More proactive but less efficient: The effect of trait self-control on emotion regulation and its neural mechanisms.

Self-control is important for maintaining good health, acquiring achievement and happiness, and improving environmental adaptability. Trait self-control can affect the processing of emotional conflict in daily life and is associated with successful emotional regulation. In this study, the task functional magnetic resonance imaging (fMRI) technology was adopted to explore the emotion regulation processing and neural mechanism of individuals with different trait self-control levels. The results showed that: (a) Individuals with high self-control experienced the lower intensity of negative emotion when viewing negative emotional pictures than individuals with low self-control, showing spontaneous emotion regulation and significantly increased activity of executive control and emotion regulation networks of the brain; (b) Individuals with low self-control were more sensitive to negative emotion, and their emotion regulation effect under external instructions was better than that of individuals with high self-control. This suggests that individuals with high trait self-control were adept at using proactive control strategies to spontaneously regulate emotional conflict and experienced less emotional conflict accordingly. However, they were less effective than low self-control individuals in resolving emotional conflicts. These findings provide an important basis for our understanding of the nature and neural mechanism of self-control.

The positivity bias of Chinese temporal collective self: Evidence from the first-person perspective and the third-person perspective.

Objective: As a unique part of human thinking, people can project themselves into the past or the future for mental time travel. This study attempts to expand the temporal self into the domain of the collective self. Methods: We used an adapted temporal collective self-reference paradigm to probe into the positivity bias of temporal collective self in this study. In Experiment 1, the first-person perspective was adopted for the participants to conduct the temporal collective self-reference processing, and the third-person perspective was adopted for the temporal collective self-reference processing in Experiment 2. Results: The findings indicated that no matter from the first-person perspective or the third-person perspective, people show positivity bias in the trait adjectives judgment, response times and recognition rates during the temporal collective self-processing. Discussion: This study explores mental time travel on the level of collective self, and contributes to deepening the understanding of temporal collective self.

Self-processing characteristics from first-person and third-person perspectives in individuals with social anxiety disorder: insights into negative bias.

Background: As one of the most common psychological problems, social anxiety disorder (SAD) has lots of negative effects on the physical and mental development of individuals, such as decreasing the quality of interpersonal relationships, and even causing depression, suicidal ideation, etc., as well as leads individuals to generate mental illness stigma. The mental illness stigma that individuals perceive affects not only how they perceive themselves (first-person perspective) but also how they perceive others' appraisals of them (third-person perspective), which further exacerbates their anxiety symptoms. Objective: The study aims to explore the self-processing characteristics of individuals with social anxiety disorder from the first-person perspective and the third-person perspective. Methods: This study adopted the self-referential paradigm to conduct the recognition memory test on individuals with social anxiety disorder (30 participants in experiment 1) and individuals without social anxiety disorder (31 participants in experiment 2) in the two experiments. Results: In experiment 1, the recognition rate of individuals with social anxiety disorder under the self-appraisals condition was significantly higher than that under the condition of appraisals on mothers; in the three conditions of self-appraisals, appraisals on mothers and mothers' reflected appraisals, the recognition rate of negative trait adjectives was significantly higher than that of positive trait adjectives. In experiment 2, there was no significant difference in recognition rate of individuals without social anxiety disorder under the three conditions, and the recognition rate of positive trait adjectives was significantly higher than that of negative trait adjectives under the three conditions. Conclusion: Individuals with social anxiety disorder have a negative bias in self-processing and are more likely to focus on self-information, which is different from the self-positive bias of individuals without social anxiety disorder. This study can be beneficial to know the self-cognitive characteristics of individuals with social anxiety disorder, help them get rid of negative cognitive patterns, and remove the mental illness stigma.

Influence of peers' actual appraisals on moral self-representations of Chinese adolescents.

Adolescence is a vital period of developing a moral self. As individuals enter adolescence, peers become increasingly important to them. This study aimed to explore the influence of peers' actual appraisals on moral self-representations. Based on Looking Glass Self Hypothesis, peers' reflected appraisals usually have a mediating effect on peers' actual appraisals and self-appraisals. This study used the Chinese Moral Trait Words Rating Scale to investigate 160 dyads of Chinese adolescents (12-14 years old). The participants filled in the Self-Appraisals Questionnaire, Peers' Reflected Appraisals Questionnaire, and Peers' Actual Appraisals Questionnaire, respectively. The results showed that: (a) peers' actual appraisals indirectly affected self-appraisals through peers' reflected appraisals in the process of forming the moral self of early Chinese adolescents; (b) Chinese adolescents had a certain accuracy in peers' actual appraisals, but often underestimated their peers' actual appraisals of them. This study was conducive to understanding the influence of peers on forming adolescents' moral self in the context of collectivistic culture.

