Research on freeze-thaw and dry-wet durability of enzymatic calcification for surface protection.

The enzymatically induced carbonate precipitation (EICP) technique is currently studied for dust control because of the formation of cemented crust layer. In the present study, polyvinyl acetate (PVAc) was used with EICP together as the EICP-PVAc treatment to solidify dust soils. In addition, several treated dust soil areas always experience repeated freeze-thaw (FT) or dry-wet (DW) cycles, both of which result in the damage of structure. Therefore, the FT cycle test and the DW cycle test were conducted to study the durability of EICP-PVAc treatment. Results showed that both FT cycles and DW cycles affected the EICP-PVAc-treated dust soils. The wind-erosion resistance and rainfall-erosion resistance were impaired, and the surface strength decreased. However, the decreasing range resulted from the FT cycle was smaller than the decreasing range resulted from the DW cycle. It indicated the EICP-PVAc-treated dust soils had better FT durability, but the DW durability was worse. Moreover, a field test was used to study the durability of application of EICP-PVAc treatment in practical field test site. Based on the surface pattern observation after 9 months, the grasses in the treated area are in good growth condition; however, few grasses grew in the untreated area. The field test demonstrated that the combined EICP-PVAc and grass seeds treatment can ensure the long-term solidification effect and durability. The results lay a solid foundation for the applications of EICP-PVAc treatment to solidify dust soils for dust control.

Enhanced rainfall erosion durability of enzymatically induced carbonate precipitation for dust control.

Globally, most cities are facing severe challenges caused by dust pollution. Recently, the significant dust control application potential of the environmentally friendly enzymatically induced carbonate precipitation (EICP) has been demonstrated. However, repeated rainfall erosion negatively affects the long-term durability of several EICP treated areas. This study applied EICP and added either polyvinyl acetate (PVAc) or polyethylene glycol (PEG) to the cementation solution. The results showed that both PVAc and PEG could improve the shear resistance and rainfall-erosion resistance of treated dust soils. However, for repeated rainfall erosion, the surface strength and calcium carbonate (CaCO3) contents of samples still decreased to less than 250 kPa and 1.1%, respectively. Therefore, combined EICP-PVAc-PEG treatment was proposed and the rainfall-erosion durability of treated dust soils was further studied. With the EICP-PVAc-PEG treatment, the dust samples achieved better shear resistance, higher surface strength, and better repeated rainfall-erosion resistance. Considering cost, cementation effects, and the effects of repeated rainfalls, EICP-PVAc-PEG treatment with 50 g/L PVAc and 30 g/L PEG was most suitable for dust control. The combined EICP-PVAc-PEG treatment significantly suppressed the generation of dust and improved the rainfall-erosion durability.

Application of enzymatic calcification for dust control and rainfall erosion resistance improvement.

Globally, most cities are facing severe challenges associated with dust pollution and it is of great significance to propose an effective and environmentally friendly dust control method. This study used enzymatically induced calcite precipitation (EICP) technology for dust control. Moreover, polyvinyl acetate (PVAc) was added to the cementation solution to improve its rainfall erosion resistance. The results showed that the optimum ratio of urease solution to cementation solution differed according to the concentrations of reactants in the cementation solution. Under combined EICP and PVAc (50 g/L) treatment, the stability of the dust-slope significantly improved. Moreover, little dust soil loss was washed out by simulated rainfall because of the more stable spatial structure of CaCO3 precipitation. Furthermore, PVAc addition increased the surface strength of slopes, while the cemented layer became thinner. With this combined EICP and PVAc (50 g/L) treatment, in a field test, the treated area of the slope had higher surface strengths and stronger erosion resistance than untreated areas. These higher surface strengths were attributed to the smaller particle size, and the stronger cementing effect of grass seeds. These results demonstrated that EICP-PVAc treatment significantly controlled dust and mitigated surface erosion of dust-slopes. This represents promising potential for the prevention of dust pollution.