Electrospinning and Partial Etching Behaviors of Core-Shell Nanofibers Directly Electrospun on Mesh Substrates for Application in a Cover-Free Compact Air Filter.

The exposure of workers to propylene glycol monomethyl ether acetate (PGMEA) in manufacturing environments can result in potential health risks. Therefore, systems for PGMEA removal are required for indoor air quality control. In this study, core-shell zeolite socony mobil-5 (ZSM-5)/polyvinylpyrrolidone-polyvinylidene fluoride nanofibers were directly electrospun and partially wet-etched on a mesh substrate to develop a cover-free compact PGMEA air filter. The electrospinning behaviors of the core-shell nanofibers were investigated to optimize the electrospinning time and humidity and to enable the manufacture of thin and light air-filter layers. The partial wet etching of the nanofibers was undertaken using different etching solvents and times to ensure the exposure of the active sites of ZSM-5. The performances of the ZSM-5/PVDF nanofiber air filters were assessed by measuring five consecutive PGMEA adsorption-desorption cycles at different desorption temperatures. The synthesized material remained stable upon repeated adsorption-desorption cycles and could be regenerated at a low desorption temperature (80 °C), demonstrating a consistent adsorption performance upon prolonged adsorption-desorption cycling and low energy consumption during regeneration. The results of this study provide new insights into the design of industrial air filters using functional ceramic/polymer nanofibers and the application of these filters.

Natural Cellulose-Based Multifunctional Nanofibers for the Effective Removal of Particulate Matter and Volatile Organic Compounds.

Multifunctional nanofibers for particulate matter (PM) and volatile organic compounds (VOCs) removal from the indoor atmospheric environment were manufactured from eco-friendly natural cellulose materials via electrospinning using an optimized solvent system containing 1-ethyl-3-methylimidazolium acetate (EmimAC) and dimethylformide (DMF) in a 3:7 volume ratio. EmimAC improved the cellulose stability, whereas DMF improved the electrospinnability of the material. Various cellulose nanofibers were manufactured using this mixed solvent system and characterized according to the cellulose type, such as hardwood pulp, softwood pulp, and cellulose powder, and cellulose content ranging from 6.0-6.5 wt%. The correlation between the precursor solution alignment and electrospinning properties indicated an optimal cellulose content of 6.3 wt% for all cellulose types. The hardwood pulp-based nanofibers possessed the highest specific surface area and exhibited high efficiency for eliminating both PM and VOCs, with a PM2.5 adsorption efficiency of 97.38%, PM2.5 quality factor of 0.28, and toluene adsorption of 18.4 mg/g. This study will contribute to the development of next-generation eco-friendly multifunctional air filters for indoor clean-air environments.

Fabrication of 3D Printed Ceramic Part Using Photo-Polymerization Process.

Ceramics are high-strength and high-temperature resistant materials that are used in various functional parts. However, due to the high strength and brittleness properties, there are many difficulties in the fabrication of complex shapes. Therefore, there are many studies related to the fabrication of ceramic parts using 3D printing technology optimized for complex shapes. Among them, studies using photo-polymerization (PP) 3D printing technology with excellent dimensional accuracy and surface quality have received the most widespread attention. To secure the physical properties of sintered ceramic, the content and distribution of materials are important. This study suggests a novel 3D printing process based on a high-viscosity composite resin that maximizes the content of zirconia ceramics. For reliable printing, the developed 3D printers that can adjust the process environment were used. To minimize warpage and delamination, the divided micro square pattern images were irradiated in two separate intervals of 1.6 s each while maintaining the internal chamber temperature at 40 °C. This contributed to improved stability and density of the sintered structures. Ultimately, the ceramic parts with a Vickers hardness of 12.2 GPa and a relative density of over 95% were able to be fabricated based on a high-viscosity resin with 25,000 cps.

Highly Porous-Cellulose-Acetate-Nanofiber Filters Fabricated by Nonsolvent-Induced Phase Separation during Electrospinning for PM2.5 Capture.

Highly porous-cellulose-acetate (CA) nanofibers were prepared by an electrospinning process based on a nonsolvent-induced phase separation (NIPS) mechanism, and their PM2.5 capture efficiencies were evaluated. The NIPS condition during the electrospinning process was achieved by selecting appropriate good and poor solvents based on the Hansen solubility parameters of CA. N,N-dimethylacetamide (DMAc) was used as the good solvent, while dichloromethane (DCM), tetrahydrofuran (THF), and acetone were used as poor solvents. Porous-CA nanofibers were observed upon using the binary solvent systems of DCM:DMAc = 1:9, DCM:DMAc = 2:8, and THF:DMAc = 1:9, and the CA nanofibers formed using the DCM/DMAc system with DCM:DMAc = 1:9 were found to have the highest specific surface area of 1839 m2/g. Based on the optimized binary solvent system with DCM:DMAc = 1:9, porous-CA nanofibers were prepared and characterized according to the CA content in the electrospinning mixture. The results confirmed that a porous structure was formed well from the surface to the core of the nanofibers. The composition range of the ternary mixture of CA and two solvents capable of producing porous-CA nanofibers was mapped on a ternary phase diagram, and highly efficient PM2.5 capture with 98.2% efficiency was realized using porous-CA nanofibers obtained using a 10 wt.% CA solution. This work provides a new strategy for improving the efficiency of porous-nanofiber filters for PM2.5 capture.