Enantioselective Amination of ß-Keto Esters Catalyzed by Chiral Calcium Phosphates.

A catalytic enantioselective amination of ß-keto esters using (S)-BINOL chiral calcium phosphate has been developed. The reaction produces chiral α-amino-ß-keto ester derivatives in most cases with moderate to excellent enantioselectivities (up to 99 %) and good yields (up to 99 %). This mild synthetic method highlights a low catalyst loading and high catalytic efficiency. When the substrate backbone was changed to 1-tetralone-derived ß-keto esters, unexpectedly high yields of selective redox products were obtained. The practicality of the reaction was realized by a scale-up without any significant loss in the enantioselectivity and yield. Chiral calcium phosphate was successfully recovered and reused for four runs, indicating its stability and high catalytic activity.

Valence of Temporal Self-Appraisals: A Comparison Between First-Person Perspective and Third-Person Perspective.

Mental time travel is one of the most remarkable achievements of mankind. On the one hand, people perceive past self, present self, and future self as a continuous unity; on the other hand, people have the ability to distinguish among the three types of temporal selves because there are different representations of them. In this study, we used an adapted temporal self-reference paradigm to explore the processing mechanism of different temporal selves. Temporal self-reference was performed from the first-person perspective in Experiment 1 and from the third-person perspective in Experiment 2. The results indicated that people showed a more positive bias toward future self compared with past self and present self no matter in the first-person perspective or third-person perspective. There was no difference in recognition rate among past self, present self, and future self. Compared with the first-person perspective, present self-processing in the third-person perspective was more abstract and generalized, which may reflect that the third-person perspective has the same distancing function as time. This study can deepen understandings on temporal self-appraisals from different perspectives.

Hierarchical Fe-Mn binary metal oxide core-shell nano-polyhedron as a bifunctional electrocatalyst for efficient water splitting.

Electrochemical water splitting is convinced as one of the most promising solutions to combat the energy crisis. The exploitation of efficient hydrogen and oxygen evolution reaction (HER/OER) bifunctional electrocatalysts is undoubtedly a vital spark yet challenging for imperative green sustainable energy. Herein, through introducing a simple pH regulated redox reaction into a tractable hydrothermal procedure, a hierarchical Fe3O4@MnOx binary metal oxide core-shell nano-polyhedron was designed by evolving MnOx wrapped Fe3O4. The MnOx effectively prevents the agglomeration and surface oxidation of Fe3O4 nano-particles and increases the electrochemically active sites. Benefiting from the generous active sites and synergistic effects of Fe3O4 and MnOx, the Fe3O4@MnOx-NF nanocomposite implements efficient HER/OER bifunctional electrocatalytic performance and overall water splitting. As a result, hierarchical Fe3O4@MnOx only requires a low HER/OER overpotential of 242/188 mV to deliver 10 mA cm-2, a small Tafel slope of 116.4/77.6 mV dec-1, combining a long-term cyclability of 5 h. Impressively, by applying Fe3O4@MnOx as an independent cathode and anode, the overall water splitting cell supplies a competitive voltage of 1.64 V to achieve 10 mA cm-2 and super long cyclability of 80 h. These results reveal that this material is a promising candidate for practical water electrolysis application.

The Influence of Actual Appraisals of Peers on the Self-Appraisals of Personality Traits for Chinese Late Adolescents: The Mediating Effect of Reflected Appraisals.

