency. In this study, ozone-peroxymonosulfate (O3/PMS) oxidation process was employed to ameliorate sludge dewaterability. Sludge capillary suction time (CST) and water content (Wc) of dewatered sludge cake could reduce from 70.5 s and 81.93% to 26.7 s and 65.65%, respectively, under the optimal dosage of 30 mg/g TS O3 and 0.4 mmol/g TS PMS. The increased sludge zeta potential, particle size, and fluidity promoted sludge dewatering performance apparently. The decreased hydrophilic, fluorescent EPS components and proteins/peptides-like + Lipids percentage in EPS as well as the ratio of α-helix/(ß-sheet + random coil) of treated EPS protein secondary structure was greatly responsible for the enhanced sludge dewaterability. SO4- and OH were detected in ozone-peroxymonosulfate process to crack sludge flocs, eliminate hydrophilic substances and liberate bound water. Moreover, the concentrations of both heavy metals and polycyclic aromatic hydrocarbons (PAHs) of sludge after O3/PMS conditioning were decreased, and the stability and toxicity of heavy metals were also reduced, except Zn. In conclusion, this work offered a comprehensive insight based on ozone-peroxymonosulfate (O3/PMS) advanced oxidation for improving the sludge dewaterability and environmental implication.

Influence of sludge organic matter on elimination of polycyclic aromatic hydrocarbons (PAHs) from waste activated sludge by ozonation: Controversy over aromatic compounds.

Ozonation has been widely used as a viable advanced oxidation process (AOP) for elimination of PAHs in waste activated sludge through effective sludge disintegration and abatement of organic pollutants. However, sludge organic matter (SOM) influences PAHs degradation during ozone treatment is still rarely understood. In this study, we investigated such an influence with the aid of solid-state 13C nuclear magnetic resonance (NMR) spectroscopy and the corresponding two-dimensional correlation analysis (2D-COS) strategy. The results showed that the degradation of SOM macromolecules in the order of aromatic substances > aliphatic carbon > α carbon > amides groups > O-alkyl upon ozone treatment. Moreover, the PAHs removal efficiency was positively correlated with the aromaticity of sludge (R2 = 0.84-0.98), while negative associated with its aliphaticity (R2 = 0.81-0.95). Lastly, humic acid (HA) was used as a proxy of aromatic SOM to further explore their interaction with PAHs in sludge matrix. The results revealed that freely dissolved (HA-D) and suspended particulates (HA-S) imposed distinctively different influence on ozone-based PAHs degradation. The HA-S facilitated the elimination of PAHs by 7.95 ± 0.11%, while those HA-D reduced the removal efficiency by 16.70 ± 0.13%.

Identifying the key sludge properties characteristics in Fe2+-activated persulfate conditioning for dewaterability amelioration and engineering implementation.

Fe2+-activated persulfate process has been introduced into sludge conditioning currently, however the key sludge properties characteristics are worthwhile comprehensively considering for the engineering implementation and management. The results indicated that both the optimal dosages of persulfate and Fe2+ were 0.6 mmol/gTS for sludge dewaterability amelioration, and the reduction efficiencies of capillary suction time (CST), specific resistance of filtration (SRF), and water content (Wc) of dewatered sludge cake reached to 90.5%, 97.2%, and 22.4%, respectively. Significantly, the persulfate and Fe2+ exerted distinctive roles in the conditioning process. The increased persulfate could promote the oxidatively disintegrated effect on sludge flocs, rendering the decrease of particle size. With the oxidative decomposition of the negatively charged biopolymers, sludge zeta potential rose gradually. However, Fe2+ contributed to more persulfate activation to generate free radicals, and the produced Fe3+ could further electrically neutralize the broken sludge fragments. The core mechanism of Fe2+-activated persulfate conditioning is "destroying and re-building" of sludge flocs. Noteworthily, EPS protein was oxidatively degraded more preferentially than EPS polysaccharide, and the decrease of the α-helix content of EPS protein was conducive to the enhancement of sludge dewaterability. Furthermore, the hydrophilic functional groups reduced clearly and element chemical states on sludge flocs altered pronouncedly, also the destroyed structure and microchannel facilitated the flowability of water. These findings provide theoretical and technical support for the practical engineering implementation of the Fe2+-activated persulfate conditioning process.