Sintering Process Optimization for 3YSZ Ceramic 3D-Printed Objects Manufactured by Stereolithography.

A 3YSZ (3 mol% yttria-stabilized zirconia) ceramic green body with 50 vol% of ceramic content was 3D-printed by supportless stereolithography under optimal drying, debinding, and sintering conditions in order to achieve high strength and density. The viscosity and flowability of the ceramic nanocomposite resins were optimized by adjusting the amounts of non-reactive diluents. The ceramic 3D-printed objects have a high polymer content compared to ceramics samples manufactured by conventional manufacturing processes, and the attraction between layers is weak because of the layer-by-layer additive method. This causes problems such as layer separation and cracking due to internal stress generated when materials such as solvents and polymers are separated from the objects during the drying and debinding processes; therefore, the drying and debinding conditions of 3YSZ ceramic 3D-printed objects were optimized based on thermogravimetry-differential thermal analysis. The sintering conditions at various temperatures and times were analyzed using X-ray diffraction, SEM, and flexural strength analysis, and the body of the 3YSZ ceramic 3D-printed object that sintered at 1450 °C for 150 min had a relative density of 99.95% and flexural strength of 1008.5 MPa. This study widens the possibility of manufacturing ceramic 3D-printed objects with complex shapes, remarkable strength, and unique functionality, enabling their application in various industrial fields.

All-in-One Piezo-Triboelectric Energy Harvester Module Based on Piezoceramic Nanofibers for Wearable Devices.

An all-in-one energy harvester module comprising a top piezoelectric layer, a bottom piezoelectric layer, and a middle triboelectric layer was fabricated based on flexible piezoceramic nanofibers to serve as a power source for wearable devices. The top and bottom piezoelectric layers were manufactured by modularizing electrospun piezoceramic nanofibers with an interdigitated electrode, and the energy harvesting characteristics were maximized by laminating the single modules in z-axis array arrangements. The triboelectric layer was manufactured by attaching polydimethylsiloxane on both sides of an electrode layer, and the energy harvesting characteristics were controlled according to the surface roughness of the triboelectric modules. The output voltages of the individual energy harvester modules of the all-in-one module were individually or integrally measured by hand pressing the lower and upper parts of the module. The all-in-one energy harvester module generated a maximum voltage (power) of 253 V (3.8 mW), and the time required to charge a 0.1 µF capacitor to 25 V was 40 s. The results of a simulated energy harvesting experiment conducted on the all-in-one energy harvester module showed that 42 LED bulbs arranged in the shape of the "KICET" logo could be turned on in real time without charging, and a mini fan consuming a power of 3.5 W was operated after charging a 10 µF capacitor for 250 s. This work shows the potential of the all-in-one module as an ecofriendly flexible energy harvester for operating wearable devices.

Wearable Core-Shell Piezoelectric Nanofiber Yarns for Body Movement Energy Harvesting.

In an effort to fabricate a wearable piezoelectric energy harvester based on core-shell piezoelectric yarns with external electrodes, flexible piezoelectric nanofibers of BNT-ST (0.78Bi0.5Na0.5TiO3-0.22SrTiO3) and polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) were initially electrospun. Subsequently, core-shell piezoelectric nanofiber yarns were prepared by twining the yarns around a conductive thread. To create the outer electrode layers, the core-shell piezoelectric nanofiber yarns were braided with conductive thread. Core-shell piezoelectric nanofiber yarns with external electrodes were then directly stitched onto the fabric. In bending tests, the output voltages were investigated according to the total length, effective area, and stitching interval of the piezoelectric yarns. Stitching patterns of the piezoelectric yarns on the fabric were optimized based on these results. The output voltages of the stitched piezoelectric yarns on the fabric were improved with an increase in the pressure, and the output voltage characteristics were investigated according to various body movements of bending and pressing conditions.

Fabrication and Characterization of Aligned Flexible Lead-Free Piezoelectric Nanofibers for Wearable Device Applications.

Flexible lead-free piezoelectric nanofibers, based on BNT-ST (0.78Bi0.5Na0.5TiO3-0.22SrTiO3) ceramic and poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) copolymers, were fabricated by an electrospinning method and the effects of the degree of alignment in the nanofibers on the piezoelectric characteristics were investigated. The microstructure of the lead-free piezoelectric nanofibers was observed by field emission scanning electron microscope (FE-SEM) and the orientation was analyzed by fast Fourier transform (FFT) images. X-ray diffraction (XRD) analysis confirmed that the phase was not changed by the electrospinning process and maintained a perovskite phase. Polarization-electric field (P-E) loops and piezoresponse force microscopy (PFM) were used to investigate the piezoelectric properties of the piezoelectric nanofibers, according to the degree of alignment-the well aligned piezoelectric nanofibers had higher piezoelectric properties. Furthermore, the output voltage of the aligned lead-free piezoelectric nanofibers was measured according to the vibration frequency and the bending motion and the aligned piezoelectric nanofibers with a collector rotation speed of 1500 rpm performed the best.