Reflected appraisals refer to the perceptions of individuals of how they are perceived by others. Numerous studies in cultural psychology have revealed that individuals in the Eastern collectivist culture show an interdependent self-construal, which depends much on the social culture. Hence, the research on reflected appraisals in the Eastern culture can improve the understanding of how the social environment shapes the self-perception of an individual. In this study, we aimed to explore the relationships among self-appraisals, reflected appraisals, and actual appraisals of peers of the Big Five personality for Chinese late adolescents. Participants were divided into 16 groups, with two to four people of each group who were familiar with each other. Each participant was told to fill out the questionnaires of reflected appraisals, actual appraisals of peers, and self-appraisals. Through analyzing 164 sets of data, the results showed the following: (a) The scores of reflected appraisals are significantly lower than that of the actual appraisals of peers. (b) The relationships among the reflected appraisals, actual appraisals of peers, and self-appraisals are distinct on different personalities. For extroversion, there are significant medium- to high-degree relationships among the three types of appraisals; while for the agreeableness, conscientiousness, emotional stability, and openness, self-appraisals are highly correlated with reflected appraisals, and reflected appraisals show a low-degree correlation with the actual appraisals of peers. (c) Reflected appraisals play a mediating role between actual appraisals of peers and self-appraisals. Our study suggests that individuals in Chinese culture generally underestimate how their peers perceive them. Furthermore, actual appraisals of peers affect the self-concepts of individuals through reflected appraisals. This study revealed the unique personality feature of self-modesty under the background of Chinese culture and the importance of peers on the development of self-concepts for Chinese late adolescents. This study can shed new light on the understanding of the development of self-concepts for late adolescents under different cultural backgrounds.

A Systematic Review Approach to Find Robust Items of the Zimbardo Time Perspective Inventory.

The Zimbardo Time Perspective Inventory (ZTPI) is one of the most well-known and widely used measures of time perspective. Various short versions were proposed to resolve the psychometric problems of the ZTPI. The present study conducted a systematic review to obtain 25 short versions, calculated the frequency of each item of the ZTPI in short versions, and hypothesized that the more frequent the item is, the more robust it becomes. The hypothesis was tested by assessing the structural validity and internal consistency of short forms with high, medium, and low frequent items in Chinese samples (575 children, 407 undergraduates, and 411 older adults). Structural validity and internal consistency analyses showed that the form with more frequent items had better psychometric properties; item frequencies were positively correlated with factor loadings. The results suggest that the systematic review is an effective approach to identify the robust items of the ZTPI. This approach is general and can be the basis to improve the psychometric properties of scales in social science.

The Memory Effect of Reflected Self-Appraisals on Different Types of Others.

The development of one's self-concept unfolds within early interactions with intimate significant others for childhood and adolescence. Previous studies suggest that people define themselves in part through internalized perceptions of other people's beliefs about them, known as reflected self-appraisals. Even in adulthood, reflected self-appraisals still remain critically influential on direct self-appraisals, and the affect might depend on the different types of others. In the present study, for the first time, we extend the classic "other-reference" paradigm to the field of reflected self-appraisals in order to examine whether there is a difference in the memory performance of reflected self-appraisals on different types of others in an early adult sample. In the experiment, participants were told to encode personality trait words by judging how different types of others (romantic partners, friends, and classmates) think about the participants themselves. After a retention interval, they received a surprise recognition memory test. The results showed that the memory performance of romantic partners is significantly better than that of friends and classmates, indicating that the memory performance of reflected self-appraisals varies across the others with different levels of closeness. Specifically, the closer the relationship between people and others is, the better the memory performance of reflected self-appraisals will be. Meanwhile, the speed and the encoding deepness of the reflected self-appraisals vary among different genders, leading to the gender effect of recognition memory. This study might help deepen our understanding on the development of self-concept in adulthood.

Chiral Phosphoric Acid Catalyzed Asymmetric Synthesis of Hetero-triarylmethanes from Racemic Indolyl Alcohols.

The direct enantioselective 1,4- and 1,8-arylations of 7-methide-7H-indoles and 6-methide-6H-indoles, respectively, generated in situ from diarylmethanols, with electron-rich arenes as nucleophiles, has been achieved in the presence of chiral phosphoric acids (CPAs). These two remote activation protocols provide an efficient approach for the construction of diverse hetero-triarylmethanes in high yields (up to 97 %) and with excellent enantioselectivities (up to 96 %). Mechanistically inspired experiments tentatively indicate that the catalytic enantioselective 1,4-addition as well as the formal SN 1 substitution could proceed efficiently in the similar catalytic systems. Furthermore, the modification of the catalytic system and diarylmethanol structure successfully deviates the reactivity toward a remote, highly enantioselective 1,8-arylation reaction. This flexible activation mode and novel reactivity of diarylmethanols expand the synthetic potential of chiral phosphoric acids.

Effects of Oxytocin on Facial Expression and Identity Working Memory Are Found in Females but Not Males.

