Low-temperature synthesis of porous organic polymers with donor-acceptor structure and ß-ketoenamine for photocatalytic oxidative coupling of amines.

In light of the widespread use of fossil fuels and the resulting environmental pollution, it is crucial to develop efficient photocatalysts for renewable energy applications that utilize visible light. Organic photocatalysts based on ß-ketoenamine offer several advantages, including facile preparation, high stability, structural controllability, and excellent photovoltaic properties. However, in previous studies, the synthesis of porous organic polymers (POPs) often involved long, high-temperature processes. In this study, POPs with donor (D)-acceptor (A) structure were constructed by utilizing various branched bridging groups and 2,4,6-triformylphloroglucinol, across multiple temperature gradients. Through adjustments in hydrothermal temperature, we successfully synthesized a series of POPs with varying enol-keto structure ratios. Among these POPs, the dimethoxybenzidine-POPs (DMDPOPs) with methoxy electron-rich branched chains exhibited superior photovoltaic performance, electron transfer rate, and photocatalytic activity compared to the dihydroxybenzidine-POPs (DHDPOPs) with electron-deficient hydroxyl branched chains. Notably, DMDPOP-30 demonstrated outstanding performance, achieving a conversion rate of 98% within 3 h. Additionally, other POPs exhibited favorable conversions (90%), further confirming the feasibility of this synthetic approach. Moreover, the synthesis of DMDPOP-30 was achieved under mild conditions at room temperature, highlighting its significant potential for practical applications.

Highly Efficient Transformation of Tar Model Compounds into Hydrogen by a Ni-Co Alloy Nanocatalyst During Tar Steam Reforming.

Hydrogen (H2) production from coal and biomass gasification was considered a long-term and viable way to solve energy crises and global warming. Tar, generated as a hazardous byproduct, limited its large-scale applications by clogging and corroding gasification equipment. Although catalytic steam reforming technology was used to convert tar into H2, catalyst deactivation restricted its applicability. A novel nanocatalyst was first synthesized by the modified sol-gel method using activated biochar as the support, nickel (Ni) as the active component, and cobalt (Co) as the promoter for converting tar into H2. The results indicated that a high H2 yield of 263.84 g H2/kg TMCs (Tar Model Compounds) and TMC conversion of almost 100% were obtained over 6% Ni-4% Co/char, with more than 30% increase in hydrogen yield compared to traditional catalysts. Moreover, 6% Ni-4% Co/char exhibited excellent resistance to carbon deposition by removing the nucleation sites for graphite formation, forming stable Ni-Co alloy, and promoting the char gasification reaction; resistance to oxidation deactivation due to the high oxygen affinity of Co and reduction of the oxidized nickel by H2 and CO; resistance to sintering deactivation by strengthened interaction between Ni and Co, high specific surface area (920.61 m2/g), and high dispersion (7.3%) of Ni nanoparticles. This work provided a novel nanocatalyst with significant potential for long-term practical applications in the in situ conversion of tar into H2 during steam reforming.