Anti-reflection coating with mullite and Duroid for large-diameter cryogenic sapphire and alumina optics.

We developed a broadband two-layer anti-reflection (AR) coating for use on a sapphire half-wave plate (HWP) and an alumina infrared (IR) filter for the cosmic microwave background (CMB) polarimetry. Measuring the faint CMB B-mode signals requires maximizing the number of photons reaching the detectors and minimizing spurious polarization due to reflection with an off-axis incident angle. Sapphire and alumina have high refractive indices of 3.1 and are highly reflective without an AR coating. This paper presents the design, fabrication, quality control, and measured performance of an AR coating using thermally sprayed mullite and Duroid 5880LZ. This technology enables large optical elements with diameters of 600 mm. We also present a thermography-based nondestructive quality control technique, which is key to assuring good adhesion and preventing delamination when thermal cycling. We demonstrate the average reflectance of about 2.6% (0.9%) for two observing bands centered at 90/150 (220/280) GHz. At room temperature, the average transmittance of a 105 mm square test sample at 220/280 GHz is 83%, and it will increase to 90% at 100 K, attributed to reduced absorption losses. Therefore, our developed layering technique has proved effective for 220/280 GHz applications, particularly in addressing dielectric loss concerns. This AR coating technology has been deployed in the cryogenic HWP and IR filters of the Simons Array and the Simons observatory experiments and applies to future experiments such as CMB-S4.

Simulation of nonlinear propagation of femtosecond laser pulses in air for quantitative prediction of the ablation crater shape.

The utilization of sub-100 fs pulses has attracted attention as an approach to further improve the quality and precision of femtosecond laser microfabrication. However, when using such lasers at pulse energies typical for laser processing, nonlinear propagation effects in air are known to distort the beam's temporal and spatial intensity profile. Due to this distortion, it has been difficult to quantitatively predict the final processed crater shape of materials ablated by such lasers. In this study, we developed a method to quantitatively predict the ablation crater shape, utilizing nonlinear propagation simulations. Investigations revealed that the ablation crater diameters derived by our method were in excellent quantitative agreement with experimental results for several metals over a two-orders-of-magnitude range in the pulse energy. We also found a good quantitative correlation between the simulated central fluence and the ablation depth. Such methods should improve the controllability of laser processing with sub-100 fs pulses and contribute to furthering their practical application to processes over a wide pulse-energy range, including conditions with nonlinear-propagating pulses.

Tb3+-doped fluorescent glass for biology.

Optical investigation and manipulation constitute the core of biological experiments. Here, we introduce a new borosilicate glass material that contains the rare-earth ion terbium(III) (Tb3+), which emits green fluorescence upon blue light excitation, similar to green fluorescent protein (GFP), and thus is widely compatible with conventional biological research environments. Micropipettes made of Tb3+-doped glass allowed us to target GFP-labeled cells for single-cell electroporation, single-cell transcriptome analysis (Patch-seq), and patch-clamp recording under real-time fluorescence microscopic control. The glass also exhibited potent third harmonic generation upon infrared laser excitation and was usable for online optical targeting of fluorescently labeled neurons in the in vivo neocortex. Thus, Tb3+-doped glass simplifies many procedures in biological experiments.