Although oxytocin (OXT) has been shown to increase the ability of face perception and processing, no study has explored whether it could improve the performance of working memory for emotional expression information in males and females. Thus, we performed a double-blind, mixed-design, placebo-controlled study to investigate the effects of OXT on temporary maintenance/manipulation of facial information through a facial expression (EMO) vs. identity (ID) working memory task, both for males (N = 45) and females (N = 46). Our results showed that in female participants, OXT increased the accuracy of the recognition of faces displaying angry and happy emotions, in the EMO tasks, and also reduced the response time to negative emotional faces, in the ID task. However, the above effects were not present in male subjects. These results indicate that OXT may increase the efficiency of working memory in face processing and this trend is reflected in females rather than in males. This study provides novel evidence for the sexually dimorphic effects of OXT on social cognition.

Differential Effects of Oxytocin on Visual Perspective Taking for Men and Women.

Although oxytocin (OXT) has been shown to lead to reduced self-orientation, no study to date has directly and effectively weakened the egocentric tendencies in perspective taking tasks for both men and women. In this double-blind, placebo-controlled, mixed design study we investigated the effects of OXT on men and women in visual perspective taking tasks. The results showed that OXT shortened the differences in response time between men and women in all experimental conditions. In addition, after OXT administration, the difference in reaction time between judging from one's own perspective and judging from others' perspectives decreased in female participants; however, this effect was not present in males. This may indicate that under OXT treatment, women have a higher tendency to overcome interference from their position and mindset when judging others' perspectives. However, OXT did not affect participants' accuracy, which is possibility because the used task was not suited to detect performance improvements caused by OXT. In summary, the above results may indicate that OXT could increase perspective-taking abilities through reducing self-bias and increasing the perception of others; furthermore, this trend mainly affected women rather than men.

The Mindful Self: A Mindfulness-Enlightened Self-view.

This paper analyzes studies of mindfulness and the self, with the aim of deepening our understanding of the potential benefits of mindfulness and meditation for mental health and well-being. Our review of empirical research reveals that positive changes in attitudes toward the self and others as a result of mindfulness-enabled practices can play an important role in modulating many mental and physical health problems. Accordingly, we introduce a new concept-the "mindful self"-and compare it with related psychological constructs to describe the positive changes in self-attitude associated with mindfulness meditation practices or interventions. The mindful self is conceptualized as a mindfulness-enlightened self-view and attitude developed by internalizing and integrating the essence of Buddhist psychology into one's self-system. We further posit that the mindful self will be an important intermediary between mindfulness intervention and mental health problems, and an important moderator in promoting well-being. More generally, we suggest that the mindful self may also be an applicable concept with which to describe and predict the higher level of self-development of those who grow up in the culture of Buddhism or regularly engage in meditation over a long period of time.

Asymmetric dearomatic Diels-Alder reactions of diverse heteroarenes via π-system activation.

An asymmetric dearomatic Diels-Alder protocol for various heteroarenes, such as benzofuran, benzothiophene, or even furan, has been developed via π-system activation. This method involves in situ generation of formal trienamine species embedding a heteroaromatic moiety, and an array of chiral fused frameworks with high molecular complexity and skeletal diversity were efficiently constructed in good to excellent stereoselectivity by the catalysis of a cinchona-based primary amine.

Remote enantioselective Friedel-Crafts alkylations of furans through HOMO activation.

Catalytic asymmetric Friedel-Crafts alkylation is a powerful protocol for constructing a chiral C(sp(2))-C(sp(3)) bond. Most previous examples rely on LUMO activation of the electrophiles using chiral catalysts with subsequent attack by electron-rich arenes. Presented herein is an alternative strategy in which the HOMO of the aromatic π system of 2-furfuryl ketones is raised through the formation of a formal trienamine species using a chiral primary amine. Exclusive regioselective alkylation at the 5-position occurred with alkylidenemalononitriles, and high reactivity and excellent enantioselectivity (up to 95% ee) was obtained by this remote activation.

Task interference from event-based prospective memory: an event-related potentials study.

Event-related potentials (ERPs) technique was used to examine brain activity related to task interference during event-based prospective memory. The behavioral data indicated that there existed task interference. Data from ERPs record on non-prospective memory trials suggested that there were significant differences in the time windows of 200-300, 300-350, and 350-400 ms after the onset of stimulus. The ERP difference wave showed the maximum amplitude over the central site (Fz) with a peak latency of 250 ms (N250). The topographical map in the time window of 200-300 ms indicated that the components reflected activation mainly in the frontal lobe. The results seemed to support preparatory attentional processes and memory processes theory and revealed that frontal lobe was involved in monitoring, which caused task interference effect.