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Talanta ; 174: 514-520, 2017 Nov 01.
Article in English | MEDLINE | ID: mdl-28738616

ABSTRACT

3D binder-free CuO nanosheets wrapped nanofilms has been in situ synthesized on Cu substrate by a simple and facile procedure, with an aim of fabricating high-performance glucose sensor. The complex morphology that the nanosheet grown on Cu subtract evolved into nanofilms and eventually converged to nanowires, is benefit for the mass transport and electro-catalysis. Compared the ECSA of the CuO modified electrode to that of the bare Cu electrode, the effective surface area during the electro-catalysis of the CuO/Cu electrode is much larger. The glucose sensor based on CuO products exhibited high sensitivity (4201µAcm-2mM-1), low detection limit (0.5µmol/L) and quick response time (0.7s). And the stability and selectivity is also fantastic. According to the serum sample analysis, it transpires that the CuO/Cu sensor displayed excellent recovery compared to the concentration values measured by medial method. So this material shows great potential applications in glucose sensors.


Subject(s)
Biosensing Techniques/instrumentation , Copper/chemistry , Glucose/analysis , Nanotechnology/instrumentation , Nanowires/chemistry , Animals , Electrochemistry , Electrodes , Hydrogen-Ion Concentration , Limit of Detection , Mice , Oxidation-Reduction
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