Insight into the roles of electrolysis-activated persulfate oxidation in the waste activated sludge dewaterability: Effects and mechanism.

Sludge dewatering, as one of the most important steps of sludge treatment, can facilitate transportation and improve disposal efficiency by reducing the volume of sludge. This study investigated the effects of electrolysis-activated persulfate oxidation on improving sludge dewaterability. The results indicated that the sludge capillary suction time (CST) and water content of dewatered sludge cake (Wc) reduced from 93.7 s and 87.8% to 9.7 s and 68.3% respectively at the optimized process parameters: electrolysis voltage of 40 V, electrolysis time of 20 min, and 1.2 mmol/g TS S2O82-. Correlation analysis revealed that the enhancement of sludge dewaterability was closely associated with the increased floc size and zeta potential, decreased protein content in three-layers extracellular polymeric substances (EPS) and viscosity (R = -0.868, p = 0.002; R = -0.703, p = 0.035; R ≥ 0.961, p < 0.001; R = 0.949, p < 0.001). Four protein fluorescence regions in EPS were analyzed by three-dimensional excitation-emission matrix parallel factor (3D-EEM-PARAFAC). The protein secondary structure was changed after the treatment, and the reduction of α-helix/(ß-sheet + random coil) indicated that more hydrophobic sites were exposed. Analysis by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) and rheological test demonstrated that the hydrophilic functional groups of the sludge were decreased and the sludge mobility was significantly enhanced after the treatment with electrolysis-activated persulfate oxidation. Moreover, bound water was converted to free water during SO4·- and ·OH generated by electrolysis-activated persulfate degraded EPS and attacked sludge cells. Meanwhile, scanning electron microscopy (SEM) images revealed that the treated sludge formed porous channel structures, which promoted the flowability of the water. These findings provide a new insight based on electrolysis-activated persulfate oxidation in sludge treatment for enhancing sludge dewaterability.

Treatment of fresh leachate by microaeration pretreatment combined with IC-AO2 process: Performance and mechanistic insight.

Fresh leachate is commonly featured with high concentrations of degradable organic matters, which can impede the performance of traditional biological treatment, especially the anaerobic reactor. Aiming at improving the biological treatment process of fresh leachate, this study creatively proposed a microaerobic-IC-AO2 (MAICAO2) process and compared it with traditional biological process, then optimized the operating conditions. Meanwhile, this work investigated the transformation rules and molecular compositions of dissolved organic matters (DOM) during MAICAO2 process, particularly the hazardous DOM (antibiotics). The innovative MAICAO2 process can effectively remove 99% chemical oxygen demand (COD), 91% total nitrogen (TN) and 91% ammonia (NH4+-N) during the operation time, and the removal efficiencies of COD, TN and NH4+-N in MAICAO2 process increased approximately 2%, 14% and 13% compared to ICAOAO process. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) confirmed that microaeration could ensure over 53% small molecular organic acids degrade before the subsequent anaerobic reaction so the system could resist the high concentration organic matters stress and improve the denitrification efficiency. Further analysis showed that different categories of antibiotics (including 6 sulfonamides, 4 tetracyclines, 2 macrolides, 4 quinolones and 2 chloramphenicols) could be effectively removed by MAICAO2 process with the total removal efficiency of 50%. This work proposed a new scenario for fresh leachate treatment by proposing the importance of the microaeration pretreatment during the biological treatment process.

Insights into the enhancement of waste activated sludge dewaterability using sodium dichloroisocyanurate and dodecyl dimethyl ammonium chloride: Performance, mechanism, and implication.