A Study on the Rheological and Mechanical Properties of Photo-Curable Ceramic/Polymer Composites with Different Silane Coupling Agents for SLA 3D Printing Technology.

Silane coupling agents (SCAs) with different organofunctional groups were coated on the surfaces of Al2O3 ceramic particles through hydrolysis and condensation reactions, and the SCA-coated Al2O3 ceramic particles were dispersed in a commercial photopolymer based on interpenetrating networks (IPNs). The organofunctional groups that have high radical reactivity and are more effective in UV curing systems are usually functional groups based on acryl, such as acryloxy groups, methacrloxy groups, and acrylamide groups, and these silane coupling agents seem to improve interfacial adhesion and dispersion stability. The coating morphology and the coating thickness distribution of SCA-coated Al2O3 ceramic particles according to the different organofunctional groups were observed by FE-TEM. The initial dispersibility and dispersion stability of the SCA-coated Al2O3/High-temp composite solutions were investigated by relaxation NMR and Turbiscan. The rheological properties of the composite solutions were investigated by viscoelastic analysis and the mechanical properties of 3D-printed objects were observed with a nanoindenter.

Polydiacetylene single-walled carbon nanotubes nano-hybrid for cellular imaging applications.

The functionalization of single-walled carbon nanotubes (SWCNTs) by forming self-assembled supramolecular structure of 10,12-pentacosadiynoic acid (PCDA) on the carbon nanotube wall is reported. PCDA assemblies on SWCNTs (PCDA/SWCNTs) were polymerized by UV irradiation to extensively conjugated polydiacetylene (PDA). PDA/SWCNT was identified by absorption and emission spectroscopy, scanning and transmission electron microscopies (SEM and TEM) and atomic force microscopy (AFM). PDA/SCWNTs showed strong near-infrared (NIR) fluorescence caused by fluorescence resonance energy transfer (FRET) between PDA network and semiconducting SWCNT core. The micro-patterning of biotinylated PDA/SWCNT with FITC-avidin on biotinylated glass surface demonstrated the potential application for a bio-sensing device. Furthermore, the biocompatibility for mammalian cancer cells was tested by viability experiments, which revealed that the PDA/SWCNTs had very low toxicity below 31.3 mg/L in terms of pristine SWCNTs concentration. Also, PDA/SWCNTs inside the cells can be observed by NIR microscopy. This unique modular method of preparation can contribute to diverse functionalities for practical applications in various non-invasive cellular imaging.

Multifunctional polydiacetylene-graphene nanohybrids for biosensor application.

Graphene nanosheet hybridized with polydiacetylene (PDA) can be used as the electrochemical biosensor applications. Self-assembly and photo-polymerization chemistry of diacetylenic monomers on reduced graphene oxide (RGO) for non-covalent functionalization were used for high solubility and further functionality of graphene in water necessary for biosensor application. This enables regular graphene micropatterns to be formed on large substrates with chemical bonding and biological interactions. The PDA/RGO nanohybrids demonstrated the formation of conjugated polymer on graphene for fluorescence and electrochemical detection. The optical and structural properties of PDA/RGO, characterized by UV-Vis, FT-IR, Raman, and photoluminescence spectrometers, demonstrated that PDA and RGO in PDA/RGO are connected by physical interactions. Further-functionalization action of PDA/RGO with biotin was verified in microfluidic biochip via biotin-straptavidin interaction. Here, the applicability of functionalized RGO in the biochip and biosensing platform based on fluorescence detection was confirmed. The electrochemical experiments showed the potential of functionalized RGO for use as an electrochemical biosensor, especially with the detection of an analyte at low concentration.

Microvalves based on ionic polymer-metal composites for microfluidic application.

Simple and highly efficient microvalve systems based on an ionic polymer-metal composite (IPMC) diaphragm actuator have been developed. The microvalve system that was fabricated in this work operates when open and close voltage is applied, due to the phenomena of lithium ion flux and the subsequent electro-osmotic drag of water to the cathode. IPMC was prepared by compositing with platinum nanoparticles on both sides of Nafion thin film. SEM images of the IPMC showed the high density and uniform size distribution of the Pt nanoparticles in the interpenetrating layer to ensure the proper performance of an IPMC actuator. The displacement of the IPMC for the microvalve was measured with a laser displacement meter. The application of open and close voltage made the operation of the valve faster. The fluorescence images of the flow in the fabricated IPMC-based microvalve system showed the successful operation of flow control in the microfluidic channel. The IPMC-based microvalve system shows a potential of IPMC for application as an actuator in microfluidic systems.