[Temporal and Spatial Variation Characteristics and Source Analysis of Agricultural Non-point Source Pollution Load in Guangdong During the Past 20 Years].

The agricultural non-point source pollution (ANPSP) load in Guangdong province is very large and has a serious impact on the regional ecological environment. Inventory analysis was used to assess and analyze the temporal and spatial variation characteristics of the ANPSP load of Guangdong province during 1999-2019, and the sources of ANPSP were discussed, as well as the relationship between them. The results showed that, during the past 20 years, the total ANPSP pollution loads of Guangdong province decreased by 6.08%, and the pollution loads of chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) increased by -11.88%, 4.99%, and 26.17%, respectively. The input intensity of chemical fertilizers and pesticides increased by 112.19% and 60.38%, respectively. The Pearl River Delta had the highest ANPSP loads in Guangdong province, followed by those in northern, western, and eastern Guangdong. Livestock and poultry breeding were the main sources of COD, the total percent fertilizers and livestock and poultry breeding were the main sources of TN, and livestock and poultry breeding and aquaculture were the main sources of TP. In addition, the contribution of pollutants discharged from aquaculture showed an obvious increasing trend. There were certain differences in the pollution sources in different regions. In western Guangdong, northern Guangdong, and eastern Guangdong, livestock and poultry breeding were the main sources of COD and TP, and fertilizer was the main source of TN; by contrast in the Pearl River Delta, aquaculture had become the main source of TN and TP pollution loads. The correlation results showed that the decline in the total ANPSP in Guangdong province was mainly due to the increase in high urbanization rate and the decrease in the proportion of rural population. In general, there were stage changes in the time and differences in spatial characteristics and sources of ANPSP in Guangdong province. A combination of comprehensive treatment and targeted pollution treatment should be adopted, and fertilizer reduction measures and pollution treatment in the aquaculture should be strengthened in an all-around way, focusing on strengthening the treatment of pollution from aquaculture in the Pearl River Delta region and the treatment of rural life pollution in northern Guangdong.

Assessment of the long-term leaching characteristics of cement-slag stabilized/solidified contaminated sediment.

The use of stabilized/solidified (S/S) soils and sediments as sustainable construction materials is a global concern due to the potential risk of contaminant leaching including potentially toxic elements. The long-term leachability of four metals (Zn, Pb, Cd and As) in sediments mixed with OPC (Ordinary Portland Cement) and OPC/GGBS (Ground Granulated Blast Furnace Slag) binders were investigated through a combination of tank leaching tests and kinetic leaching models, with varying ranges of curing ages and ambient pH. The leaching data revealed that both binder compositions offer an excellent immobilization capacity for the four metals, while their releases are strongly pH-dependent and are a complex function of curing time. The partial replacement of OPC by GGBS is more effective for fixing Zn and As at pH of 1, Pb at pH of 7, Zn and Pb at pH of 10. Controlling leaching mechanisms and leachability indices were determined using nonlinear regression analysis and kinetic leaching models. The first-order diffusion model (FRDM) was the most applicable model for describing the leaching characteristics of these metals under the investigated cases, the leaching rate is controlled by surface wash-off initially and then by diffusion. The leachability indices indicate that the cement-slag S/S sediment can be regarded as an environmentally sustainable material with potential beneficial uses in construction.

Occurrence, fate and ecological risk of chlorinated paraffins in Asia: A review.

Chlorinated paraffins (CPs), complex mixtures of polychlorinated alkanes, are widely used in various industries and are thus ubiquitous in the receiving environment. The present study comprehensively reviewed the occurrence, fate and ecological risk of CPs in various environmental matrices in Asia. Releases from the production and consumption of CPs or CP-containing materials, wastewater discharge and irrigation, sewage sludge application, long-range atmospheric transport and aerial deposition have been found to be most likely sources and transport mechanisms for the dispersion of CPs in various environmental matrices, such as air, water, sediment, soil and biota. CPs can be bioaccumulated in biota and biomagnified through food webs, likely causing toxic ecological effects in organisms and posing health risks to humans. Inhalation, dust ingestion and dietary intake are strongly suggested as the major routes of human exposure. Research gaps are discussed to highlight the perspectives of future research to improve future efforts regarding the analysis of CPs, the environmental occurrence and elimination of CPs, the total environmental pressure, and the risks to organisms and populations.

[Characteristics and simulation of heat and CO2 fluxes over a typical cropland during the winter wheat growing in the North China Plain].

In order to study the surface energy budget of the cropland in North China Plain, this paper discussed the characteristics of heat and CO2 fluxes of the cropland during the winter wheat growing, and then simulated the dynamic change of the flux of heat and carbon by SiB2 (simple biosphere model Version2) based on the observational data from 2005-10-10 to 2006-06-10 of Weishan experimental station. The results showed that the heat and CO2 fluxes put up obvious inter-daily variations in the course of the wheat growing and their maximum appeared at around midday. The diurnal variations of them are obvious too, and the net radiation, latent heat flux and the heat flux of underlaying surface during the winter were minimum while they were maximum in the anthesis and maturation of wheat; and the sensible heat flux during the winter was maximum and it was minimum in the shooting and heading period of wheat; while the CO2 flux during the shooting and heading period of wheat was the maximum and it was minimum during the winter. Finally, SiB2 model was used to simulate the heat and CO2 fluxes and the surface temperature based on the data of Weishan observation station and the results showed that the model was good at simulating, the simulated net radiation, latent heat flux, sensible heat flux, the heat flux of underlaying surface, CO2 flux and surface temperature were shown to be basically in agreement with observations with their square of related coefficient being 0.985, 0.637, 0.481, 0.725, 0.499 and 0.877 respectively. In addition, the average simulated value of net radiation, latent heat flux and the heat flux of underlaying surface were lower than the observed value and others were higher than the observed ones. In addition, the fluxes and surface temperature were simulated by SiB2 in the different stages of winter wheat and the results showed that the accuracy of the model in the shooting and heading period of wheat was better than the other two stages and the leaf area index was sensitive to the model.