Sludge dewatering is essential for reduction of sludge volume to cut the cost of transportation and disposal. Combined application of sodium dichloroisocyanurate (DCCNa) and dodecyl dimethyl ammonium chloride (DDAC) was attempted to promote sludge dewatering performance and physicochemical properties for the first time in this work. The results showed that capillary suction time (CST) and moisture content of dewatered sludge cake (Mc) decreased to 15.9 s and 61.54% compared to 144.5 s and 90.39% of raw sludge, respectively, with the addition of optimal dosage of 150 mg DCCNa/g DS and 125 mg DDAC/g DS. The conditioning mechanism of combined treatment was elucidated by investigating the variations of extracellular polymeric substances (EPS) composition, flocs morphological structure, rheological behavior, moisture distribution and Fourier transform infrared (FTIR) of sludge. It could be found that sludge floc cells were decomposed and bound water was released after DCCNa treatment. The bound water content was further decreased with the presence of DDAC. In addition, DDAC not only increased the zeta potential and flowability of sludge, but also reduced the surface tension and interact with oxygen-containing functional groups in sludge. As a result, the sludge dewaterability was significantly improved. Moreover, the calorific value analysis of dewatered sludge cake indicated that combined conditioning of DCCNa and DDAC presented the advantage of incineration disposal.

The extent of sludge solubilization allows to estimate the efficacy of ozonation for removal of polycyclic aromatic hydrocarbons (PAHs) in municipal sewage sludge.

Ozone treatment has been proven as an effective technology for removing PAHs in municipal sewage sludge. However, given the complex interaction of PAHs with sludge extracellular polymeric substances (EPS), effective sludge disintegration is required to make PAHs more accessible to oxidants, which also affects PAHs partitioning. Here, we investigated two treatment systems, namely ozonation (ozone) and sequential hydrodynamic cavitation and ozonation (HC+ozone), under varied conditions, to determine whether the extent of sludge disintegration can estimate a measurable removal of PAHs. The results showed that both the PAHs removal efficiency and kinetics highly depended on pH and ozone dose. Although no significant removal of PAHs occurred during HC treatment, the observed rate constants for Σ16 PAHs removal in HC+ozone system were 1.2-1.4-fold higher than those obtained in ozone system under the same condition. The accelerated PAHs removal could be attributed to the reduced flocs size (80% smaller) and increased soluble EPS concentration (5-fold higher) with HC pretreatment. Lastly, a positive correlation was noted between the PAHs removal efficiency and soluble EPS concentration (R2 = 0.85), indicating the important role of dissolved and colloidal matter (DCM) for PAHs partitioning between aqueous and particulate phases.

Alleviating the nitrite stress on anaerobic ammonium oxidation by pyrolytic biochar.

The nitrite (NO2-) inhibition in anaerobic ammonium oxidation (anammox) process is widely reported. Here, the effects of three pyrolytic biochars (CS300, CS550 and CS800) were investigated to alleviate NO2- stress on anammox process under exposure of varied NO2--N concentrations (70, 200, 400 and 600 mg L-1). No nitrite inhibition was observed at 70 mg N L-1. However, the total nitrogen removal efficiency (TNREs) decreased with NO2--N concentration increased, while the biochar-amended groups achieved higher TNREs than the control (CK). At 200 mg N L-1, the TNREs were 60.2%, 99.0%, 98.5% and 86.6% for CK, CS300, CS550 and CS800, respectively. At 400 mg N L-1, the TNREs were 23.3%, 56.0%, 37.1% and 29.7% for CK, CS300, CS550 and CS800, respectively. At 600 mg N L-1 in which severe inhibition was observed, the TNREs were increased by 231% (p = 0.002), 149% (p = 0.014), and 51.0% (p = 0.166) for CS300, CS550 and CS800, respectively, as compared to CK, with the corresponding specific anammox activity increased by 3.1-, 2,0- and 1.1-folds, respectively. CS300 enriched the relative abundance of Candidatus Kuenenia and increased the gene copies of functional genes (hzsA, hdh, nirS and nirK). Besides, CS300 effectively alleviated the suppression of three membrane-associated enzyme complexes for anammox electron transport chain, indicating the possible contribution of redox-active moieties of CS300 to energy conversion metabolism for mitigating the NO2--N inhibition. This study provided an effective strategy for alleviating NO2--N stress by applying an environmentally compatible material (biochar) on anammox process.